science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: cyclohexadienyl radical			Other Names: 

Formula: C6H7						CAS-No.: 

Study: uv absorption spectrum


Authors: F. Berho, M.-T. Rayez, R. Lesclaux

Title: UV Absorption Spectrum and Self-Reaction Kinetics of the Cyclohexadienyl Radical, and Stability of a Series of Cyclohexadienyl-Type Radicals

Journal/Source: J. Phys. Chem. A, 103, 5501-5509, (1999); DOI: 10.1021/jp9904318


Data: diagram, table

Energy/Wavelength range: 280 - 315 nm

Resolution: 

Temperature: 298 K

Temperature dependence: no

Pressure/Concentration: atmospheric pressure 760 (± 10 Torr)

Phase: gas

pH


Comments: The absolute UV spectrum exhibits an intense peak of absorption at 302 nm, similar to that of other cyclohexadienyltype
radicals, with sigma(max) = (2.55 ± 0.45) x 10-17 cm2 molecule-1 at 302 nm (total uncertainty).

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