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Literature Service: Halogenated Ethanes

Substances: Halogenated Ethanes I (C2BrF5, C2Br2F4, CF3CH2Br, CF3CHBrCl, CF3CHBrF, CF2ClCFCl2, CF2ClCF2Cl, CF3CF2Cl, CF3CCl3CF3CHCl2, CF3CHFCl, CH3CFCl2, CH3CF2Cl, CH3CCl3, CH3CHF2, C2H4Br2, C2H5Br, C2H5Cl, C2H4Cl2)

The relevant Spectra Data are available (for registered users) at: Spectra Service

Please note: In addition, information concerning related publications (e.g. quantum yield studies or photolysis studies) for some of the substances are given. Send us your feedback

Authors Journal/Source Title/Paper

Data Sheet

C2BrF5; bromopentafluoroethane; CAS-No.: 354-55-2
W.H. Pence, S.L. Baughcum, S.R. Leone J. Phys. Chem., 85, 3844-3851, (1981) Laser UV photofragmentation of halogenated molecules. Selective bond dissociation and wavelength-specific quantum yields for excited I(2P1/2) and Br(2P1/2) atoms

L.T. Molina, M.J. Molina, F.S. Rowland J. Phys. Chem., 86, 2672-2676, (1982) Ultraviolet Absorption Cross Sections of Several Brominated Methanes and Ethanes of Atmospheric Interest 

L. Zhang, W. Fuss, K.L. Kompa Chem. Phys., 144, 289-297, (1990) Bond-selective photodissociation of CX (X = Br, I) in XC2H4C2F4X

C2Br2F4; 1,2-dibromotetrafluoroethane; CAS-No.: 124-73-2
L.T. Molina, M.J. Molina, F.S. Rowland J. Phys. Chem., 86, 2672-2676, (1982) Ultraviolet Absorption Cross Sections of Several Brominated Methanes and Ethanes of Atmospheric Interest

J.B. Burkholder, R.W. Wilson, T. Gierczak, R. Talukdar, S.A. McKeen, J.J. Orlando, G.L. Vaghjiani, A.R. Ravishankara J. Geophys. Res., 96, 5025-5043, (1991) Atmospheric Fate of CF3Br, CF2Br2, CF2ClBr, and CF2BrCF2Br (210 K, 230 K, 250 K, 270 K, 296 K)

V.L. Orkin, E.E. Kasimovskaya J. Atmos. Chem., 21, 1, (1995) Ultraviolet absorption spectra of some Br-Containing Haloalkanes 

related data (quantum yield studies; photolysis studies, etc.)
P. Zhou, W.S. McGivern, O. Sorkhabi, A.G. Suits, S.W. North J. Chem. Phys., 113, 7149, (2000) Quantum yields and energy partitioning in the ultraviolet photodissociation of 1,2 dibromo-tetrafluoroethane (Halon-2402)

CF3CH2Br; 1-bromo-2,2,2-trifluoroethane; CAS-No.: 421-06-7
V.L. Orkin, E.E. Kasimovskaya J. Atmos. Chem., 21, 1, (1995) Ultraviolet absorption spectra of some Br-Containing Haloalkanes 

CF3CHBrCl; 1,1,1-trifluoro-2-chloro-2-bromoethane; halothane; CAS-No.: 151-67-7
V.L. Orkin, E.E. Kasimovskaya J. Atmos. Chem., 21, 1, (1995) Ultraviolet absorption spectra of some Br-Containing Haloalkanes

M. Bilde, T.J. Wallington, C. Ferronato, J.J. Orlando, G.S. Tyndall, E. Estupinan, S. Haberkorn J. Phys. Chem. A, 102 (11), 1976-1986, (1998) Atmospheric Chemistry of CH2BrCl, CHBrCl2, CHBr2Cl, CF3CHBrCl, and CBr2Cl2

T. Langbein, H. Sonntag, D. Trapp, A. Hoffmann, W. Malms, E.-P. Röth, V. Mörs, R. Zellner British Journal of Anaesthesia, 82 (1), 66-73, (1999) Volatile anaesthetics and the atmosphere: atmospheric lifetimes and atmospheric effects of halothane, enflurane, isoflurane, desflurane and sevoflurane

