science-softCon UV/Vis+ Spectra Data Base (UV/Vis+ Photochemistry Database)

Literature Service: Organic Carbonyl Compounds/Aldehydes/Ketones/Amides and related radicals

Substances:  

HCO, CH2O, HCDO, CD2O, CH3CO, CH3CHO, HOCH2CHO, C2H5CHO, C3H7CHO, C4H9CHO, C5H11CHO, C6H6O2, C6H10O, C6H13CHO, CH2CHCHO, CH3CH2CCHO, CH3CH=CHCHO, (CH3)2CHCHO, (CH3)2CHCH2CHO, CH3CH=C(CH3)CHO, C3H8O, (CH3)3CCHO, CH3COCH3, CD3C(O)CD3, CH3C(O)CH2Cl, CH3COCHO, CH3COC2H5, C2H5COC2H5, ((CH3)2CH)2C(O), CH3C(O)CH2CH(CH3)2, CH3C(O)(CH)2CH(CH3)2, CHOCHO, CH2C(CH3)CHO, CH3C(O)CH2OH, CH3COCHCH2, (CH3)2NC(O)CH3, C6H10O, C3H4O2, C4H6O2, C5H8O2, CH2CO, C10H16O2

The relevant Spectra Data are available (for registered users) at: Spectra Service. Please use your browser capabilities to search this site!

Please note: In addition, information concerning related publications (e.g. quantum yield studies or photolysis studies) for some of the substances are given. Send us your feedback

Authors Journal/Source Title/Paper

Data Sheet

HCO; formyl radical; CAS-No.: 2597-44-6
G. Herzberg, D.A. Ramsey Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, Volume 233, Issue 1192, pp. 34-54 The 7500 to 4500 Angstrom Absorption System of the Free HCO Radical

C.J. Hochanadel, T.J. Sworski, P.J. Ogren J. Phys. Chem., 84(3), 231-235, (1980) Ultraviolet Spectrum and Reaction Kinetics of the Formyl Radical

J.E. Baggott, H.M. Frey, P.D. Lightfoot, R. Walsh Chem. Phys. Lett., 132, 225-230, (1986) The absorption cross section of the HCO radical at 614.59 nm and the rate constant for HCO + HCO --> H2CO + CO

Yongxin Tang, Lei Zhu J. Phys. Chem. A, 108 (40), 8307-8316, (2004) Wavelength-Dependent Photolysis of n-Hexanal and n-Heptanal in the 280-330-nm Region

L.N. Krasnoperov, E.N. Chesnokov, H. Stark, A.R. Ravishankara Proceedings of the Combustion Institute, 30, 935-943, (2005) Elementary reactions of formyl (HCO) radical studied by laser photolysis-transient absorption spectroscopy

J. E. Flad, S. S. Brown, J. B. Burkholder, H. Stark, A. R. Ravishankara Phys. Chem. Chem. Phys., 8, 3636 - 3642, (2006) Absorption cross sections for the A2A" (0,90,0) <-- X2A' (0,01,0) band of the HCO radical

V. A. Shubert, S. T. Pratt J. Phys. Chem. A, Article ASAP, (2010) Photodissociation of Acetaldehyde and the Absolute Photoionization Cross Section of HCO

Additional HCO spectra and datasheets are available via our Spectra Service
CH2O; formaldehyde; CAS-No.: 50-00-0
R.D. McQuigg, J.G. Calvert J. Am. Chem. Soc., 91, 1590- 1599, (1969) The Photodecomposition of CH2O, CD2O, CHDO, and CH2O-CD2O mixtures at xenon flash lamp intensities

J.E. Mentall, E.P. Gentieu, M. Krauss, D. Neumann J. Chem. Phys., 55, 5471, (1971) Photoionization and Absorption Spectrum of Formaldehyde in the Vacuum Ultraviolet

S. Glicker, L.J. Stief J. Chem. Phys., 54, 2852-2857, (1971) Photolysis of Formaldehyde at 1470 and 1236 A

J.G. Calvert, J.A. Kerr, K.L. Demerjan, R.D. McQuigg Science, 175, 751-752, (1972) Photolysis of Formaldehyd as a Hydrogen Atom Source in the Lower Stratosphere 

H.P. Sperling, S. Toby Can. J. Chem./Rev. can. chim. 51(4): 471-475, (1973) The Photochemical Decomposition of Gaseous Formaldehyde

G.K. Moortgat priv. comm., (1980) MPI Mainz, 1980

A.M. Bass priv. comm., (1980) (295 K)

A.M. Bass, L.C. Glasgow, C. Miller, J.P. Jesson, D.L. Filkin Planet. Space Sci., 28, 675-679, (1980) Temperature Dependent Absortion Cross Sections for Formaldehyde (CH2O): The Effect of Formaldehyde on Stratospheric Chlorine Chemistry (223 K)

A.M. Bass, L.C. Glasgow, C. Miller, J.P. Jesson, D.L. Filkin Planet. Space Sci., 28, 675-679, (1980) Temperature Dependent Absortion Cross Sections for Formaldehyde (CH2O): The Effect of Formaldehyde on Stratospheric Chlorine Chemistry (296 K)

P. Brint, J.-P. Connerade, C. Mayhew, K. Sommer J. Chem. Soc., Faraday Trans., 2, 81, 1643-1652, (1985) The vacuum ultraviolet absorption spectrum of formaldehyde

G.K. Moortgat, W. Schneider J. Phys. Chem. Ref. Data, 18, 1014, (1989) (285 K)

C.A. Cantrell, J.A. Davidson, A.H. McDaniel, R.E. Shetter, J.G. Calvert J. Phys. Chem., 94, 3902-3908, (1990) Temperature-Dependent Formaldehyde Cross Sections in the Near-Ultraviolet Spectral Region

C.A. Cantrell, J.A. Davidson, A.H. McDaniel, R.E. Shetter, J.G. Calvert J. Phys. Chem., 94, 3902-3908, (1990) Temperature-Dependent Formaldehyde Cross Sections in the Near-Ultraviolet Spectral Region 

J.D. Rogers J. Phys. Chem., 94, 4011-4015, (1990) Ultraviolet Absorption Cross Sections and Atmospheric Photodissociation Rate Constants of Formaldehyde

R. Meller priv. comm., (1992) MPI Mainz, 1992 (297 K)

G. Cooper, J. E. Anderson, C. E. Brion Chem. Phys., 209, 61-77, (1996) Absolute photoabsorption and photoionization of formaldehyde in the VUV and soft X-ray regions (3–200 eV)

