science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: hydroxycyclohexadienyl radical		Other Names: cyclohexadienyl, 6-hydroxy-

Formula: C6H7O						CAS-No.: 11084-15-4	PubChem: CID 192872

Study: uv absorption cross sections, kinetics


Authors: S.Y. Grebenkin, L.N. Krasnoperov

Title: Kinetics and Thermochemistry of the Hydroxycyclohexadienyl Radical Reaction with O2: C6H6OH + O2 <--> C6H6(OH)OO

Journal/Source: J. Phys. Chem. A, 108 (11), 1953-1963, (2004); DOI: 10.1021/jp030935c


Data: table, diagram

Energy/Wavelength range: 265 - 335 nm

Resolution: 

Temperature: 298 K

Temperature dependence: no

Pressure/Concentration: 1 bar (He)

Phase: gas

pH:


Comments: The radical has continuous absorption in the range 260-340 nm with a maximum absorption cross-section of (8.1 ± 1.4) x 10-18 cm2 molecule-1 at 280 nm.

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