Substances: NH3, NH2D, NHD2, ND3, N2H2, PCl3, PF3, PH3, F3OP, PbO, SiCl4, SiF4, SiH3, SiH4, Si(CH3)4, C2H3Cl3Si, C3H5Cl3Si, UF5, UF6, As4, C4H8O2
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Service
Please note: In addition,
information concerning related publications (e.g. quantum yield studies or
photolysis studies) for some of the substances are given. Send
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| Authors | Journal/Source | Title/Paper |
Data Sheet |
| NH3; ammonia; CAS-No.: 7664-41-7 | |||
| A. D. Walsh, P. A. Warsop | Trans. Faraday Soc., 57, 345 - 358, (1961) | The ultra-violet absorption spectrum of ammonia |
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| B.A. Thompson, P. Harteck, R.R. Reever Jr. | J. Geophys. Res., 68, 6431-6436, (1963) | Ultraviolet Absorption Coefficients of CO2, CO, H2O, N2O, NH3, NO, SO2, and CH4 between 1850 and 4000 A |
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| U. Persson, B. Marthinsson, J. Johansson, S. T. Eng | Applied Optics, 19, 1711, (1980) | Temperature and pressure dependence of NH3 and C2H4 absorption cross sections at CO2 laser wavelengths |
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| A. M. Quinton, J. P. Simons | J. Chem. Soc., Faraday Trans. 2, 78, 1261 - 1269, (1982) | Vacuum ultraviolet photodissociation of ammonia |
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| M. Suto, L.C. Lee | J. Chem. Phys., 78, 4515, (1983) | Photodissociation of NH3 at 106 - 200 nm |
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| G. R. Burton, Wing Fat Chan, G. Cooper, C. E. Brion | Chem. Phys., 177, 217-231, (1993) | The electronic absorption spectrum of NH3 in the valence shell discrete and continuum regions. Absolute oscillator strengths for photoabsorption (5–200 eV) |
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| J. Mellqvist, A. Rosen | J. Quant. Spectros. Rad. Trans., 56 (2), 187-208, (1996) | DOAS for flue gas monitoring-I. Temperature effects in the U.V./visible absorption spectra of NO, NO2, SO2 and NH3 |
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| J. Mellqvist, A. Rosen | J. Quant. Spectros. Rad. Trans., 56 (2), 209-224, (1996) | DOAS for flue gas monitoring-II. Deviations from the Beer-Lambert law for the U.V./visible absorption spectra of NO, NO2, SO2 and NH3 |
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| A.C.A. Souza, S.K. Srivastava | J. Braz. Chem. Soc., 7 (2), 91-95, (1996) | Photoabsorption cross sections derived by the electron energy loss spectroscopy technique for ammonia, methane and acetylene |
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| R.M. Mihalcea, M.E.Webber, D.S. Baer, R.K. Hanson, G.S. Feller, W.B. Chapman | Appl. Phys. B, 67, 283–288, (1998) | Diode-laser absorption measurements of CO2, H2O, N2O, and NH3 near 2.0 micrometer |
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| D. Edvardsson, P. Baltzer, L. Karlsson, B. Wannberg, D. M. P. Holland, D. A. Shaw, E. E. Rennie | J. Phys. B: At. Mol. Opt. Phys., 32, 2583-2609, (1999) | A photoabsorption, photodissociation and photoelectron spectroscopy study of NH3 and ND3 |
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| F.Z. Chen, D.L. Judge, C.Y.R. Wu, J. Caldwell | Planetary and Space Science, 47, 261-266, (1999) | Low and Room Temperature Photoabsorption Cross Sections of NH3 in the UV Region (175 K, 195 K, 295 K) |
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| R.K. Vatsa, H.-R. Volpp | Chem. Phys. Let., 340, 289-295, (2001) | Absorption cross-sections for some atmospherically important molecules at the H atom Lyman-alpha wavelength (121.567 nm) |
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| G.H. Mount, B. Rumburg, J. Havig, B. Lamb, H. Westberg, D. Yonge, K. Johnson, R. Kincaid | Atmos. Environment, 36, 1799-1810, (2002) | Measurement of atmospheric ammonia at a dairy using differential optical absorption spectroscopy in the mid-ultraviolet |
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| B.-M. Cheng, H.-C. Lu, H.-K. Chen, M. Bahou, Y.-P. Lee, A. M. Mebel, L. C. Lee, M.-C. Liang, Y. L. Yung | Astrophys. J., 647, 1535-1542, (2006) | Absorption Cross Sections of NH3, NH2D, NHD2, and ND3 in the Spectral Range 140-220 nm and Implication to Planetary Isotopic Fractionation |
