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Substance: carbon disulfide-chlorine adduct		Other Names: 

Formula: CS2-Cl						CAS-No.: 

Study: UV absorption spectroscopy, kinetics


Authors: V. Dookwah-Roberts, R. Soller, J.M. Nicovich, P.H. Wine

Title: Spectroscopic and kinetic study of the gas-phase CS2-Cl adduct

Journal/Source: J. Photochem. Photobiol. A: Chem., 176 (1-3), 114-123, (2005); https://doi.org/10.1016/j.jphotochem.2005.08.013


Data: table, diagram

Energy/Wavelength range: 320 - 600 nm

Resolution: 5.5 nm FWHM

Temperature: 240 K

Temperature dependence: no

Pressure/Concentration:  P = 100 Torr N2 

Phase: gas

pH:


Comments: CS2Cl is found to possess a strong absorption band at lambda(max) ~ 365 nm with sigma(max) = (2.3 ± 0.7) x 10-17 cm2 molecule-1 (base e) and a weaker 
band at lambda(max) ~ 480 nm; the gas-phase spectrum of CS2Cl is very similar to the previously reported liquid-phase spectrum in CCl4 solvent.

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