M. W. Mackey, J. W. Daily, J. T. McKinnon, E. P. Riedel J. Photochem. Photobiol. A: Chemistry, 105, 1-6, (1997) High-temperature UV-visible absorption spectral measurements and estimated primary photodissociation rates of formaldehyde, chlorobenzene and 1-chloronaphthalene 

H. Barry, L. Corner, G. Hancock, R. Peverall, G.A.D. Ritchie Phys. Chem. Chem. Phys., 4, 445 - 450, (2002) Cross sections in the ny5 band of formaldehyde studied by cavity enhanced absorption spectroscopy near 1.76 micrometer

G. Friedrichs, D.F. Davidson, R.K. Hanson Int. J. Chem. Kinet., 34, 374-386, (2002) Direct measurements of the reaction H + CH2O --> H2 + HCO behind shock waves by means of vis-uv detection of formaldehyde

Y. Chen, L. Zhu J. Phys. Chem. A, 107, 4643-4651, (2003) Wavelength-dependent photolysis of glyoxal in the 290-420 nm region; (298 K)

Bai X., T. Metz, F. Ossler, M. Alden Spectrochimica Acta, Part A 60, 821-828, (2004) Absorption of formaldehyde (H2CO) in the A1A2<--X1A1 band system at elevated temperatures and pressures

M. Staak, E. W. Gash, D. S. Venables, A. A. Ruth J. Molecular Spectroscopy, 229, 115-121, (2005) The rotationally-resolved absorption spectrum of formaldehyde from 6547 to 6804 cm-1

F. D. Pope, C. A. Smith, P. R. Davis, D. E. Shallcross, M. N. R. Ashfold, A. J. Orr-Ewing Faraday Discuss., 130, 59-72, (2005) Photochemistry of formaldehyde under tropospheric conditions

F. D. Pope, C. A. Smith, M. N. R. Ashfold, A. J. Orr-Ewing Phys. Chem. Chem. Phys., 7, 79 - 84, (2005) High-resolution absorption cross sections of formaldehyde at wavelengths from 313 to 320 nm

D. T. Co, T. F. Hanisco, J. G. Anderson, F. N. Keutsch J. Phys. Chem. A, 109 (47), 10675 -10682, (2005) Rotationally Resolved Absorption Cross Sections of Formaldehyde in the 28100-28500 cm-1 (351-356 nm) Spectral Region: Implications for in Situ LIF Measurements 

C. A. Smith, F. D. Pope, B. Cronin, C. B. Parkes, A. J. Orr-Ewing J. Phys. Chem. A, 110 (41), 11645 -11653, (2006) Absorption Cross Sections of Formaldehyde at Wavelengths from 300 to 340 nm at 294 and 245 K

Weixiong Zhao, Xiaoming Gao, Lunhua Deng, Teng Huang, Tao Wu, Weijun Zhang JQSRT, 107, 331-339, (2007) Absorption spectroscopy of formaldehyde at 1.573. micrometer

A. Gratien, B. Picquet-Varrault, J. Orphal, E. Perraudin, J.-F. Doussin, J.-M. Flaud J. Geophys. Res., 112, D05305, (2007) Laboratory intercomparison of the formaldehyde absorption cross sections in the infrared (1660–1820 cm-1) and ultraviolet (300–360 nm) spectral regions

A. Gratien, E. Nilsson, J.-F. Doussin, M. S. Johnson, C. J. Nielsen, Y. Stenstrom, B. Picquet-Varrault J. Phys. Chem. A, 111 (45), 11506 -11513, (2007) UV and IR Absorption Cross-sections of HCHO, HCDO, and DCDO

T. Brauers, J. Bossmeyer, H.-P. Dorn, E. Schlosser, R. Tillmann, R. Wegener, A. Wahner Atmos. Chem. Phys., 7, 3579-3586, (2007) Investigation of the formaldehyde differential absorption cross section at high and low spectral resolution in the simulation chamber SAPHIR

P. G. Carbajo, S. C. Smith, A.-L. Holloway, C. A. Smith, F. D. Pope, D. E. Shallcross, A. J. Orr-Ewing J. Phys. Chem. A, 112 (48), 12437-12448, (2008) Ultraviolet Photolysis of HCHO: Absolute HCO Quantum Yields by Direct Detection of the HCO Radical Photoproduct

M. B. Crow, A. Gilchrist, G. Hancock, R. Peverall, G. Richmond, G. A. D. Ritchie, S. R. Taylor J. Phys. Chem. A, 113 (24), 6689-6696, (2009) High-Resolution Absorption Studies of the 1A2 - 1A1 202401 Band of Formaldehyde

related data (quantum yield studies; photolysis studies, etc.)
K.B. Harvey, J.F. Ogilvie Can. J. Chem., 40, 85-91, (1962) Infrared absorption of formaldehyde at low temperatures, evidence for multiple trapping sites in an argon matrix

M. Venugopalan, K.O. Kutschke Can. J. Chemistry, 42, 2451-2455, (1964) The photolysis of formaldehyde, formaldehyde-d2, and their mixtures

A. Horowitz, J.G. Calvert Int. J. Chem. Kinetics, 10, 805-819, (1978) Wavelength dependence of the quantum efficiencies of the primary processes in formaldehyde photolysis at 25°C

J. H. Clark, C. B. Moore, N. S. Nogar J. Chem. Phys., 68, 1264-1272, (1978) The photochemistry of formaldehyde: Absolute quantum yields, radical reactions, and NO reactions

G. K. Moortgat, F. Slemr, W. Seiler, P. Warneck Chem. Phys. Lett., 54, 444-447, (1978) Photolysis of formaldehyde: Relative quantum yields of H2 and CO in the wavelength range 270–360 nm

G.K. Moortgat, P. Warneck J. Chem. Phys., 70, 3639-3651, (1979) CO and H2 quantum yields in the photodecomposition of formaldehyde in air

K.Y. Tang, P.W. Fairchild, E.K.C. Lee J. Phys. Chem., 83, 569-573, (1979) Laser-induced photodecomposition of formaldehyde (~A1A2) from its single vibronic levels. Determination of the quantum yield of H-atom by HNO (~A1A'') chemiluminescence

G.K. Moortgat, W. Seiler, P. Warneck J. Chem. Phys., 78, 1185-1190, (1983) Photodissociation of HCHO in air: CO and H2 quantum yields at 220 and 300 K

N. I. Sorokin, G. I. Skubnevskaya, N. M. Bazhin Theoretical and Experimental Chemistry, 18 (4), 410-416, (1983) Gas-phase photolysis of formaldehyde in the region of molecular dissociation