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| B-M. Cheng | NSRRC Activity Report 2006/2007, 11-13, (2007) | VUV Photoabsorption Cross Sections of 15NH3 |
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| Y.-J. Wu, H.-C. Lu, H.-K. Chen, B.-M. Cheng, Y.P. Lee, L.C. Lee | J. Chem. Phys. 127, 154311, (2007) | Photoabsorption cross sections of NH3, NH2D, NHD2, and ND3 in the spectral range 110–144 nm |
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| Hsiao-Chi Lu, Hong-Kai Chen, Bing-Ming Cheng, J.F. Ogilvie | Spectrochim. Acta Part A: Molecular and Biomolecular Spectroscopy, 71 (4), 1485-1491, (2008) | Absorption spectra in the vacuum ultraviolet region of small molecules in condensed phases |
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| D.M. O’Leary, J. Orphal, A.A. Ruth, U. Heitmann, P. Chelin, C.E. Fellows | JQSRT, 109, 1004-1015, (2008) | The cavity-enhanced absorption spectrum of NH3 in the near-infrared region between 6850 and 7000 cm-1 |
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| Hui Jia, Weixiong Zhao, Tingdong Cai, Weidong Chen, Weijun Zhang, Xiaoming Gao | JQSRT, 110, 347-357, (2009) | Absorption spectroscopy of ammonia between 6526 and 6538 cm-1 |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| H.S. Taylor | Third Report of the Committee on Photochemistry: Reprint and Circular Series of the National Research Council, Committee on Photochemistry; ISBN: 0-309-55909-X, pp 85-90, (1938) | The secondary processes in the photodecomposition of ammonia and hydrazine |
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| W. Groth | Angewandte Chemie, 77 (8), 361-392, (1965) | Die Photolyse des Ammoniaks im Vakuum-Ultraviolett |
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| H. Okabe, M. Lenzi | J. Chem. Phys. 47, 5241, (1967) | Photodissociation of NH3 in the Vacuum Ultraviolet |
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| R. L. Lilly, R. E. Rebbert, P. Ausloos | J. Photochem., 2 (1), 49-61, (1973-1974) | Far ultra-violet photolysis of ammonia quantum yield determination for the primary process: NH3 (ND3) + hv --> NH (ND) + H2 (D2) |
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| M. N. R. Ashfold, R. N. Dixon, M. Kono, D. H. Mordaunt, C. L. Reed, M. J. J. Vrakking, I. M. Mills | Philosophical Transactions: Mathematical, Physical and Engineering Sciences, Vol. 355, No. 1729, Molecular Rydberg Dynamics, pp. 1659-1676, (1997) | Near Ultraviolet Photolysis of Ammonia and Methylamine Studied by H Rydberg Atom Photofragment Translational Spectroscopy |
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| Additional datasheets and spectra of NH3 are available at our Spectra Service | |||
| NH2D; ammonia-d1; CAS-No.: 13587-49-0 | |||
| B.-M. Cheng, H.-C. Lu, H.-K. Chen, M. Bahou, Y.-P. Lee, A. M. Mebel, L. C. Lee, M.-C. Liang, Y. L. Yung | Astrophys. J., 647, 1535-1542, (2006) | Absorption Cross Sections of NH3, NH2D, NHD2, and ND3 in the Spectral Range 140-220 nm and Implication to Planetary Isotopic Fractionation |
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| NHD2; ammonia-d2; CAS-No.: 13780-28-4 | |||
| B.-M. Cheng, H.-C. Lu, H.-K. Chen, M. Bahou, Y.-P. Lee, A. M. Mebel, L. C. Lee, M.-C. Liang, Y. L. Yung | Astrophys. J., 647, 1535-1542, (2006) | Absorption Cross Sections of NH3, NH2D, NHD2, and ND3 in the Spectral Range 140-220 nm and Implication to Planetary Isotopic Fractionation |
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| ND3; ammonia-d3; CAS-No.: 13550-49-7 | |||
| B.-M. Cheng, H.-C. Lu, H.-K. Chen, M. Bahou, Y.-P. Lee, A. M. Mebel, L. C. Lee, M.-C. Liang, Y. L. Yung | Astrophys. J., 647, 1535-1542, (2006) | Absorption Cross Sections of NH3, NH2D, NHD2, and ND3 in the Spectral Range 140-220 nm and Implication to Planetary Isotopic Fractionation |
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| N2H2; diimide; diazene; CAS-No.: 3618-05-1 | |||
| R.A. Back, C. Willis, D.A. Ramsey | Can. J. Chemistry, 52, 1006-1012, (1974) | The near-ultraviolet absorption spectrum of diimide vapor |
