science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (c) science-softCon 2019

Substance: ammonia-d3					Other Names: 

Formula: ND3						CAS-No.: 13550-49-7

Study: photolysis, quantum yields, absorption coefficients

                
Authors: R.L. Lilly, R.E. Rebbert, P. Ausloos

Title: Far ultra-violet photolysis of ammonia quantum yield determination for the primary process: NH3 (ND3) + hv -> NH (ND) + H2 (D2)

Journal/Source: J. Photochem., 2 (1), 49-61, (1973-1974); doi:10.1016/0047-2670(73)80004-8


Data: table

Energy/Wavelength range: 104.8-106.7nm; 123.6 nm; 147nm

Resolution: 

Temperature: 298 K

Temperature dependence: no

Pressure/Concentration: 10 - 180 Torr

Phase: gas

pH:


Comments: The gas phase photolysis of NH3-C2D4 and ND3-C2H4 mixtures has been investigated at 147 nm (8.4 eV), 123.6 nm (10 eV) 
and 104.8-106.7 nm (11.6-11.8 eV). The quantum yield of D2 in the irradiation of ND3-C2H4 mixtures is independent of the concentration 
of C2H4 and of the pressure of ND3 (10 to 180 Torr).
The absorption coefficients at 104.8-106.7,123.6 and 147nm are presented.

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