J. Desai, J. Heicklen J. Photochemistry, 40, 23-29, (1987) The wavelength dependence of the photo-oxidation of CH2O

G. D. Smith, L. T. Molina, M. J. Molina J. Phys. Chem. A, 106 (7), 1233-1240, (2002) Measurement of Radical Quantum Yields from Formaldehyde Photolysis between 269 and 339 nm

Additional formaldehyde spectra and datasheets are available via our Spectra Service
HCDO; formaldehyde-d; CAS-No.: 1664-99-9
A. Gratien, E. Nilsson, J.-F. Doussin, M. S. Johnson, C. J. Nielsen, Y. Stenstrom, B. Picquet-Varrault J. Phys. Chem. A, 111 (45), 11506 -11513, (2007) UV and IR Absorption Cross-sections of HCHO, HCDO, and DCDO

CD2O; formaldehyde-2d; CAS-No.: 1664-98-8
A. Gratien, E. Nilsson, J.-F. Doussin, M. S. Johnson, C. J. Nielsen, Y. Stenstrom, B. Picquet-Varrault J. Phys. Chem. A, 111 (45), 11506 -11513, (2007) UV and IR Absorption Cross-sections of HCHO, HCDO, and DCDO

related data (quantum yield studies; photolysis studies, etc.)
J. H. Clark, C. B. Moore, N. S. Nogar J. Chem. Phys., 68, 1264-1272, (1978) The photochemistry of formaldehyde: Absolute quantum yields, radical reactions, and NO reactions

CH3CO; acetyl radical; CAS-No.: 3170-69-2
D.A. Parkes Chem. Phys. Lett., 77, 527-532, (1981) The ultraviolet absorption spectra of the acetyl radical and the kinetics of the CH3 + CO reaction at room temperature

M.M. Maricq, J.J. Szente Chem. Phys. Lett., 253, 333-339, (1996) The UV spectrum of acetyl and the kinetics of the chain reaction between acetaldehyde and chlorine

M. Cameron, V. Sivakumaran, T. J. Dillon, J. N. Crowley Phys. Chem. Chem. Phys., 4, 3628 - 3638, (2002) Reaction between OH and CH3CHO Part 1. Primary product yields of CH3(296 K), CH3CO (296 K), and H (237-296 K)

B. Rajakumar, J. E. Flad, T. Gierczak, A. R. Ravishankara, J. B. Burkholder J. Phys. Chem. A, 111 (37), 8950-8958, (2007) Visible Absorption Spectrum of the CH3CO Radical

CH3CHO; acetaldehyde; CAS-No.: 75-07-0
J.W. Ellis J. Am. Chem. Soc., 51, 1384-1394, (1929) The near infrared absorption spectra of some aldehydes, ketones, esters and ethers

A.D. Walsh Proceedings of the Royal Society of London. A, Math. Phys. Sci.,185, 176-182, (1946) The absorption spectrum of acetaldehyde in the vacuum ultra-violet

J.S. Lake, A.J. Harrison J. Chem. Phys., 30, 361, (1959) Absorption of acyclic oxygen compounds in the vacuum ultraviolet. III. Acetone and acetaldehyde

V. McMillan John Wiley & Sons, London, p. 368, (1966) Calvert and Pitts, Photochemistry 

G. Lucazeau, C. Sandorfy J. Mol. Spectroscopy, 35, 214-231, (1970) On the far-ultraviolet spectra of some simple aldehydes

J. Weaver, J. Meagher, J. Heicklen J. Photochemistry, 6, 111-126, (1976-1977) Photo-oxidation of CH3CHO vapor at 3130 Ĺ

H. Meyrahn PhD-Thesis, (1984) University of Mainz, Germany, (298 K)

M. Noble, K.C. Lee J. Chem. Phys., 81, 1632-1642, (1984) The jet-cooled electronic spectrum of acetaldehyde and deuterated derivatives at rotational resolution

W. Schneider, G.K. Moortgat priv. comm., (1989) MPI Mainz, (294 K)

P. Brint, L. O'Toole, C. A. Mayhew, W. Dussa J. Chem. Soc., Faraday Trans., 86, 3349 - 3354, (1990) Vacuum-ultraviolet absorption spectrum of acetaldehyde, CH3CHO, and the related deuterides CH3CDO and CD3CDO

H.G. Libuda Uni Wuppertal, Germany, (1992) Spektroskopische und kinetische Untersuchungen an halogenierten Carbonylverbindungen von atmosphaerischem Interesse, Ph-D-Thesis 

R. D. Martinez, A. A. Buitrago, N. W. Howell, C. H. Hearn, J. A. Joens Atmos. Env. A, 26, 785-792, (1992) The near U.V. absorption spectra of several aliphatic aldehydes and ketones at 300 K

Huan Xu, Pamela J. Wentworth, Noel W. Howell, Jeffrey A. Joens Spectrochimica Acta Part A: Molecular Spectroscopy, 49, 1171-1178, (1993) Temperature dependent near-UV molar absorptivities of aliphatic aldehydes and ketones in aqueous solution

P. Limao-Vieira, S. Eden, N.J. Mason, S.V. Hoffmann Chem. Phys. Lett., 376, 737-747, (2003) Electronic state spectroscopy of acetaldehyde, CH3CHO, by high-resolution VUV photo-absorption

Y. Hashikawa, M. Kawasaki, R.L. Waterland, M.D. Hurley, J.C. Ball, T.J. Wallington, M.P. Sulbaek Andersen, O.J. Nielsen Journal of Fluorine Chemistry, 125,1925–1932, (2004) Gas phase UV and IR absorption spectra of CxF2x+1CHO (x = 1–4)

related data (quantum yield studies; photolysis studies, etc.)
F. Daniels Third Report of the Committee on Photochemistry: Reprint and Circular Series of the National Research Council,Committee on Photochemistry; ISBN: 0-309-55909-X, pp 15-34, (1938) A table of quantum yields in experimental photochemistry

Yongxin Tang, Lei Zhu, Liang T. Chu, Bin Xiang Chem. Phys., 330, 155-165, (2006) Cavity ring-down spectroscopic study of acetaldehyde photolysis in the gas phase, on aluminum surfaces, and on ice films

HOCH2CHO; glycolaldehyde; acetaldehyde, hydroxy-; CAS-No.: 141-46-8
C. Bacher, G.S. Tyndall, J.J. Orlando J. Atmos. Chem., 39, 171-189, (2001) The atmosperic chemistry of glycolaldehyde

