science-softCon uv/vis+ photochemistry database; www.photochemistry.org; (C) science-softCon 2019 Substance: chlorine oxide dimer Other Names: Formula: ClOOCl CAS-No.: 10049-04-4 Study: UV absorption spectrum, quantum yields, photolysis Authors: D.M. Wilmouth, T.F. Hanisco, R.M. Stimpfle, J.G. Anderson Title: Chlorine-Catalyzed Ozone Destruction: Cl Atom Production from ClOOCl Photolysis Journal/Source: J. Phys. Chem. A, 113 (51), 14099-14108, (2009); DOI: 10.1021/jp9053204 Data Energy/Wavelength range: 248, 308, 352 nm Resolution: Temperature: Temperature dependence: Pressure/Concentration: Phase: pH: Comments: The authors found the product of the quantum yield of the Cl atom production channel of ClOOCl photolysis and the ClOOCl absorption cross section, (phi · sigma)ClOOCl = 660 ± 100 at 248 nm, 39.3 ± 4.9 at 308 nm, and 8.6 ± 1.2 at 352 nm (units of 10-20 cm2 molecule-1). Author to whom correspondence should be addressed: (e-mail address):