Substances: Halogenated Ethanes I (C2BrF5, C2Br2F4, CF3CH2Br, CF3CHBrCl, CF3CHBrF, CF2ClCFCl2, CF2ClCF2Cl, CF3CF2Cl, CF3CCl3, CF3CHCl2, CF3CHFCl, CH3CFCl2, CH3CF2Cl, CH3CCl3, CH3CHF2, C2H4Br2, C2H5Br, C2H5Cl, C2H4Cl2)
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Please note: In addition, information concerning related publications (e.g. quantum yield studies or photolysis studies) for some of the substances are given. Send us your feedback
| Authors | Journal/Source | Title/Paper |
Data Sheet |
| C2BrF5; bromopentafluoroethane; CAS-No.: 354-55-2 | |||
| W.H. Pence, S.L. Baughcum, S.R. Leone | J. Phys. Chem., 85, 3844-3851, (1981) | Laser UV photofragmentation of halogenated molecules. Selective bond dissociation and wavelength-specific quantum yields for excited I(2P1/2) and Br(2P1/2) atoms | |
| L.T. Molina, M.J. Molina, F.S. Rowland | J. Phys. Chem., 86, 2672-2676, (1982) | Ultraviolet Absorption Cross Sections of Several Brominated Methanes and Ethanes of Atmospheric Interest | |
| L. Zhang, W. Fuss, K.L. Kompa | Chem. Phys., 144, 289-297, (1990) | Bond-selective photodissociation of CX (X = Br, I) in XC2H4C2F4X | |
| C2Br2F4; 1,2-dibromotetrafluoroethane; CAS-No.: 124-73-2 | |||
| L.T. Molina, M.J. Molina, F.S. Rowland | J. Phys. Chem., 86, 2672-2676, (1982) | Ultraviolet Absorption Cross Sections of Several Brominated Methanes and Ethanes of Atmospheric Interest | |
| J.B. Burkholder, R.W. Wilson, T. Gierczak, R. Talukdar, S.A. McKeen, J.J. Orlando, G.L. Vaghjiani, A.R. Ravishankara | J. Geophys. Res., 96, 5025-5043, (1991) | Atmospheric Fate of CF3Br, CF2Br2, CF2ClBr, and CF2BrCF2Br (210 K, 230 K, 250 K, 270 K, 296 K) | |
| V.L. Orkin, E.E. Kasimovskaya | J. Atmos. Chem., 21, 1, (1995) | Ultraviolet absorption spectra of some Br-Containing Haloalkanes | |
| related data (quantum yield studies; photolysis studies, etc.) | |||
| P. Zhou, W.S. McGivern, O. Sorkhabi, A.G. Suits, S.W. North | J. Chem. Phys., 113, 7149, (2000) | Quantum yields and energy partitioning in the ultraviolet photodissociation of 1,2 dibromo-tetrafluoroethane (Halon-2402) | |
| CF3CH2Br; 1-bromo-2,2,2-trifluoroethane; CAS-No.: 421-06-7 | |||
| V.L. Orkin, E.E. Kasimovskaya | J. Atmos. Chem., 21, 1, (1995) | Ultraviolet absorption spectra of some Br-Containing Haloalkanes | |
| CF3CHBrCl; 1,1,1-trifluoro-2-chloro-2-bromoethane; halothane; CAS-No.: 151-67-7 | |||
| V.L. Orkin, E.E. Kasimovskaya | J. Atmos. Chem., 21, 1, (1995) | Ultraviolet absorption spectra of some Br-Containing Haloalkanes | |
| M. Bilde, T.J. Wallington, C. Ferronato, J.J. Orlando, G.S. Tyndall, E. Estupinan, S. Haberkorn | J. Phys. Chem. A, 102 (11), 1976-1986, (1998) | Atmospheric Chemistry of CH2BrCl, CHBrCl2, CHBr2Cl, CF3CHBrCl, and CBr2Cl2 | |
| T. Langbein, H. Sonntag, D. Trapp, A. Hoffmann, W. Malms, E.-P. Röth, V. Mörs, R. Zellner | British Journal of Anaesthesia, 82 (1), 66-73, (1999) | Volatile anaesthetics and the atmosphere: atmospheric lifetimes and atmospheric effects of halothane, enflurane, isoflurane, desflurane and sevoflurane | |
| CF3CHBrF; tetrafluorobromoethane; CAS-No.: 124-72-1 | |||
