science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: chlorine dimethyl sulfoxide radical adduct	Other Names: 

Formula: CH3(Cl)S(O)CH3					CAS-No.:

Study: UV/Vis absorption spectroscopy, kinetics

                
Authors: K.M. Kleissas, J.M. Nicovich, P.H. Wine

Title: Spectroscopy and kinetics of the gas phase addition complex of atomic chlorine with dimethyl sulfoxide

Journal/Source: J. Photochem. Photobiol. A: Chem., 187, 1-9, (2007); http://dx.doi.org/10.1016/j.jphotochem.2006.08.020


Data: diagram, table

Energy/Wavelength range: 310 - 510 nm

Resolution: 10 nm

Temperature: 296 K

Temperature dependence: 

Pressure/Concentration:

Phase: gas

pH:


Comments: lambda max = 394 nm and sigma max = (4.0±1.4)×10-17 cm2 molecule-1 (base e); The cross 
sections can be put on an absolute scale by taking the 390 nm cross section to be 
(4.0 +/- 1.4) x 10^-17 cm^2 (base e) as discussed in the paper.


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