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| R. A. Back, C. Willis | Can. J. Chem., 52(13): 2513–2515, (1974) | The Near-ultraviolet Absorption Spectrum of Diimide in Liquid Ammonia and its Decomposition between -65 and -38 °C |
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| R.A. Back, C. Willis, D.A. Ramsay | Can. J. Chemistry, 56, 1575-1578, (1978) | The near-ultraviolet absorption spectrum of diimide: a re-examination |
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| P.S. Neudorfl, R.A. Back, A.E. Douglas | Can. J. Chem., 59, 506-517, (1981) | The absorption spectrum of trans-diimide (N2H2) in the vacuum ultraviolet region |
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| H. R. Tang, D. M. Stanbury | Inorg. Chem., 33 (7), 1388-1391, (1994) | Direct Detection of Aqueous Diazene: Its UV Spectrum and Concerted Dismutation |
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| PCl3; phosphorus trichloride; CAS-No.: 7719-12-2 | |||
| J.W. Au, C.E. Brion | Chem. Phys., 218, 87-107, (1997) | Quantitative studies of the photoabsorption and photoionization of PCl3 in the valence and inner (P 2p,2s; Cl 2p,2s) shell regions |
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| PF3; phosphorus trifluoride; CAS-No.: 7783-55-3 | |||
| J. W. Au, G. Cooper, C. E. Brion | Chem. Phys., 215, 397-418, (1997) | Photoabsorption and photoionization of the valence and inner (P 2p, 2s) shells of PF3: Absolute oscillator strengths and dipole-induced breakdown pathways |
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| PH3; phosphine; CAS-No.: 7803-51-2 | |||
| A.M. Halpern, B.R. Ramachandran | J. Molecular Spectroscopy, 151, 26-32, (1992) | The electronic spectroscopy and photophysics of saturated phosphines |
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| R.A.H. Butler, L. Sagui, I. Kleiner, L.R. Brown | J. Molecular Spectroscopy, 238, 178-192, (2006) | The absorption spectrum of phosphine (PH3) between 2.8 and 3.7 micrometer: Line positions, intensities, and assignments |
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| F3OP; phosphoryl fluoride; trifluorophosphine oxide; CAS-No.: 13478-20-1 | |||
| D. C. Frost, F. G. Herring, K. A. R. Mitchell, I. A. Stenhouse | J. Am. Chem. Soc., 93 (7), 1596-1600, (1971) | Photoelectron spectra and electronic structures of trifluoroamine oxide and trifluorophosphine oxide |
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| SiCl4; tetrachlorsilane; CAS-No.: 10026-04-7 | |||
| G.C. Causley, B.R. Russell | J. Electron Spectrosc. Relat. Phenom., 11, 383-397, (1977) | The vacuum ultraviolet absorption spectra of the Group IVA tetrachlorides |
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| K. Kameta, M. Ukai, T. Numazawa, N. Terezawa, Y. Chikahiro, N. Kouchi, Y. Hatano | J. Chem. Phys., 99, 2487-2494, (1993) | Photoabsorption, photoionization, and neutral-dissociation cross sections of SiF4, SiCl4, and Si(CH3)4 in the extreme ultraviolet range |
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| T. Ibuko, M. Kono, Y. Asari, A. Hiraya, K. Shobatake | J. Chem. Phys., 106, 4853-4859, (1997) | Photoabsorption and fluorescence cross sections of SiCl4 in the region of 6.2 - 31 eV |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| H. Biehl, K. J. Boyle, D. P. Seccombe, D. M. Smith, R. P. Tuckett, H. Baumgärtel, H. W. Jochims | Journal of Electron Spectroscopy and Related Phenomena, 97, 89-113, (1998) | Vacuum–UV fluorescence spectroscopy of CCl4, SiCl4 and GeCl4 in the range 9–25 eV |
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| SiF4; silicon tetrafluoride; CAS-No.: 7783-61-1 | |||
| M. Suto, X. Wang, L.C. Lee | J. Chem. Phys., 86, 1152-1156, (1987) | Quantitative study on the photoexcitation process of SiF4 at 49-120 nm |
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| X.Z. Guo, G. Cooper, W.F. Chan, G.R. Burton, C.E. Brion | Chem. Phys., 161, 471-484, (1992) | Absolute oscillator-strengths for the photoabsorption, photoionization and ionic photofragmentation of silicon tetrafluoride. II. The Si 2p and 2s inner shells |
