science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: fluoromethyl peroxy radical			Other Names: 

Formula: CH2FO2						CAS-No.:

Study: uv absorption spectra, kinetics

                
Authors: P. Dagaut, T.J. Wallington, M.J. Kurylo

Title: The UV absorption spectra and kinetics of the self reactions of CH2ClO2 and CH2FO2 radicals in the gas phase

Journal/Source: Int. J. Chem. Kinetics, 20, 815-826, (1988); DOI: 10.1002/kin.550201006


Data: table, diagram

Energy/Wavelength range: 210 - 290 nm

Resolution: 

Temperature: 298 K

Temperature dependence: no

Pressure/Concentration:

Phase: gas

pH:


Comments: The ultraviolet absorption spectra of chloromethylperoxy and fluoromethylperoxy radicals, CH2ClO2 and CH2FO2, and the kinetics of their 
respective self reactions have been studied in the gas phase using a flash photolysis technique. The absorption spectra for both radicals were quantified 
over the wavelength range 210 and 290 nm.
Scaled by 4.58/3.83 to sigma(CH3O2) at 240 nm.

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