I. Magneron, A. Mellouki, G. Le Bras, G. K. Moortgat, A. Horowitz, K. Wirtz J. Phys. Chem. A, 109 (20), 4552-4561, (2005) Photolysis and OH-Initiated Oxidation of Glycolaldehyde under Atmospheric Conditions

R. Karunanandan, D. Hölscher, T. J. Dillon, A. Horowitz, J. N. Crowley J. Phys. Chem. A, 111 (5), 897-908, (2007) Reaction of HO with Glycolaldehyde, HOCH2CHO: Rate Coefficients (240-362 K) and Mechanism

C. Zhu, L. Zhu J. Phys. Chem. A, 114 (32), 8384-8390, (2010) Photolysis of Glycolaldehyde in the 280-340 nm Region

C2H5CHO; propionaldehyde; propanal; CAS-No.: 123-38-6
J.W. Ellis J. Am. Chem. Soc., 51, 1384-1394, (1929) The near infrared absorption spectra of some aldehydes, ketones, esters and ethers

F.E. Blacet, R.A. Crane J. Am. Chem. Soc., 76(21), 5337-5340, (1954) The Photolysis of the Aliphatic Aldehydes. XVII. Propionaldehyde, n-Butyraldehyde and Isobutyraldehyde at 2380 and 1870 A

V.  McMillan John Wiley & Sons, London, p. 368, (1966) Calvert and Pitts, Photochemistry

R. D. Martinez, A. A. Buitrago, N. W. Howell, C. H. Hearn, J. A. Joens Atmos. Env. A, 26, 785-792, (1992) The near U.V. absorption spectra of several aliphatic aldehydes and ketones at 300 K

H. Xu, P. J. Wentworth, N. W. Howell, J. A. Joens Spectrochimica Acta Part A: Molecular Spectroscopy, 49, 1171-1178, (1993) Temperature dependent near-UV molar absorptivities of aliphatic aldehydes and ketones in aqueous solution

N. C. Shand, C.-L. Ning, M.R.F. Siggel, I.C. Walker, J. Pfab J. Chem. Soc., Faraday T rans., 93(16), 2883-2888, (1997) One- and two-photon spectroscopy of the 3s <-- n Rydberg transition of propionaldehyde (propanal)

Y. Chen, L. Zhu J. Phys. Chem. A, 105, 9689-9696, (2001) The Wavelength dependence of the photodissociation of propionaldehyde in the 280-330 nm region

related data (quantum yield studies; photolysis studies, etc.)
J. Heicklen, J. Desai, A. Bahta, C. Harper, R. Simonaitis J. Photochem., 34, 117-135, (1986) The temperature and wavelength dependence of the photo-oxidation of propionaldehyde

C3H7CHO; n-butyraldehyde; n-butanal; CAS-No.: 123-72-8
J.W. Ellis J. Am. Chem. Soc., 51, 1384-1394, (1929) The near infrared absorption spectra of some aldehydes, ketones, esters and ethers

F.E. Blacet, R.A. Crane J. Am. Chem. Soc., 76, 5337-5340, (1954) The photolysis ot the aliphatic aldehydes. XVII. Propionaldehyde, n-butyraldehyde, and isobutyraldehyde at 2380 and 1870 A

R. P. Borkowski, P. Ausloos J. Am. Chem. Soc., 84, 4044-4048, (1962) The vapor phase fluorescence and its relationship to the photolysis of propionaldehyde and the butyraldehydes

R.D. Martinez, A. A. Buitrago, N.W. Howell, C.H. Hearn, J.A. Joens Atmospheric Environment A, 26, 785-792, (1992) The near U.V. absorption spectra of several aliphatic aldehydes and ketones at 300 K

Huan Xu, Pamela J. Wentworth, Noel W. Howell, Jeffrey A. Joens Spectrochimica Acta Part A: Molecular Spectroscopy, 49, 1171-1178, (1993) Temperature dependent near-UV molar absorptivities of aliphatic aldehydes and ketones in aqueous solution

J. Tadic, I. Juranic, G.K. Moortgat J. Photochem. Photobiol. A: Chemistry, 143, 169-179, (2001) Pressure dependence of the photooxidation of selected carbonyl compounds in air: n-butanal and n-pentanal

Y. Chen, L. Zhu, J.S. Francisco J. Phys. Chem. A, 106, 7755-7763, (2002) Wavelength-dependent photolysis of n-butyraldehyde and i-butyraldehyde in the 280-330 nm region

C4H9CHO; n-pentanal; n-valeraldehyde; CAS-No.: 110-62-3
Y.Y. Sham, J.A. Joens Spectrochimica Acta, 51A, 247-251, (1995) Temperature dependent near UV molar absorptivities of several small aldehydes in aqueous solution

T. Cronin, L. Zhu J. Phys. Chem. A, 102, 10274-10279, (1998) Dye laser photolysis of n-pentanal from 280 to 330 nm

J. Tadic, I. Juranic, G.K. Moortgat J. Photochem. Photobiol. A: Chemistry, 143, 169-179, (2001) Pressure dependence of the photooxidation of selected carbonyl compounds in air: n-butanal and n-pentanal

C5H11CHO; hexanal; hexanaldehyde; CAS-No.: 66-25-1
Y.Y. Sham, J.A. Joens Spectrochimica Acta, 51A, 247-251, (1995) Temperature dependent near UV molar absorptivities of several small aldehydes in aqueous solution

H. Plagens Ph-D Thesis, University of Wuppertal, Germany, (2001) Untersuchung zum atmosphärenchemischen Abbau langkettiger Aldehyde

Yongxin Tang, Lei Zhu J. Phys. Chem. A, 108 (40), 8307 -8316, (2004) Wavelength-Dependent Photolysis of n-Hexanal and n-Heptanal in the 280-330-nm Region

M.P. O'Connor, J.C. Wenger, A. Mellouki, K. Wirtz, A. Munoz Phys. Chem. Chem. Phys., 8, 5236-5246, (2006) The atmospheric photolysis of E-2-hexenal, Z-3-hexenal and E,E-2,4-hexadienal

E. Jimenez, B. Lanza, E. Martinez, J. Albaladejo Atmos. Chem. Phys., 7, 1565–1574, (2007) Daytime tropospheric loss of hexanal and trans-2-hexenal: OH kinetics and UV photolysis

related data (quantum yield studies; photolysis studies, etc.)
J. Tadic, I. Juranic, G. K. Moortgat Molecules, 6, 287-299, (2001) Photooxidation of n-Hexanal in Air

