science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: chlorine dioxide				Other Names: 

Formula: OClO						CAS-No.: 

Study: quantum yield, photolysis, UV absorption spectrum


Authors: C.L. Thomsen, P.J. Reid, S.R. Keiding

Title: Quantum Yield for ClOO Formation following Photolysis of Aqueous OClO 

Journal/Source: J. Am. Chem. Soc., 122 (51), 12795 -12801, (2000); 10.1021/ja002148o S0002-7863(00)02148-X 


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Phase: aqueous solution

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Comments: The main photolytic products ClO + O, formed with a quantum yield of ~90%.
The total quantum yield for chlorine atom production is PHI(Cl) ~10%.
The UV absorption spectrum for aqueous ClOO is reported.

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