| V.L. Orkin, E.E. Kasimovskaya | J. Atmos. Chem., 21, 1, (1995) | Ultraviolet absorption spectra of some Br-Containing Haloalkanes | |
| CF2ClCFCl2 ; trichlorotrifluoroethane; CFC-113; CAS-No.: 76-13-1 | |||
| Chou, C.C., R.J. Milstein, W.S. Smith, H. Vera Ruiz, M.J. Molina, F.S. Rowland | J. Phys. Chem., 82, 1-7, (1978) | Stratospheric Photodissociation of Several Saturated Perhalo Chlorofluorocarbon Compounds in Current Technological Use (Fluorocarbons-13, -113, -114, and -115) | |
| Hubrich, C., and F. Stuhl | J. Photochem., 12, 93- 107, (1980) | The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest (208 K, 298 K) | |
| P.C. Simon, D. Gillotay, N. Vanlaethem-Meuree, J. Wisemberg | Ann. Geophysicae, 76, 239-248, (1988) | Temperature Dependence of Ultraviolet Absorption Cross-Sections of Chlorofluoroethanes (210 K, 295 K) | |
| CF2ClCF2Cl; dichlorotetrafluoroethane; CFC-114; CAS-No.: 76-14-2 | |||
| C.C. Chou, R.J. Milstein, W.S. Smith, H. Vera Ruiz, M.J. Molina, F.S. Rowland | J. Phys. Chem., 82, 1-7, (1978) | Stratospheric Photodissociation of Several Saturated Perhalo Chlorofluorocarbon Compounds in Current Technological Use (Fluorocarbons-13, -113, -114, and -115) | |
| C. Hubrich, F. Stuhl | J. Photochem., 12, 93- 107, (1980) | The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest (208 k, 298 K) | |
| P.C. Simon, D. Gillotay, N. Vanlaethem-Meuree, J. Wisemberg | Ann. Geophysicae, 76, 239-248, (1988) | Temperature Dependence of Ultraviolet Absorption Cross-Sections of Chlorofluoroethanes (210 K, 295 K) | |
| CF3CF2Cl; chloropentafluoroethane; CFC-115; CAS-No.: 76-15-3 | |||
| J. Doucet, P. Sauvageau, C. Sandorfy | J. Chem. Phys., 62, 355-359, (1975) | Photoelectron and far-ultraviolet absorption spectra of chlorofluoro derivatives of ethane | |
| C.C. Chou, R.J. Milstein, W.S. Smith, H. Vera Ruiz, M.J. Molina, F.S. Rowland | J. Phys. Chem., 82, 1-7, (1978) | Stratospheric Photodissociation of Several Saturated Perhalo Chlorofluorocarbon Compounds in Current Technological Use (Fluorocarbons-13, -113, -114, and -115) | |
| B.E. Cole, R.N. Dexter | J. Quant. Spectrosc. Radiat. Transfer, 19, 303-309, (1978) | Photoabsorption cross sections for chlorinated methanes and ethanes between 46 and 100 Å | |
| C. Hubrich, F. Stuhl | J. Photochem., 12, 93- 107, (1980) | The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest (208 k, 298 K) | |
| P.C. Simon, D. Gillotay, N. Vanlaethem-Meuree, J. Wisemberg | Ann. Geophysicae, 76, 239-248, (1988) | Temperature Dependence of Ultraviolet Absorption Cross-Sections of Chlorofluoroethanes (210 K, 295 K) | |
| A.R. Ravishankara, S. Solomon, A.A. Turnipseed, R.F. Warren | Science, 259, 194-199, (1993) | Atmospheric lifetimes of long-lived halogenated species | |
| CF3CCl3; 1,1,1-trifluoro-2,2,2-trichloroethane; CAS-No.: 354-58-5 | |||
| related data (quantum yield studies; photolysis studies, etc.) | |||
| F. Taketani, K. Takahashi, Y. Matsumi | J. Phys. Chem. A, 109 (12), 2855-2860, (2005) | Quantum Yields for Cl(2Pj) Atom Formation from the Photolysis of Chlorofluorocarbons and Chlorinated Hydrocarbons at 193.3 nm | |
| CF3CHCl2; 2,2-dichloro-1,1,1-trifluoro-ethane; CFC-123; CAS-No.: 306-83-2 | |||