CF3CHBrF; tetrafluorobromoethane; CAS-No.: 124-72-1
V.L. Orkin, E.E. Kasimovskaya J. Atmos. Chem., 21, 1, (1995) Ultraviolet absorption spectra of some Br-Containing Haloalkanes

CF2ClCFCl2 ; trichlorotrifluoroethane; CFC-113; CAS-No.: 76-13-1
Chou, C.C., R.J. Milstein, W.S. Smith, H. Vera Ruiz, M.J. Molina, F.S. Rowland J. Phys. Chem., 82, 1-7, (1978) Stratospheric Photodissociation of Several Saturated Perhalo Chlorofluorocarbon Compounds in Current Technological Use (Fluorocarbons-13, -113, -114, and -115) 

Hubrich, C., and F. Stuhl J. Photochem., 12, 93- 107, (1980) The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest (208 K, 298 K)

P.C. Simon, D. Gillotay, N. Vanlaethem-Meuree, J. Wisemberg Ann. Geophysicae, 76, 239-248, (1988) Temperature Dependence of Ultraviolet Absorption Cross-Sections of Chlorofluoroethanes (210 K, 295 K)

CF2ClCF2Cl; dichlorotetrafluoroethane; CFC-114; CAS-No.: 76-14-2
C.C. Chou, R.J. Milstein, W.S. Smith, H. Vera Ruiz, M.J. Molina, F.S. Rowland J. Phys. Chem., 82, 1-7, (1978) Stratospheric Photodissociation of Several Saturated Perhalo Chlorofluorocarbon Compounds in Current Technological Use (Fluorocarbons-13, -113, -114, and -115)

C. Hubrich, F. Stuhl J. Photochem., 12, 93- 107, (1980) The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest (208 k, 298 K)

P.C. Simon, D. Gillotay, N. Vanlaethem-Meuree, J. Wisemberg Ann. Geophysicae, 76, 239-248, (1988) Temperature Dependence of Ultraviolet Absorption Cross-Sections of Chlorofluoroethanes (210 K, 295 K)

CF3CF2Cl; chloropentafluoroethane; CFC-115; CAS-No.: 76-15-3
J. Doucet, P. Sauvageau, C. Sandorfy J. Chem. Phys., 62, 355-359, (1975) Photoelectron and far-ultraviolet absorption spectra of chlorofluoro derivatives of ethane

C.C. Chou, R.J. Milstein, W.S. Smith, H. Vera Ruiz, M.J. Molina, F.S. Rowland J. Phys. Chem., 82, 1-7, (1978) Stratospheric Photodissociation of Several Saturated Perhalo Chlorofluorocarbon Compounds in Current Technological Use (Fluorocarbons-13, -113, -114, and -115) 

B.E. Cole, R.N. Dexter J. Quant. Spectrosc. Radiat. Transfer, 19, 303-309, (1978) Photoabsorption cross sections for chlorinated methanes and ethanes between 46 and 100 Å

C. Hubrich, F. Stuhl J. Photochem., 12, 93- 107, (1980) The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest (208 k, 298 K)

P.C. Simon, D. Gillotay, N. Vanlaethem-Meuree, J. Wisemberg Ann. Geophysicae, 76, 239-248, (1988) Temperature Dependence of Ultraviolet Absorption Cross-Sections of Chlorofluoroethanes (210 K, 295 K)

A.R. Ravishankara, S. Solomon, A.A. Turnipseed, R.F. Warren Science, 259, 194-199, (1993) Atmospheric lifetimes of long-lived halogenated species

CF3CCl3; 1,1,1-trifluoro-2,2,2-trichloroethane; CAS-No.: 354-58-5
related data (quantum yield studies; photolysis studies, etc.)
F. Taketani, K. Takahashi, Y. Matsumi J. Phys. Chem. A, 109 (12), 2855-2860, (2005) Quantum Yields for Cl(2Pj) Atom Formation from the Photolysis of Chlorofluorocarbons and Chlorinated Hydrocarbons at 193.3 nm