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| K. Kameta, M. Ukai, T. Numazawa, N. Terezawa, Y. Chikahiro, N. Kouchi, Y. Hatano | J. Chem. Phys., 99, 2487-2494, (1993) | Photoabsorption, photoionization, and neutral-dissociation cross sections of SiF4, SiCl4, and Si(CH3)4 in the extreme ultraviolet range |
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| SiH3; silyl radical; CAS-No.: 13765-44-1 | |||
| R. D. Johnson, III, J. W. Hudgens | Chem. Phys. Lett., 141 (3), 163-165, (1987) | A new eletronic spectrum of the SiH3 radical observed using multiphoton ionization spectroscopy |
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| P. D. Lightfoot, R. Becerra, A. A. Jemi-Alade, R. Lesclaux | Chem. Phys. Lett., 180 (5), 441-445, (1991) | The UV absorption spectrum of SiH3 |
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| M. G. H. Boogaarts, P. J. Böcker, W. M. M. Kessels, D. C. Schram, M. C. M. van de Sanden | Chem. Phys. Lett., 326, 400-406, (2000) | Cavity ring down detection of SiH3 on the broadband A2A1' <-- 2A1 transition in a remote Ar-H2-SiH4 plasma |
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| A.V. Baklanov, L.N. Krasnoperov | J. Phys. Chem. A, 105, 4917-4922, (2001) | UV absorption spectrum and rate constant for self-reaction of silyl radicals |
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| SiH4; silane; CAS-No.: 7803-62-5 | |||
| G. Cooper, T. Ibuki, C.E. Brion | Chem. Phys. 140, 147-155, (1990) | Absolute oscillator-strengths for photoabsorption, photoionization and ionic photofragmentation of silane . II. The Si 2p and 2s inner shells |
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| G. Cooper, T. Ibuki, C.E. Brion | Chem. Phys. 140, 133-145, (1990) | Absolute oscillator-strengths for photoabsorption, photoionization and ionic photofragmentation of silane. I. The valence shell |
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| G. Cooper, T. Ibuki, C.E. Brion | Chem. Phys. 196, 293-306, (1995) | Absolute oscillator-strengths for the photoabsorption of silane in the valence and Si 2p and 2s regions (7.5-350 eV) |
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| Si(CH3)4; tetramethylsilane; CAS-No.: 75-76-3 | |||
| A.C.A. Souza, S.K. Srivastava | J. Braz. Chem. Soc., 5 (2), 59-65, (1994) | Photoabsorption cross sections of Ar, N2 and Si(CH3)4 derived from electron energy loss spectroscopy |
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| C2H3Cl3Si; trichlorovinylsilane; CAS-No.: 75-94-5 | |||
| J.D. DeSain, L.E. Jusinski, C.A. Taatjes | Phys. Chem. Chem. Phys., 8, 2240-2248, (2006) | Ultraviolet photochemistry of trichlorovinylsilane and allyltrichlorosilane: vinyl radical (HCCH2) and allyl radical (H2CCHCH2) production in 193 nm photolysis |
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| C3H5Cl3Si; allyltrichlorosilane; CAS-No.: 107-37-9 | |||
| J.D. DeSain, L.E. Jusinski, C.A. Taatjes | Phys. Chem. Chem. Phys., 8, 2240-2248, (2006) | Ultraviolet photochemistry of trichlorovinylsilane and allyltrichlorosilane: vinyl radical (HCCH2) and allyl radical (H2CCHCH2) production in 193 nm photolysis |
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| UF5; uranium pentafluoride | |||
| K.C. Kim, G.A. Laguna | Chem. Phys. Lett., 82, 292-295, (1981) | The absorption spectrum of laser-produced UF5 molecules in the 350–700 nm region |
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| UF6; uranium hexafluoride | |||
| S.K. Srivastava, S. Trajmar, A. Chutjian, W.X. Williams, D.C. Cartwright | J. Chem. Phys., 65, 208-211, (1976) | Photoabsorption spectrum of UF6 by electron impact |
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| As4; arsenic tetramer; CAS-No.: 12187-08-5 | |||
| K.P. Killeen | J. Appl. Phys., 73, 2596, (1993) | Ultraviolet absorption and photodissociation of As4 |
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| C4H8O2; 1,3-dioxane; CAS-No.: 505-22-6 | |||
| H.-P. Schuchmann, C. von Sonntag | Can. J. Chem., 63, 1833-1839, (1985) | Vacuum-ultraviolet photolysis (185 nm) of liquid 1,3-dioxan |
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