| R.G. Green, R.P. Wayne | J. Photochem., 6, 374-376, (1976/1977) | Vacuum Ultra-Violet Absorption Spectra of Halogenated Methanes and Ethanes | |
| D. Gillotay, P.C. Simon, G. Brasseur | Planet. Space Sci., 37,105-108, (1989) | Absorption Cross-Section of Alternative Chlorofluoroethanes and Potential Effects on the Ozone Layer | |
| A. C. Brown, C. E. Canosa-Mas, A. D. Parr, R. P. Wayne | Atmos. Env., 24, 2499-2511, (1990) | Laboratory studies of some halogenated ethanes and ethers: Measurements of rates of reaction with OH and of infrared absorption cross-sections | |
| J.J. Orlando, J.B. Burkholder, S.A. McKeen, A.R. Ravishankara | J. Geophys. Res., 96, 5013-5023, (1991) | Atmospheric Fate of Several Hydrofluoroethanes and Hydrochloroethanes: 2. UV Absorption Cross Sections and Atmospheric Lifetimes (203 K, 223 K, 243 K, 263 K, 295 K) | |
| D. Gillotay, P.C. Simon | J. Atmos. Chem., 12, 269-285, (1991) | Temperature-Dependence of Ultraviolet Absorption Cross-Sections of Alternative Chlorofluoroethanes (210 K, 230 K, 250 K, 270 K, 295 K) | |
| A.K. Nayak, T. J. Buckley, M. J. Kurylo, A. Fahr | J. Geophys. Res., 101, D4, 9055-9062, (1996) | Temperature dependence of the gas and liquid phase ultraviolet absorption cross sections of HCFC-123 (CF3CHCl2) and HCFC-142b (CH3CF2Cl) | |
| CF3CHFCl; 2-chloro-1,1,1,2-tetrafluoroethane; CFC-124; CAS-No.: 2837-89-0 | |||
| J.J. Orlando, J.B. Burkholder, S.A. McKeen, A.R. Ravishankara | J. Geophys. Res., 96, 5013-5023, (1991) | Atmospheric Fate of Several Hydrofluoroethanes and Hydrochloroethanes: 2. UV Absorption Cross Sections and Atmospheric Lifetimes (203 K, 223 K, 243 K, 263 K, 295 K) | |
| D. Gillotay, P.C. Simon | J. Atmos. Chem., 12, 269-285, (1991) | Temperature-Dependence of Ultraviolet Absorption Cross-Sections of Alternative Chlorofluoroethanes (210 K, 230 K, 250 K, 270 K, 295 K) | |
| CH3CFCl2; dichlorofluoroethane; CFC-141b; CAS-No.: 1717-00-6 | |||
| D. Gillotay, P.C. Simon, G. Brasseur | Planet. Space Sci., 37,105-108, (1989) | Absorption Cross-Section of Alternative Chlorofluoroethanes and Potential Effects on the Ozone Layer | |
| A. C. Brown, C. E. Canosa-Mas, A. D. Parr, R. P. Wayne | Atmos. Env., 24, 2499-2511, (1990) | Laboratory studies of some halogenated ethanes and ethers: Measurements of rates of reaction with OH and of infrared absorption cross-sections | |
| R. Talukdar, A. Mellouki, T. Gierczak, J.B. Burkholder, S. McKeen, A.R. Ravishankara | J. Phys. Chem., 95, 5815-5821, (1991) | Atmospheric Fate of CF2H2, CH3CF3, CHF2CF3, and CH3CFCl2: Rate Coefficients for Reactions with OH and UV Absorption Cross Sections of CH3CFCl2 (203 K, 223 K, 243 K, 263 K, 295 K) | |
| D. Gillotay, P.C. Simon | J. Atmos. Chem., 12, 269-285, (1991) | Temperature-Dependence of Ultraviolet Absorption Cross-Sections of Alternative Chlorofluoroethanes (210 K, 230 K, 250 K, 270 K, 295 K) | |
| A. Fahr, W. Braun, M.J. Kurylo | J. Geophys. Res., 98, 20467-20474, (1993) | Scattered Light and Accuracy of the Cross-Section Measurements of Weak Absorptions: Gas and Liquid Phase UV Absorption Cross Section of CH3CFCl2 | |
