science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: triphenylbismuth				Other Names: triphenylbismuthane

Formula: C18H15Bi					CAS-No.: 603-33-8	PubChem: CID 11774

Study: uv absorption spectra

                
Authors: H.H. Jaffe

Title: Conjugation of Several Phenyl Radicals Bonded to a Single Central Atom

Journal/Source: J. Chem. Phys., 22, 1430-1433, (1954); http://dx.doi.org/10.1063/1.1740411 


Data: diagram, table

Energy/Wavelength range: 220 - 300 nm

Resolution: 

Temperature: 298 K

Temperature dependence: no

Pressure/Concentration:

Phase: solution (95% ethanol)

pH:


Comments: Spectroscopic evidence is used to show that phenyl radicals are only weakly conjugated with central atoms (S, P, As, Sb, Si, Sn, Pb) not having unshared valence electrons.

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