C6H10O; trans-2-hexenal, CAS-No.: 6728-26-3
E. Jimenez, B. Lanza, E. Martinez, J. Albaladejo Atmos. Chem. Phys., 7, 1565–1574, (2007) Daytime tropospheric loss of hexanal and trans-2-hexenal: OH kinetics and UV photolysis

C6H13CHO; heptanal; heptaldehyde; CAS-No.:111-71-7
H. Plagens Ph-D Thesis, University of Wuppertal, Germany, (2001) Untersuchung zum atmosphärenchemischen Abbau langkettiger Aldehyde

Yongxin Tang, Lei Zhu J. Phys. Chem. A, 108 (40), 8307 -8316, (2004) Wavelength-Dependent Photolysis of n-Hexanal and n-Heptanal in the 280-330-nm Region

CH2CHCHO; acrolein; 2-propenal; CAS-No.: 107-02-8
A.D. Walsh Trans. Faraday Soc., 41, 498 - 505, (1945) The absorption spectra of acrolein, crotonaldehyde and mesityl oxide in the vacuum ultra-violet

Y.Y. Sham, J.A. Joens Spectrochimica Acta, 51A, 247-251, (1995) Temperature dependent near UV molar absorptivities of several small aldehydes in aqueous solution

I. Magneron, R. Thévenet, A. Mellouki, G. Le Bras, G.K. Moortgat, K. Wirtz J. Phys. Chem. A, 106 (11), 2526 -2537, (2002) A Study of the Photolysis and OH-initiated Oxidation of Acrolein and trans-Crotonaldehyde

A.M.D. Lee, J.D. Coe, S. Ullrich, M.-L. Ho, S.-J. Lee, B.-M. Cheng, M.Z. Zgierski, I.-C. Chen, T.J. Martinez, A. Stolow J. Phys. Chem. A, 111 (47), 11948 -11960, (2007) Substituent Effects on Dynamics at Conical Intersections: alpha, beta-Enones 

related data (quantum yield studies; photolysis studies, etc.)
B.-M. Haas, T.K. Minton, P. Felder, J.R. Huber J. Phys. Chem., 95, 5149-5159, (1991) Photodissociation of acrolein and propynal at 193 nm in a molecular beam. Primary and secondary reactions

CH3CH2CCHO; methacrolein; 2-methyl-2-propenal; CAS-No.: 78-85-3
A.M.D. Lee, J.D. Coe, S. Ullrich, M.-L. Ho, S.-J. Lee, B.-M. Cheng, M.Z. Zgierski, I.-C. Chen, T.J. Martinez, A. Stolow J. Phys. Chem. A, 111 (47), 11948 -11960, (2007) Substituent Effects on Dynamics at Conical Intersections: alpha, beta-Enones 

CH3CH=CHCHO; crotonaldehyde; CAS-No.: 123-73-9
A.M.D. Lee, J.D. Coe, S. Ullrich, M.-L. Ho, S.-J. Lee, B.-M. Cheng, M.Z. Zgierski, I.-C. Chen, T.J. Martinez, A. Stolow J. Phys. Chem. A, 111 (47), 11948 -11960, (2007) Substituent Effects on Dynamics at Conical Intersections: alpha, beta-Enones 

(CH3)2CHCHO; i-butyraldehyde; CAS-No.: 78-84-2
Y.Y. Sham, J.A. Joens Spectrochimica Acta, 51A, 247-251, (1995) Temperature dependent near UV molar absorptivities of several small aldehydes in aqueous solution

Y. Chen, L. Zhu, J.S. Francisco J. Phys. Chem. A, 106, 7755-7763, (2002) Wavelength-dependent photolysis of n-butyraldehyde and i-butyraldehyde in the 280-330 nm region

(CH3)2CHCH2CHO; i-pentanal; 3-methylbutanal; CAS-No.: 590-86-3
L. Zhu, T. Cronin, A. Narang J. Phys. Chem. A, 103, 7248-7253, (1999) Wavelength-dependent photolysis of i-pentanal and t-pentanal from 280-330 nm region

B. Lanza, E. Jimenez, B. Ballesteros, J. Albaladejo Chemical Physics Letters, 454, 184–189, (2008) Absorption cross section determination of biogenic C5-aldehydes in the actinic region

(CH3)3CCHO; t-pentanal; 2,2-dimethylpropanal; CAS-No.: 630-19-3
L. Zhu, T. Cronin, A. Narang J. Phys. Chem. A, 103, 7248-7253, (1999) Wavelength-dependent photolysis of i-pentanal and t-pentanal from 280-330 nm region

CH3CH=C(CH3)CHO; trans-2-methyl-2-butenal; CAS-No.: 497-03-0
B. Lanza, E. Jimenez, B. Ballesteros, J. Albaladejo Chemical Physics Letters, 454, 184–189, (2008) Absorption cross section determination of biogenic C5-aldehydes in the actinic region

C5H8O; 3-methyl-2-butenal; CAS-No.: 107-86-8
B. Lanza, E. Jimenez, B. Ballesteros, J. Albaladejo Chemical Physics Letters, 454, 184–189, (2008) Absorption cross section determination of biogenic C5-aldehydes in the actinic region

C6H6O2; HCOCH=CHCH=CHCHO(E,E); E,E-2,4-hexadienedial; (E,E)-muconaldehyde; CAS-No.: 18409-46-6
B. Xiang, L. Zhu Chem. Phys. Lett., 450, 31-38, (2007) Absorption cross sections of E,E-2,4-hexadienedial at 248 nm, and in the 290–430 nm region, and photolysis study at 248, 308, and 351 nm

CH3COCHO; methylglyoxal; pyruvaldehyde; CAS-No.: 78-98-8
E. Kyle, S.W. Orchard J. Photochem., 7, 305-317, (1977) The photolysis of methyl glyoxal vapour at 436 nm

C.N. Plum, R. Atkinson, W.P.L. Carter, J.N. Pitts, Jr. Environm. Sci. Technol., 17, 479-484, (1983) OH Radical Rate Constants and Photolysis Rates of a-Dicarbonyls 

R. Meller, W. Raber, J.N. Crowley, M.E. Jenkin, G.K. Moortgat J. Photochem. Photobiol., 62, 163-171, (1991) The UV-Visible Absorption Spectrum of Methylglyoxal

R. Meller, W. Raber, J.N. Crowley, M.E. Jenkin, G.K. Moortgat J. Photochem. Photobiol., 62, 163-171, (1991) The UV-Visible Absorption Spectrum of Methylglyoxal 