| R.K. Vatsa, H.-R. Volpp | Chem. Phys. Lett., 340, 289-295, (2001) | Absorption cross-sections for some atmospherically important molecules at the H atom Lyman-alpha wavelength (121.567 nm) | |
| related data (quantum yield studies; photolysis studies, etc.) | |||
| A. Laeuter, D. Suresh, H.-R. Volpp | J. Chem. Phys., 118, 5821-5830, (2003) | Absolute chlorine and hydrogen atom quantum yield measurements in the 193.3 nm photodissociation of CH3CFCl2 (HCFC-141b) | |
| A. Laeuter, ,H.-R. Volpp, J. P. Mittal, R. K. Vatsa | J.Chem.Sci., 119 (4), 277-282, (2007) | Lyman-a photodissociation of CH3CFCl2 (HCFC-141b): Quantum yield and translational energy of hydrogen atoms | |
| CH3CF2Cl; 1-chloro-1,1-difluoroethane; CFC-142b; CAS-No.: 75-68-3 | |||
| J. Doucet, P. Sauvageau, C. Sandorfy | J. Chem. Phys., 62, 355, (1975) | Photoelectron and far-ultraviolet absorption spectra of chlorofluoro derivatives of ethane | |
| R.G. Green, R.P. Wayne | J. Photochem., 6, 374-376, (1976/77) | Vacuum Ultra-Violet Absorption Spectra of Halogenated Methanes and Ethanes | |
| T. Ichimura, A.W. Kirk, E. Tschuikow-Roux | Int. J. Chem. Kinetics, 9, 697-703, (1977) | Photolysis of 1,1,1-difluorochloroethane (Freon 142) at 147 nm | |
| C. Hubrich, F. Stuhl | J. Photochem., 12, 93- 107, (1980) | The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest (208 K, 298 K) | |
| D. Gillotay,, P.C. Simon, G. Brasseur | Planet. Space Sci., 37,105-108, (1989) | Absorption Cross-Section of Alternative Chlorofluoroethanes and Potential Effects on the Ozone Layer | |
| A. C. Brown, C. E. Canosa-Mas, A. D. Parr, R. P. Wayne | Atmos. Env., 24, 2499-2511, (1990) | Laboratory studies of some halogenated ethanes and ethers: Measurements of rates of reaction with OH and of infrared absorption cross-sections | |
| J.J. Orlando, J.B. Burkholder, S.A. McKeen, A.R. Ravishankara | J. Geophys. Res., 96, 5013-5023, (1991) | Atmospheric Fate of Several Hydrofluoroethanes and Hydrochloroethanes: 2. UV Absorption Cross Sections and Atmospheric Lifetimes (203 K, 223 K, 243 K, 263 K, 295 K) | |
| D. Gillotay, P.C. Simon | J. Atmos. Chem., 12, 269-285, (1991) | Temperature-Dependence of Ultraviolet Absorption Cross-Sections of Alternative Chlorofluoroethanes (210 K, 230 K, 250 K, 270 K, 295 K) | |
| A.K. Nayak, T.J. Buckley, M.J. Kurylo, A. Fahr | J. Geophys. Res., 101, D4, 9055-9062, (1996) | Temperature dependence of the gas and liquid phase ultraviolet absorption cross sections of HCFC-123 (CF3CHCl2) and HCFC-142b (CH3CF2Cl) | |
| R.K. Vatsa, H.-R. Volpp | Chem. Phys. Lett., 340, 289-295, (2001) | Absorption cross-sections for some atmospherically important molecules at the H atom Lyman-alpha wavelength (121.567 nm) | |
| related data (quantum yield studies; photolysis studies, etc.) | |||
| R. A. Brownsword, M. Hillenkamp, T. Laurent, H.-R. Volpp, J. Wolfrum, R.K. Vatsa, H.-S. Yoo | J. Chem. Phys., 107 (3), 779-785, (1997) | H atom formation dynamics in the dissociation of CH3–CF2Cl (HCFC-142b) after UV and VUV laser photoexcitation | |
| R. A. Brownsword, P. Schmiechen, H.-R. Volpp, H.P. Upadhyaya, Y.J. Jung, K.-H. Jung | J. Chem. Phys., 110, 11823-11829, (1999) | Chlorine atom formation dynamics in the dissociation of CH3CF2Cl (HCFC-142b) after UV laser photoexcitation | |
