science-softCon uv/vis spectra data base;		www.uv-spectra.de; (C) science-softCon 2008

Substance: chlorine nitrate				Other Names: 

Formula: ClONO2					CAS-No.: 14545-72-3

Study: quantum yields, photolysis


Authors: S. L. Nickolaisen, S. P. Sander, R. R. Friedl 

Title: Pressure-Dependent Yields and Product Branching Ratios in the Broadband Photolysis of Chlorine Nitrate 

Journal/Source: J. Phys. Chem., 100 (24), 10165-10178, (1996); DOI: 10.1021/jp953612s 


Data: (diagram, table, disk): 

Wavelenght range: 254 nm

Resolution: 

Temperature: 

Temperature dependence: 

Pressure: 10 - 100 Torr (bath gas)


Comments: The absolute product yield displayed a pressure dependence, the branching between the two channels (1a: ClO + NO2; 1b: Cl + NO3) 
was independent of pressure.
The relative branching ratios are 0.61 ± 0.20 for channel 1a and 0.39 ± 0.20 for channel 1b for photolysis with lambda > 200 nm and 0.44 ± 0.08 for 
channel 1a and 0.56 ± 0.08 for channel 1b for photolysis with  lambda > 300 nm.

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