UV/Vis+ Photochemistry Database
Literature-Service: Sulfur containing radicals and ions
Substances (unsorted): CS, CCS, FSO3, FSO5, FSO2N, CF3OS, CF3SO, CF3SOO, CH3S, CH3SCH2, CH3SCH2O2, CH3SO2, CH3SO3, HOSO, HSO2, (SCN)2-, SO2-, SO3-, SO4-, SO4(2-), SO5-, S2O3-, S2O3(2-), S4O6(2-), S4O6(3-), S2O8(2-)
The relevant Spectral Data, graphical representations, links to abstracts and other photochemical data & information are available for registered users, see Subscription
Please note: The substance groups are only a rough classification. To search for a specific substance please use the Search Tool or see the Substance-list.
Use your browser capabilities to search this site or use our Search Tool to search the database.
| Authors | Journal/Source | Title/Paper | Data Sheet |
|---|---|---|---|
| CS; carbon monosulfide; carbon sulfide; CAS-No.: 2944-05-0 | |||
| Y. Zhang, Y. Wang, Y. Liu, X. Ai, Z. Zhang, J. Li | J. Quant. Spectr. Rad. Transfer, 243, 106836, (2020) | Measurement of the absorption cross sections of unstable CS based on the dynamic equilibrium of CS2 and CS in the photolysis of CS2 |
|
| CCS | |||
| E. Riaplov, M. Wyss, J.P. Maier, D. Panten, G. Chambaud, P. Rosmus, J. Fabian | J. Mol. Spectroscopy, 222, 15-21, (2003) | Electronic absorption spectra of CCS- and CCS in neon matrices |
|
| FSO3; fluorosulfate radical; CAS-No.: 21549-02-0 | |||
| C.J. Cobos, A.E. Croce de Cobos, H. Hippler, E. Castellano | J. Phys. Chem., 93, 3089-3094, (1989) | Direct determination of the limiting high-pressure rate constants of the system FSO3 + FSO3 <--> F2S2O6 over the temperature range 293 - 381 K |
|
| A.E. Croce | J. Photochem. Photobiol. A: Chem., 51, 293-299, (1990) | Spectrokinetic determination of fluorosulphate radical absorption cross-sections |
|
| J.D. Burley, H.S. Johnston | J. Photochem. Photobiol. A: Chem., 66, 141-151, (1992) | Photoabsorption cross-sections of (FSO3)2 and FSO3 |
|
| C.J. Cobos, A.E. Croce, E. Castellano | J. Fluorine Chem., 79, 157-160, (1996) | Absorption cross-sections for vibrationally excited fluorosulphate radicals |
|
| M.E. Tucceri, M.P. Badenes, A.E. Croce, C.J. Cobos | Chem. Commun., 1, 71-72, (2001) | Kinetics of formation of the novel peroxide FC(O)OO(O2)SF |
|
| H. Beckers, P. Garcia, H. Willner, G.A. Arguello, C.J. Cobos, J.S. Francisco | Angew. Chem. Int. Ed., 46, 3754-3757, (2007) | Side-On versus End-On Bonding of O2 to the FSO3 Radical: Matrix Isolation and Ab Initio Study of FSO5 |
|
| FSO5; | |||
| A.E. Croce, C.J. Cobos, E. Castellano | J. Fluorine Chem., 82, 91-97, (1997) | Kinetics of formation and unimolecular decomposition of the FS(O2)OOO radical |
|
| H. Beckers, P. Garcia, H. Willner, G.A. Arguello, C.J. Cobos, J.S. Francisco | Angew. Chem. Int. Ed., 46, 3754-3757, (2007) | Side-On versus End-On Bonding of O2 to the FSO3 Radical: Matrix Isolation and Ab Initio Study of FSO5 |
|
| FSO2N; fluorosulfonyl nitrene radical; CAS-No.: | |||
| X. Zeng, H. Beckers, H. Willner | J. Am. Chem. Soc., 135, 6, 2096–2099, (2013) | Thermally Persistent Fluorosulfonyl Nitrene and Unexpected Formation of the Fluorosulfonyl Radical |
|
| CF3OS; trifluoromethyl oxathiyl radical; CAS-No.: | |||
| Z. Wu, J. Xu, G. Deng, X. Chu, L. Sokolenko, T. Trabelsi, J.S. Francisco, A.K. Eckhardt, P.R. Schreiner, X. Zeng | Chemistry, Eur. J., 24 (7), 1505-1508, (2018) | The Trifluoromethyl Sulfinyl and Oxathiyl Radicals |