CF3CHCl2; 2,2-dichloro-1,1,1-trifluoro-ethane; CFC-123; CAS-No.: 306-83-2
R.G. Green, R.P. Wayne J. Photochem., 6, 374-376, (1976/1977) Vacuum Ultra-Violet Absorption Spectra of Halogenated Methanes and Ethanes 

D. Gillotay, P.C. Simon, G. Brasseur Planet. Space Sci., 37,105-108, (1989) Absorption Cross-Section of Alternative Chlorofluoroethanes and Potential Effects on the Ozone Layer 

A. C. Brown, C. E. Canosa-Mas, A. D. Parr, R. P. Wayne Atmos. Env., 24, 2499-2511, (1990) Laboratory studies of some halogenated ethanes and ethers: Measurements of rates of reaction with OH and of infrared absorption cross-sections

J.J. Orlando, J.B. Burkholder, S.A. McKeen, A.R. Ravishankara J. Geophys. Res., 96, 5013-5023, (1991) Atmospheric Fate of Several Hydrofluoroethanes and Hydrochloroethanes: 2. UV Absorption Cross Sections and Atmospheric Lifetimes (203 K, 223 K, 243 K, 263 K, 295 K)

D. Gillotay, P.C. Simon J. Atmos. Chem., 12, 269-285, (1991) Temperature-Dependence of Ultraviolet Absorption Cross-Sections of Alternative Chlorofluoroethanes (210 K, 230 K, 250 K, 270 K, 295 K)

A.K. Nayak, T. J. Buckley, M. J. Kurylo, A. Fahr  J. Geophys. Res., 101, D4, 9055-9062, (1996) Temperature dependence of the gas and liquid phase ultraviolet absorption cross sections of HCFC-123 (CF3CHCl2) and HCFC-142b (CH3CF2Cl)

CF3CHFCl;  2-chloro-1,1,1,2-tetrafluoroethane; CFC-124; CAS-No.: 2837-89-0
J.J. Orlando, J.B. Burkholder, S.A. McKeen, A.R. Ravishankara J. Geophys. Res., 96, 5013-5023, (1991) Atmospheric Fate of Several Hydrofluoroethanes and Hydrochloroethanes: 2. UV Absorption Cross Sections and Atmospheric Lifetimes (203 K, 223 K, 243 K, 263 K, 295 K)

D. Gillotay, P.C. Simon J. Atmos. Chem., 12, 269-285, (1991) Temperature-Dependence of Ultraviolet Absorption Cross-Sections of Alternative Chlorofluoroethanes (210 K, 230 K, 250 K, 270 K, 295 K)

CH3CFCl2; dichlorofluoroethane; CFC-141b; CAS-No.: 1717-00-6
D. Gillotay, P.C. Simon, G. Brasseur Planet. Space Sci., 37,105-108, (1989) Absorption Cross-Section of Alternative Chlorofluoroethanes and Potential Effects on the Ozone Layer

A. C. Brown, C. E. Canosa-Mas, A. D. Parr, R. P. Wayne Atmos. Env., 24, 2499-2511, (1990) Laboratory studies of some halogenated ethanes and ethers: Measurements of rates of reaction with OH and of infrared absorption cross-sections

R. Talukdar, A. Mellouki, T. Gierczak, J.B. Burkholder, S. McKeen, A.R. Ravishankara J. Phys. Chem., 95, 5815-5821, (1991) Atmospheric Fate of CF2H2, CH3CF3, CHF2CF3, and CH3CFCl2: Rate Coefficients for Reactions with OH and UV Absorption Cross Sections of CH3CFCl2 (203 K, 223 K, 243 K, 263 K, 295 K)

D. Gillotay, P.C. Simon J. Atmos. Chem., 12, 269-285, (1991) Temperature-Dependence of Ultraviolet Absorption Cross-Sections of Alternative Chlorofluoroethanes (210 K, 230 K, 250 K, 270 K, 295 K)

