science-softCon uv/vis+ spectra data base; www.uv-spectra.de, (C) science-softCon 2019 Substance: methane Other Names: Formula: CH4 CAS-No.: 74-82-8 Study: photoabsorption spectroscopy Authors: J.W. Au, G. Cooper, G.R. Burton, T.N. Olney, C.E. Brion Title: The valence shell photoabsorption of the linear alkanes, CnH2n+2 (n=1–8): absolute oscillator strengths (7–220 eV) Journal/Source: Chem. Phys., 173, 209-239, (1993); doi:10.1016/0301-0104(93)80142-V Data: table, diagram Energy/Wavelength range: 7 - 220 eV (~ 5.6 - 177 nm) Resolution: ~ 0.048 eV fwhm; ~ 1 eV fwhm Temperature: Temperature dependence: Pressure/Concentration. Phase: gas pH: Comments: The absolute valence shell photoabsorption spectra of the first eight members of the homologous linear (normal) alkane series, CH4 to C8H18, have been obtained from electron energy loss measurements using dipole (e, e) spectroscopy at a resolution of 1 eV fwhm in the equivalent photon energy range 7-220 eV. Absolute oscillator strengths (transition probabilities) for discrete and continuum photoabsorption transitions have been determined throughout the entire energy range. Author to whom correspondence should be addressed: (e-mail address):