T.A. Staffelbach, J.J. Orlando, G.S. Tyndall, J.G. Calvert J. Geophys. Res., 100, 14189-14198, (1995) The UV-Visible Absorption Spectrum and Photolysis Quantum Yields of Methylglyoxal 

Y. Chen, L. Zhu J. Phys. Chem. A, 104, 11126-11131, (2000) Wavelength-dependent photolysis of methylglyoxal in the 290-440 nm region

CH3C(O)CH3; acetone; dimethyl ketone; propanone; CAS-No.: 67-64-1
W. A. Noyes Jr., G. B. Porter, J. E. Jolley Chem. Rev., 56 (1), 49-94, (1956) The Primary Photochemical Process In Simple Ketones

J.S. Lake, A.J. Harrison J. Chem. Phys., 30, 361-362, (1959) Absorption of acyclic oxygen compounds in the vacuum ultraviolet. III. Acetone and acetaldehyde

V. McMillan John Wiley & Sons, London, p. 377, (1966) Calvert and Pitts, Photochemistry 

I. S. Pominov, A. A. Navlova J. Applied Spectroscopy, 9 (1), 700-702, (1968) Effect of temperature and salts on the UV absorption spectra of acetone and methylethylketone

H. Meyrahn, J. Pauly, W Schneider, P. Warneck J. Atmos. Chem., 4, 277-291, (1986) Quantum Yields for the Photodissociation of Acetone in Air and an Estimate for the Life Time of Acetone in the Lower Troposphere

W. Schneider, G.K. Moortgat priv. comm., (1987) MPI Mainz, 1987 

W. Braun, R. Klein, A. Fahr, H. Okabe, A. Mele Chem. Phys. Lett., 166, 397-403, (1990) Laser photolysis of trimethylgallium at 193 nm: Quantum yields for methyl radical and ethane production

R. D. Martinez, A. A. Buitrago, N. W. Howell, C. H. Hearn, J. A. Joens Atmos. Environment, Part A, 26 (5), 785-792, (1992) The near U.V. absorption spectra of several aliphatic aldehydes and ketones at 300 K

Huan Xu, Pamela J. Wentworth, Noel W. Howell, Jeffrey A. Joens Spectrochimica Acta Part A: Molecular Spectroscopy, 49, 1171-1178, (1993) Temperature dependent near-UV molar absorptivities of aliphatic aldehydes and ketones in aqueous solution

M. Wollenhaupt, S.A. Carl, A. Horowitz, J.N. Crowley J. Phys. Chem. A, 104 (12), 2695 -2705, (2000) Rate Coefficients for Reaction of OH with Acetone between 202 and 395 K

M. Yujing, A. Mellouki J. Photochem. Photobiol. A: Chemistry, 134, 31-36, (2000) The near-UV absorption cross sections for several ketones

Chuji Wang, Susan T. Scherrer, Delwar Hossain Applied Spectroscopy, 58, Number 7, 784-791, (2004) Measurements of Cavity Ringdown Spectroscopy of Acetone in the Ultraviolet and Near-Infrared Spectral Regions: Potential for Development of a Breath Analyzer

V. Feigenbrugel, C. Loew, S. Le Calve, P. Mirabel J. Photochemistry and Photobiology A: Chemistry, 174, 76-81, (2005) Near-UV molar absorptivities of acetone, alachlor, metolachlor, diazinon and dichlorvos in aqueous solution

J. D. Koch, J. Gronki, R. K. Hanson Journal of Quantitative Spectroscopy and Radiative Transfer, 109, 2037-2044, (2008) Measurements of near-UV absorption spectra of acetone and 3-pentanone at high temperatures

M. Nobre, A. Fernandes, F. Ferreira da Silva, R. Antunes, D. Almeida, V. Kokhan, S. V. Hoffmann, N. J. Mason, S. Eden, P. Limăo-Vieira Phys. Chem. Chem. Phys., 10, 550 - 560, (2008) The VUV electronic spectroscopy of acetone studied by synchrotron radiation

related data (quantum yield studies; photolysis studies, etc.)
L. Ju-Te Lin, P. Ausloos J. Photochem., 1, 453-462, (1972-1973) Gas phase photolysis of acetone in the far ultra-violet 

A. Horowitz J. Phys. Chem., 95 (26), 10816-10823, (1991) Wavelength dependence of the primary photodissociation processes in acetone photolysis

T. Gierczak, J. B. Burkholder, S. Bauerle, A. R. Ravishankara Chem. Phys., 231, 229-244, (1998) Photochemistry of acetone under tropospheric conditions

M. Emrich, P. Warneck J. Phys. Chem. A, 104 (42), 9436 -9442, (2000) Photodissociation of Acetone in Air: Dependence on Pressure and Wavelength. Behavior of the Excited Singlet State

S. Aloisio, J. S. Francisco Chem. Phys. Lett., 329, 179-184, (2000) The photochemistry of acetone in the presence of water 

K. Takahashi, T. Nakayama,Y. Matsumi, Y. Osamura J. Phys. Chem. A, 108 (39), 8002 -8008, (2004) Hydrogen Atom Formation in the Photolysis of Acetone at 193 nm

M.A. Blitz, D.E. Heard, M.J. Pilling, S.R. Arnold, M. P. Chipperfield Geophys. Res. Lett., 31, (2004) Pressure and temperature-dependent quantum yields for the photodissociation of acetone between 279 and 327.5 nm

S.R. Arnold, M. P. Chipperfield, M.A. Blitz, D.E. Heard, M.J. Pilling Geophys. Res. Lett., 31, (2004) Photodissociation of acetone: Atmospheric implications of temperature-dependent quantum yields

H. Somnitz, M. Fida, T. Ufer, R. Zellner Phys. Chem. Chem. Phys., 7, 3342 - 3352, (2005) Pressure dependence for the CO quantum yield in the photolysis of acetone at 248 nm: A combined experimental and theoretical study

M.A. Blitz, D.E. Heard, M.J. Pilling J. Phys. Chem. A, 110 (21), 6742 -6756, (2006) Study of Acetone Photodissociation over the Wavelength Range 248-330 nm: Evidence of a Mechanism Involving Both the Singlet and Triplet Excited States

R. Nadasdi, G. Kovacs, I. Szilagyi, A. Demeter, S. Dobe, T. Berces, F. Marta Chem. Phys. Lett., 440, 31-35, (2007) Exciplex laser photolysis study of acetone with relevance to tropospheric chemistry

V. Khamaganov, R. Karunanandan, A. Rodriguez, J. N. Crowley Phys. Chem. Chem. Phys., 9, 4098-4113, (2007) Photolysis of CH3C(O)CH3 (248 nm, 266 nm), CH3C(O)C2H5 (248 nm) and CH3C(O)Br (248 nm): pressure dependent quantum yields of CH3 formation

B. Rajakumar, T. Gierczak, J. Flad, A.R. Ravishankara, J.B. Burkholder J. Photochem. Photobiol. A: Chem., 199, 336-344, (2008) The CH3CO quantum yield in the 248 nm photolysis of acetone, methyl ethyl ketone, and biacetyl

I. Szilágyi, G. Kovács, M. Farkas, G. L. Zügner, A. Gola, S. Dóbé, A. Demeter Reaction Kinetics and Catalysis Letters, 96 (2), 437-446, (2009) Photochemical and photophysical study on the kinetics of the atmospheric photodissociation of acetone

V. G. Khamaganov, R. Karunanandan, A. Horowitz, T. J. Dillon, J. N. Crowley Phys. Chem. Chem. Phys., 11, 6173 - 6181, (2009) Photolysis of CH3C(O)CH3 at 248 and 266 nm: pressure and temperature dependent overall quantum yields

Additional acetone spectra and datasheets are available via our Spectra Service
CD3C(O)CD3; acetone-d6; CAS-No.: 666-52-4
related data (quantum yield studies; photolysis studies, etc.)
I. Szilágyi, G. Kovács, M. Farkas, G. L. Zügner, A. Gola, S. Dóbé, A. Demeter Reaction Kinetics and Catalysis Letters, 96 (2), 437-446, (2009) Photochemical and photophysical study on the kinetics of the atmospheric photodissociation of acetone

CH3C(O)CH2Cl; chloroacetone; CAS-No.: 78-95-5
J.B. Burkholder, M.K. Gilles, T. Gierczak,  A.R. Ravishankara Geophys. Res. Lett. Vol. 29, No. 17, 1822, (2002) The atmospheric degradation of 1-bromopropane (CH3CH2CH2Br): The photochemistry of bromoacetone

CH3C(O)C2H5; 2-butanone; methyl ethyl ketone (MEK); CAS-No.: 78-93-3
V. McMillan Calvert and Pitts, Photochemistry, John Wiley & Sons, London, p. 377, (1966)  (298 K)

W. Schneider, G.K. Moortgat priv. comm., (1988) MPI Mainz, 1988 (294 K)

R.D. Martinez, A.A. Buitrago, N.W. Howell, C.H. Hearn, J.A. Joens Atmos. Environ. 26A, 785-792, (1992) The near UV absorption spectra of several aliphatic aldehydes and ketones

M. Yujing, A. Mellouki J. Photochem. Photobiol. A: Chemistry, 134, 31-36, (2000) The near-UV absorption cross sections for several ketones

related data (quantum yield studies; photolysis studies, etc.)
P. Ausloos, E.W.R. Steacie Can. J. Chem., 33, 1062-1068, (1955) The photolysis of methyl ethyl ketone

M. T. B. Romero, M. A. Blitz, D. E. Heard, M. J. Pilling, B. Price, P. W. Seakins, L. Wang Faraday Discuss., 130, 73 - 88, (2005) Photolysis of methylethyl, diethyl and methylvinyl ketones and their role in the atmospheric HOx budget

B. Rajakumar, T. Gierczak, J. Flad, A.R. Ravishankara, J.B. Burkholder J. Photochem. Photobiol. A: Chem., 199, 336-344, (2008) The CH3CO quantum yield in the 248 nm photolysis of acetone, methyl ethyl ketone, and biacetyl

C2H5COC2H5; 3-pentanone; diethyl ketone; CAS-No.: 96-22-0
J. D. Koch, R. K. Hanson Applied Physics B: Lasers and Optics, 76, 319-324, (2003) Temperature and excitation wavelength dependencies of 3-pentanone absorption and fluorescence for PLIF applications

J. D. Koch, J. Gronki, R. K. Hanson Journal of Quantitative Spectroscopy & Radiative Transfer, 109, 2037–2044, (2008) Measurements of near-UV absorption spectra of acetone and 3-pentanone at high temperatures

related data (quantum yield studies; photolysis studies, etc.)
M. T. B. Romero, M. A. Blitz, D. E. Heard, M. J. Pilling, B. Price, P. W. Seakins, L. Wang Faraday Discuss., 130, 73 - 88, (2005) Photolysis of methylethyl, diethyl and methylvinyl ketones and their role in the atmospheric HOx budget

((CH3)2CH)2C(O); 2,4-dimethyl-3-pentanone; CAS-No.: 565-80-0
M. Yujing, A. Mellouki J. Photochem. Photobiol. A: Chemistry, 134, 31-36, (2000) The near-UV absorption cross sections for several ketones

CH3C(O)CH2CH(CH3)2; 4-methyl-2-pentanone; hexone; CAS-No.: 108-10-1
M. Yujing, A. Mellouki J. Photochem. Photobiol. A: Chemistry, 134, 31-36, (2000) The near-UV absorption cross sections for several ketones

CH3C(O)(CH)2CH(CH3)2; 5-methyl-2-hexanone; MIAK; CAS-No.: 110-12-3
M. Yujing, A. Mellouki J. Photochem. Photobiol. A: Chemistry, 134, 31-36, (2000) The near-UV absorption cross sections for several ketones

CHOCHO; glyoxal; CAS-No.: 107-22-2
C.N. Plum, R. Atkinson, W.P.L. Carter, J.N. Pitts, Jr. Environm. Sci. Technol., 17, 479-484, (1983) OH Radical Rate Constants and Photolysis Rates of a-Dicarbonyls 

M. Malik, J. A. Joens Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 56, 2653-2658, (2000) Temperature dependent near-UV molar absorptivities of glyoxal and gluteraldehyde in aqueous solution

J.J. Orlando, G.S. Tyndall Int. J. Chem. Kinet., 33, 149-156, (2001) The atmospheric chemistry of the HC(O)CO radical

A. Horowitz, R. Meller, G.K. Moortgat J. Photochem. Photobiol. A: Chemistry, 146, 19-27, (2001) The UV-VIS absorption cross sections of the alpha-dicarbonyl compounds: pyruvic acid, biacetyl and glyoxal

Y. Chen, L. Zhu J. Phys. Chem. A, 107, 4643-4651, (2003) Wavelength-dependent photolysis of glyoxal in the 290-420 nm region

R. Volkamer, P. Spietz, J. Burrows, U. Platt J. Photochemistry and Photobiology A: Chemistry, 172, 35-46, (2005) High-resolution absorption cross-section of glyoxal in the UV–vis and IR spectral ranges

related data (quantum yield studies; photolysis studies, etc.)
G. W. Loge, C. S. Parmenter J. Phys. Chem., 85 (12), 1653-1662, (1981) Collision-free dissociation after excitation of single rotational levels in S1 glyoxal

L. Zhu, D. Kellis, C.-F. Ding Chem. Phys. Lett., 257, 487-491, (1996) Photolysis of glyoxal at 193, 248, 308, and 351 nm

J. Tadic, G. K. Moortgat, K. Wirtz J. Photochem. Photobiol. A: Chemistry, 177, 116-124, (2006) Photolysis of glyoxal in air

K. J. Feierabend, J. E. Flad, S. S. Brown, J. B. Burkholder J. Phys. Chem. A, 113 (27), 7784-7794, (2009) HCO Quantum Yields in the Photolysis of HC(O)C(O)H (Glyoxal) between 290 and 420 nm; supporting information available from ACS 

R. J. Salter, M. A. Blitz, D. E. Heard, M. J. Pilling, P. W. Seakins J. Phys. Chem. A, 113, 8278–8285, (2009) New Chemical Source of the HCO Radical Following Photoexcitation of Glyoxal, (HCO)2

CH2C(CH3)CHO
R. Meller priv. comm., (1990) MPI Mainz, (294 K)

R. Meller priv. comm., (1990) MPI Mainz, (294 K)

CH3C(O)CH2OH; acetol; hydroxyacetone; CAS-No.: 116-09-6
R. Meller, J.N. Crowley priv. comm., (1990) MPI Mainz, (296 K)

J. J. Orlando, G. S. Tyndall, J.-M. Fracheboud, E. G. Estupińa, S. Haberkorn, A. Zimmer Atmos. Env., 33, 1621-1629, (1999) The rate and mechanism of the gas-phase oxidation of hydroxyacetone 

CH3COCHCH2; methyl vinyl ketone; MVK; CAS-No.: 78-94-4
W. Schneider, G.K. Moortgat priv. comm., (1989) MPI Mainz, (294 K)

A. Fahr, W. Braun, A.H. Laufer J. Phys. Chem., 97, 1502-1506, (1993) Photolysis of methyl vinyl ketone at 193.3 nm: quantum yield determination of methyl and vinyl radicals

T. Gierczak, J.B. Burkholder, R.K. Talukdar, A. Mellouki, S.B. Barone, A.R. Ravishankara J. Photochem. Photobiol. A: Chem., 110, 1-10, (1997) Atmospheric fate of methyl vinyl ketone and methacrolein

related data (quantum yield studies; photolysis studies, etc.)
M. T. B. Romero, M. A. Blitz, D. E. Heard, M. J. Pilling, B. Price, P. W. Seakins, L. Wang Faraday Discuss., 130, 73 - 88, (2005) Photolysis of methylethyl, diethyl and methylvinyl ketones and their role in the atmospheric HOx budget

M. E. Earle, R. Mills, J. M. Roscoe J. Photochem. Photobiol. A: Chemistry, 206, 71-79, (2009) The photolysis of methyl vinyl ketone at 308nm

(CH3)2NC(O)CH3; dimethyl acetamide; DMA; CAS-No.: 127-19-5
A. Chakir, G. Solignac, A. Mellouki, and D. Daumont Chem. Phys. Letters, 404, 74-78 (2005) Gas phase UV absoption cross-sections for a series of amides

A. Chakir, G. Solignac, A. Mellouki, and D. Daumont Chem. Phys. Letters, 404, 74-78 (2005) Gas phase UV absoption cross-sections for a series of amides

C6H10O; cyclohexanone; CAS-No.: 108-94-1
E. Iwasaki, Y. Matsumi, K. Takahashi, T. J. Wallington, M.D. Hurley, J. J. Orlando, E. W. Kaiser, J. G. Calvert Int. J. Chem. Kin., 40, 223-229, (2008) Atmospheric chemistry of cyclohexanone: UV spectrum and kinetics of reaction with chlorine atoms

C3H4O2; glycidaldehyde; CAS-No.: 765-34-4
S. Ma, I. Barnes, K. H. Becker Environ. Sci. Technol., 32, 3515-3521, (1998) Atmospheric Degradation of Glycidaldehyde: Photolysis and Reaction with OH Radicals

C4H6O2; biacetyl; 2,3-butanedione; CAS-No.: 431-03-8
related data (quantum yield studies; photolysis studies, etc.)
W. E. Bell, F. E. Blacet J. Am. Chem. Soc., 76, 5332-5337, (1954) The Photolysis of Biacetyl

B. Rajakumar, T. Gierczak, J. Flad, A.R. Ravishankara, J.B. Burkholder J. Photochem. Photobiol. A: Chem., 199, 336-344, (2008) The CH3CO quantum yield in the 248 nm photolysis of acetone, methyl ethyl ketone, and biacetyl

C5H8O2; acetylacetone; CAS-No.: 123-54-6
H. Nakanishi, H. Morita, S. Nagakura Bulletin of the Chemical Society of Japan, 51 (6), 1723-1729, (1978) Charge-Transfer Character in the Intramolecular Hydrogen Bond: Vacuum Ultraviolet Spectra of Acetylacetone and Its Fluoro Derivatives

CH2CO; ketene; ethenone; CAS-No.: 463-51-4
W. C. Price, J. P. Teegan, A. D. Walsh J. Chem. Soc., 920, (1951) The absorption spectrum of keten in the far ultra-violet

R.N. Dixon, G.H. Kirby Trans. Faraday Soc., 62, 1406-1410, (1966) Absorption spectrum of ketene in the visible and near ultra-violet

A.H. Laufer, R.A. Keller J. Am. Chem. Soc., 93, 61-63, (1971) Lowest excited states of ketene

related data (quantum yield studies; photolysis studies, etc.)
W.G. Paterson, H. Gesser Can. J. Chem., 35, 1137-1138, (1957) The photolysis of ketene at low temperatures

C10H16O2; pinonaldehyde; CAS-No.: 2704-78-1
M. Hallquist, I. Wängberg, E. Ljungström Environ. Sci. Technol., 31 (11), 3166-3172, (1997) Atmospheric Fate of Carbonyl Oxidation Products Originating from alpha-Pinene and DELTA3-Carene: Determination of Rate of Reaction with OH and NO3 Radicals, UV Absorption Cross Sections, and Vapor Pressures


Top of Page

© 2010, science-softCon, Webmaster