|
| CF3SO; trifluoromethyl sulfinyl radical; CAS-No.: | |||
| Z. Wu, J. Xu, G. Deng, X. Chu, L. Sokolenko, T. Trabelsi, J.S. Francisco, A.K. Eckhardt, P.R. Schreiner, X. Zeng | Chemistry, Eur. J., 24 (7), 1505-1508, (2018) | The Trifluoromethyl Sulfinyl and Oxathiyl Radicals |
|
| CF3SOO; CF3O2S trifluoromethyl thiylperoxy radical; CAS-No.: | |||
| B. Zhu, Z. Wu, L. Wang, B. Lu, T. Trabelsi, J.S. Francisco, X. Zeng | Chem. Comm., 57, 12143-12146, (2021) | Matrix-isolated trifluoromethylthiyl radical: sulfur atom transfer, isomerization and oxidation reactions |
|
| CH3S; methylthio radical; methylsulfanyl; CAS-No.: 7175-75-9; PubChem: CID 123247 | |||
| Z. Wu, X. Shao, B. Zhu, L. Wang, B. Lu, T. Trabelsi, J.S. Francisco, X. Zeng | Comm. Chem., 5, 19, (2022) | Spectroscopic characterization of two peroxyl radicals during the O2-oxidation of the methylthio radical |
|
| C2H5S; CH3SCH2; methylthiomethyl radical; CAS-No.: | |||
| T.J. Wallington, T. Ellermann, O.J. Nielsen | J. Phys. Chem., 97, 8442-8449, (1993) | Atmospheric chemistry of dimethyl sulfide: UV spectra and self-reaction kinetics of CH3SCH2 and CH3SCH2O2 radicals and kinetics of the reactions CH3SCH2 + O2 --> CH3SCH2O2 and CH3SCH2O2 + NO --> CH3SCH2O + NO2 |
|
| CH3SCH2O2; methylthiomethylperoxy radical; CAS-No.: | |||
| T.J. Wallington, T. Ellermann, O.J. Nielsen | J. Phys. Chem., 97, 8442-8449, (1993) | Atmospheric chemistry of dimethyl sulfide: UV spectra and self-reaction kinetics of CH3SCH2 and CH3SCH2O2 radicals and kinetics of the reactions CH3SCH2 + O2 --> CH3SCH2O2 and CH3SCH2O2 + NO --> CH3SCH2O + NO2 |
|
| CH3SO2; CH3O2S; methyl thiylperoxy radical; CAS-No.: | |||
| Z. Wu, X. Shao, B. Zhu, L. Wang, B. Lu, T. Trabelsi, J.S. Francisco, X. Zeng | Comm. Chem., 5, 19, (2022) | Spectroscopic characterization of two peroxyl radicals during the O2-oxidation of the methylthio radical |
|
| CH3SO3; CH3O3S; methylsulfonyloxyl radical; CAS-No.: | |||
| B. Zhu, X. Zeng, H. Beckers, J.S. Francisco, H. Willner | Angewandte Chemie Int. Ed., 54, 11404–11408, (2015) | The Methylsulfonyloxyl Radical, CH3SO3 |
|
| HOSO; (hydroxythio)oxidanyl; hydroxidooxidosulfur radical; HOSO radical; CAS-No.: | |||
| B. Lu, T. Trabelsi, V.J. Esposito, R.C. Fortenberry, J.S. Francisco, X. Zeng | J. Phys. Chem. A, 125, 50, 10615–10621, (2021) | Spectroscopic Characterization of HSO2• and HOSO• Intermediates Involved in SO2 Geoengineering |
|
| HSO2; sulfinic acid radical; CAS-No.: | |||
| B. Lu, T. Trabelsi, V.J. Esposito, R.C. Fortenberry, J.S. Francisco, X. Zeng | J. Phys. Chem. A, 125, 50, 10615–10621, (2021) | Spectroscopic Characterization of HSO2• and HOSO• Intermediates Involved in SO2 Geoengineering |
|
| (SCN)2-; thiocyanate dimer radical anion; CAS-No.: | |||
| H. Herrmann, D. Hoffmann, T. Schaefer, P. Braeuer, A. Tilgner | ChemPhysChem, 11, 3796-3822, (2010) | Tropospheric Aqueous-Phase Free-Radical Chemistry: Radical Sources, Spectra, Reaction Kinetics and Prediction Tools |
|
| SO2-; sulfur dioxide anion; CAS-No.: 12143-17-8 | |||
| E. Hayon, A. Treinin, J. Wilf | J. Am. Chem. Soc., 94, 1, 47–57, (1972) | Electronic spectra, photochemistry, and autoxidation mechanism of the sulfite-bisulfite-pyrosulfite systems. SO2-, SO3-, SO4-, and SO5- radicals |