| K. Le Bris, K. Strong | J. Quant. Spectr. Rad. Transfer, 111, 364-371, (2010) | Temperature-dependent absorption cross-sections of HCFC-142b | |
| CH3CCl3; 1,1,1-trichloroethane; CAS-No.: 71-55-6 | |||
| D. Salomon, A. W. Kirk, E. Tschuikow-Roux | J. Photochemistry, 7, 345-353, (1977) | Primary processes in the photochemical decomposition of 1,1,1-trichloroethane at 147 nm | |
| N. Vanlaethem-Meuree, J. Wisemberg, P.C. Simon | Geophys. Res. Lett., 6, 451-454, (1979) | Ultraviolet Absorption Spectrum of Methylchloroform in the Vapor Phase (210 K, 230 K, 250 K, 270 K, 295 K) | |
| C. Hubrich, F. Stuhl | J. Photochem., 12, 93- 107, (1980) | The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest (208 K, 298 K) | |
| A.K. Nayak, M.J. Kurylo, A. Fahr | J. Geophys. Res., 100, 11185-11189, (1995) | UV Absorption Cross Sections of
Methylchloroform: Temperature-Dependent Gas and Liquid Phase Measurements (333
K, 313 K 295 K, 273 K, 253 K, 233 K, 223 K) |
|
| related data (quantum yield studies; photolysis studies, etc.) | |||
| S. Hautecloque | J. Photochem., 12 (3), 187-196, (1980) | Photolyse de CH3CCl3 dans l'uv proche | |
| CH3CHF2; 1,1-difluoroethane; CAS-No.: 75-37-6 | |||
| P. Sauvageau, J. Doucet, R. Gilbert, C. Sandorfy | J. Chem. Phys., 61, 391-395, (1974) | Vacuum ultraviolet and photoelectron spectra of fluoroethanes | |
| C2H4Br2; ethylene dibromide; CAS-No.: 106-93-4 | |||
| A.P. Uthman, P.J. Demlein, T.D. Allston, M.C. Withiam, M.J. McClements, G.A. Takacs | J. Phys. Chem., 82, 2252-2257, (1978) | Photoabsorption Spectra of Gaseous Methyl Bromide, Ethylene Dibromide, Nitrosyl Bromide, Thionyl Chloride, and Sulfuryl Chloride | |
| C2H5Br; bromoethane; ethyl bromide; CAS-No.: 74-96-4 | |||
| K.-H. Jung, H.S. Yoo, J.H. Hahn | Int. J. Chem. Kinet., 16, 397-405, (1984) | Photodecomposition reaction of ethyl bromide at 147 nm | |
| L. Zhang, W. Fuss, K.L. Kompa | Chem. Phys., 144, 289-297, (1990) | Bond-selective photodissociation of CX (X = Br, I) in XC2H4C2F4X | |
| C2H5Cl; chloro ethane; CAS-No.: 75-00-3 | |||
| T. Ichimura, A. W. Kirk, G. Kramer, E. Tschuikow-Roux | J. Photochemistry, 6, 77-90, (1976/1977) | Photolysis of ethyl chloride (Freon 160) at 147 nm | |
| C. Hubrich, F. Stuhl | J. Photochem., 12, 93- 107, (1980) | The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest | |
| Dae Kon Oh, Kwang Bum Hong, Kwang Ok Park, Kyung-Hoon Jung | J. Photochem. Photobiol. A: Chemistry, 51, 269-279, (1990) | Primary processes in the 163.3 nm photolysis of gas-phase ethyl chloride | |
| related data (quantum yield studies; photolysis studies, etc.) | |||
| Sung-Seen Choi and Dae-Gon Oh, Seong Keun Kim, Kyung-Hoon Jung | J. Photochem. Photobiol. A: Chemistry, 64, 135-143, (1992) | Photolysis of ethyl chloride at 121.6 nm | |
| C2H4Cl2; 1,2-dichlorethane; CAS-No.: 107-06-2 | |||
| B.R. Russell, L.O. Edwards, J.W. Raymonda | J. Am. Chem. Soc., 95, 2129-2133, (1973) | Vacuum ultraviolet absorption spectra of the chloromethanes | |
| T. Yano, E. Tschuikow-Roux | J. Phys. Chem., 84, 3372-3377, (1980) | A reexamination of the photodissociation of CH2ClCH2Cl at 147 nm. Test for chlorine atom reactions | |