A. Fahr, W. Braun, M.J. Kurylo J. Geophys. Res., 98, 20467-20474, (1993) Scattered Light and Accuracy of the Cross-Section Measurements of Weak Absorptions: Gas and Liquid Phase UV Absorption Cross Section of CH3CFCl2 

R.K. Vatsa, H.-R. Volpp Chem. Phys. Lett., 340, 289-295, (2001) Absorption cross-sections for some atmospherically important molecules at the H atom Lyman-alpha wavelength (121.567 nm)

related data (quantum yield studies; photolysis studies, etc.)
A. Laeuter, D. Suresh, H.-R. Volpp J. Chem. Phys., 118, 5821-5830, (2003) Absolute chlorine and hydrogen atom quantum yield measurements in the 193.3 nm photodissociation of CH3CFCl2 (HCFC-141b)

A. Laeuter, ,H.-R. Volpp, J. P. Mittal, R. K. Vatsa J.Chem.Sci., 119 (4), 277-282, (2007) Lyman-a photodissociation of CH3CFCl2 (HCFC-141b): Quantum yield and translational energy of hydrogen atoms

CH3CF2Cl;  1-chloro-1,1-difluoroethane; CFC-142b; CAS-No.: 75-68-3
J. Doucet, P. Sauvageau, C. Sandorfy J. Chem. Phys., 62, 355, (1975) Photoelectron and far-ultraviolet absorption spectra of chlorofluoro derivatives of ethane

R.G. Green, R.P. Wayne J. Photochem., 6, 374-376, (1976/77) Vacuum Ultra-Violet Absorption Spectra of Halogenated Methanes and Ethanes 

T. Ichimura, A.W. Kirk, E. Tschuikow-Roux Int. J. Chem. Kinetics, 9, 697-703, (1977) Photolysis of 1,1,1-difluorochloroethane (Freon 142) at 147 nm

C. Hubrich, F. Stuhl J. Photochem., 12, 93- 107, (1980) The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest (208 K, 298 K)

D. Gillotay,, P.C. Simon, G. Brasseur Planet. Space Sci., 37,105-108, (1989) Absorption Cross-Section of Alternative Chlorofluoroethanes and Potential Effects on the Ozone Layer 

A. C. Brown, C. E. Canosa-Mas, A. D. Parr, R. P. Wayne Atmos. Env., 24, 2499-2511, (1990) Laboratory studies of some halogenated ethanes and ethers: Measurements of rates of reaction with OH and of infrared absorption cross-sections

J.J. Orlando, J.B. Burkholder, S.A. McKeen, A.R. Ravishankara J. Geophys. Res., 96, 5013-5023, (1991) Atmospheric Fate of Several Hydrofluoroethanes and Hydrochloroethanes: 2. UV Absorption Cross Sections and Atmospheric Lifetimes (203 K, 223 K, 243 K, 263 K, 295 K)

D. Gillotay, P.C. Simon J. Atmos. Chem., 12, 269-285, (1991) Temperature-Dependence of Ultraviolet Absorption Cross-Sections of Alternative Chlorofluoroethanes (210 K, 230 K, 250 K, 270 K, 295 K)

A.K. Nayak, T.J. Buckley, M.J. Kurylo, A. Fahr J. Geophys. Res., 101, D4, 9055-9062, (1996) Temperature dependence of the gas and liquid phase ultraviolet absorption cross sections of HCFC-123 (CF3CHCl2) and HCFC-142b (CH3CF2Cl)

R.K. Vatsa, H.-R. Volpp Chem. Phys. Lett., 340, 289-295, (2001) Absorption cross-sections for some atmospherically important molecules at the H atom Lyman-alpha wavelength (121.567 nm)

related data (quantum yield studies; photolysis studies, etc.)
R. A. Brownsword, M. Hillenkamp, T. Laurent, H.-R. Volpp, J. Wolfrum, R.K. Vatsa, H.-S. Yoo J. Chem. Phys., 107 (3), 779-785, (1997) H atom formation dynamics in the dissociation of CH3–CF2Cl (HCFC-142b) after UV and VUV laser photoexcitation

