science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: thiophosgene					Other Names: carbon chlorosulfide; thiocarbonyl chloride

Formula: CCl2S						CAS-No.: 463-71-8

Study: uv absorption spectroscopy


Authors: M. Maciejewski, M. Szymanski, R.P. Steer

Title: A dark, excited electronic state of thiophosgene in the near ultraviolet

Journal/Source: Chem. Phys., 165, 101-112, (1992); http://www.sciencedirect.com/science/article/pii/030101049280047Y


Data: diagram, table

Energy/Wavelength range: 285 - 340 nm

Resolution: 

Temperature: 295 K

Temperature dependence: no

Pressure/Concentration:

Phase: solution (PFDMCH; perfluoro-1,3-dimethylcyclohexane)

pH:


Comments: A new, weak (f ~ 5 x 10^-5) band at lambda 285 <= 340 nm has been positively identified m the absorption spectrum of the pure, monomeric
solute. The fluorescence spectrum and the fluorescence quantum yields are given.

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