science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: benzylperoxy radical				Other Names: methylbenzene

Formula: C7H7O2; C6H5CH2O2				CAS-No.: 108-88-3

Study: uv absorption spectroscopy, kinetics

                
Authors: B. Nozière, R. Lesclaux, M.D. Hurley, M.A. Dearth, T.J. Wallington

Title: A kinetic and mechanistic study of the self-reaction and reaction with HO2 of the benzylperoxy radical

Journal/Source: J. Phys. Chem., 98, 2864-2873, (1994); DOI: 10.1021/j100062a023


Data: table, diagram

EnergyWavelength range: 220 - 300 nm

Resolution:

Temperature: 295 K

Temperature dependence: no

Pressure/Concentration: 

Phase: gas

pH:


Comments: The uv spectrum of the benzylperoxy radical was similar to those of alkylperoxy radicals, with a maximum
cross section at 245 nm of 6.8 x 10^-18 cm2 molecule-1.

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