R. A. Brownsword, P. Schmiechen, H.-R. Volpp, H.P. Upadhyaya, Y.J. Jung, K.-H. Jung J. Chem. Phys., 110, 11823-11829, (1999) Chlorine atom formation dynamics in the dissociation of CH3CF2Cl (HCFC-142b) after UV laser photoexcitation

K. Le Bris, K. Strong J. Quant. Spectr. Rad. Transfer, 111, 364-371, (2010) Temperature-dependent absorption cross-sections of HCFC-142b

CH3CCl3; 1,1,1-trichloroethane; CAS-No.: 71-55-6
D. Salomon, A. W. Kirk, E. Tschuikow-Roux J. Photochemistry, 7, 345-353, (1977) Primary processes in the photochemical decomposition of 1,1,1-trichloroethane at 147 nm

N. Vanlaethem-Meuree, J. Wisemberg, P.C. Simon Geophys. Res. Lett., 6, 451-454, (1979) Ultraviolet Absorption Spectrum of Methylchloroform in the Vapor Phase (210 K, 230 K, 250 K, 270 K, 295 K)

C. Hubrich, F. Stuhl J. Photochem., 12, 93- 107, (1980) The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest (208 K, 298 K)

A.K. Nayak, M.J. Kurylo, A. Fahr J. Geophys. Res., 100, 11185-11189, (1995) UV Absorption Cross Sections of Methylchloroform: Temperature-Dependent Gas and Liquid Phase Measurements (333 K, 313 K 295 K,  273 K, 253 K,  233 K, 223 K)

related data (quantum yield studies; photolysis studies, etc.)
S. Hautecloque J. Photochem., 12 (3), 187-196, (1980) Photolyse de CH3CCl3 dans l'uv proche

CH3CHF2; 1,1-difluoroethane; CAS-No.: 75-37-6
P. Sauvageau, J. Doucet, R. Gilbert, C. Sandorfy J. Chem. Phys., 61, 391-395, (1974) Vacuum ultraviolet and photoelectron spectra of fluoroethanes

C2H4Br2; ethylene dibromide; CAS-No.: 106-93-4
A.P. Uthman, P.J. Demlein, T.D. Allston, M.C. Withiam, M.J. McClements, G.A. Takacs J. Phys. Chem., 82, 2252-2257, (1978) Photoabsorption Spectra of Gaseous Methyl Bromide, Ethylene Dibromide, Nitrosyl Bromide, Thionyl Chloride, and Sulfuryl Chloride

C2H5Br; bromoethane; ethyl bromide; CAS-No.: 74-96-4
K.-H. Jung, H.S. Yoo, J.H. Hahn Int. J. Chem. Kinet., 16, 397-405, (1984) Photodecomposition reaction of ethyl bromide at 147 nm

L. Zhang, W. Fuss, K.L. Kompa Chem. Phys., 144, 289-297, (1990) Bond-selective photodissociation of CX (X = Br, I) in XC2H4C2F4X

C2H5Cl; chloro ethane; CAS-No.: 75-00-3
T. Ichimura, A. W. Kirk, G. Kramer, E. Tschuikow-Roux J. Photochemistry, 6, 77-90, (1976/1977) Photolysis of ethyl chloride (Freon 160) at 147 nm

C. Hubrich, F. Stuhl J. Photochem., 12, 93- 107, (1980) The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest 

Dae Kon Oh, Kwang Bum Hong, Kwang Ok Park, Kyung-Hoon Jung J. Photochem. Photobiol. A: Chemistry, 51, 269-279, (1990) Primary processes in the 163.3 nm photolysis of gas-phase ethyl chloride

related data (quantum yield studies; photolysis studies, etc.)
Sung-Seen Choi and Dae-Gon Oh, Seong Keun Kim, Kyung-Hoon Jung J. Photochem. Photobiol. A: Chemistry, 64, 135-143, (1992) Photolysis of ethyl chloride at 121.6 nm 

C2H4Cl2; 1,2-dichlorethane; CAS-No.: 107-06-2
B.R. