science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: thiophene					Other Names: thiacyclopentadiene

Formula: C4H4S						CAS-No.: 110-02-1

Study: uv absorption spectroscopy

                
Authors: D.M.P. Holland, A.B. Trofimov, E.A. Seddon, E.V. Gromov, T. Korona, N. de Oliveira, L.E. Archer, D. Joyeux, L. Nahon

Title: Excited electronic states of thiophene: high resolution photoabsorption Fourier transform spectroscopy and ab initio calculations

Journal/Source: Phys. Chem. Chem. Phys.,16, 21629-21644, (2014); DOI: 10.1039/C4CP02420F 


Data: table, diagram

Energy/Wavelength range: ~ 5 - 12.5 eV (~ 99.2 - 248 nm)

Resolution: 2.1 meV (FWHM)

Temperature: 298 K

Temperature dependence: no

Pressure/Concentration: 

Phase: gas

pH:


Comments: A highly resolved photoabsorption spectrum has been measured between ~ 5 and 12.5 eV. The relative photoabsorption spectrum obtained 
from the FTS has been normalised, at an energy of 9.1 eV, to the absolute photoabsorption cross section measured by Rennie et al. (Chem. Phys., 306, 295, 2004).

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