science-softCon uv/vis+ photochemistry database;		www.photochemistry.org; (C) science-softCon 2023

Substance: 1,1-dichloro-2,2,2-trifluoroethylperoxy radical	Other Names: 

Formula: C2Cl2F3O2; CF3CCl2O2					CAS-No.: 	PubChem: CID

Study: UV absorption spectrum, kinetics

                
Authors: G.D. Hayman, M.E. Jenkin, T.P. Murrels, S.J. Shalliker

Title: Kinetic and mechanistic studies associated with the atmospheric degradation of HCFC-123

Journal/Source: STEP-HALOCIDE/AFEAS Workshop, Dublin, (1991)


Data: diagram, table

Energy/Wavelength range: 220 - 290 nm

Resolution: 

Pathlength:

Temperature: 298 K

Temperature dependence: no

Pressure/Concentration: 

Phase: gas

pH:


Comments: Laser photolysis of CF3CCl3 at 193 nm in the presence of oxygen. Reference and absorption cross sections from the review of
P.D. Lightfoot, R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, F. Zabel, "Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry,
CEC air pollution research report 40, p42, (1993).