|
| SO3-; sulfite radical anion; sulfur trioxide radical anion; CAS-No.: 12210-38-7 | |||
| E. Hayon, A. Treinin, J. Wilf | J. Am. Chem. Soc., 94, 1, 47–57, (1972) | Electronic spectra, photochemistry, and autoxidation mechanism of the sulfite-bisulfite-pyrosulfite systems. SO2-, SO3-, SO4-, and SO5- radicals |
|
| H. Herrmann | Phys. Chem. Chem. Phys.,9, 3935-3964, (2007) | On the photolysis of simple anions and neutral molecules as sources of O-/OH, SOx- and Cl in aqueous solution |
|
| SO4-; SO4 radical anion; sulfate radical; CAS-No.: 12143-45-2 | |||
| E. Hayon, A. Treinin, J. Wilf | J. Am. Chem. Soc., 94, 1, 47–57, (1972) | Electronic spectra, photochemistry, and autoxidation mechanism of the sulfite-bisulfite-pyrosulfite systems. SO2-, SO3-, SO4-, and SO5- radicals |
|
| H. Herrmann, D. Hoffmann, T. Schaefer, P. Braeuer, A. Tilgner | ChemPhysChem, 11, 3796-3822, (2010) | Tropospheric Aqueous-Phase Free-Radical Chemistry: Radical Sources, Spectra, Reaction Kinetics and Prediction Tools |
|
| SO4(2-); sulfate; sulfate anion; CAS-No.: 14808-79-8; PubChem: CID 1117 | |||
| J.L. Weeks, G.M.A.C. Meaburn, S. Gordon | Radiation Research, 19 (3), 559-567, (1963) | Absorption Coefficients of Liquid Water and Aqueous Solutions in the Far Ultraviolet |
|
| SO5-; SO5 radical anion; sulfur pentoxide radical anion; CAS-No.: | |||
| E. Hayon, A. Treinin, J. Wilf | J. Am. Chem. Soc., 94, 1, 47–57, (1972) | Electronic spectra, photochemistry, and autoxidation mechanism of the sulfite-bisulfite-pyrosulfite systems. SO2-, SO3-, SO4-, and SO5- radicals |
|
| H. Herrmann | Phys. Chem. Chem. Phys.,9, 3935-3964, (2007) | On the photolysis of simple anions and neutral molecules as sources of O-/OH, SOx- and Cl in aqueous solution |
|
| S2O3-; thiosulfate radical anion; CAS-No.: | |||
| M. Schoeneshoefer | Int. J. Radiat. Phys. Chem., 5, 375-376, (1973) | Pulsradiolytische untersuchung über das S4O6(3-)-radikal als zwischenprodukt der thiosulfatoxidation und tetrathionatreduktion |
|
| S2O3(2-); thiosulfate ion; thiosulfate; sulfurothioate; CAS-No.: 14383-50-7; PubChem: CID 1084 | |||
| A.D. Awtrey, R.E. Connick | J. Am. Chem. Soc., 73 (4), 1842-1843, (1951) | The Absorption Spectra of I2, I3-, I-, IO3-, S4O6- and S2O3-. Heat of the Reaction I3- = I2 + I- |
|
| S4O6(2-); tetrathionate; tetrathionate ion(2-); CAS-No.: 15536-54-6; PubChem: CID 4657547 | |||
| A.D. Awtrey, R.E. Connick | J. Am. Chem. Soc., 73 (4), 1842-1843, (1951) | The Absorption Spectra of I2, I3-, I-, IO3-, S4O6- and S2O3-. Heat of the Reaction I3- = I2 + I- |
|
| S4O6(3-); S4O6(3-) radical anion; CAS-No.: | |||
| M. Schoeneshoefer | Int. J. Radiat. Phys. Chem., 5, 375-376, (1973) | Pulsradiolytische untersuchung über das S4O6(3-)-radikal als zwischenprodukt der thiosulfatoxidation und tetrathionatreduktion |
|
| S2O8(2-); peroxydisulfate ion; CAS-No.: 15092-81-6; PubChem: CID 107879 | |||
| J. Zhao, E.M. Payne, B. Liu, C. Shang, E.R. Blatchley III, W.A. Mitch, R. Yin | Water Research, 241, 120169, (2023) | Making Waves: Opportunities and Challenges of Applying Far-UVC Radiation in Controlling Micropollutants in Water |
|
| R. Yin, Y. Zhang, Y. Wang, J. Zhao, C. Shang | Environ. Sci. Technol., 58, 13, 6030–6038, (2024) | Far-UVC Photolysis of Peroxydisulfate for Micropollutant Degradation in Water |
|
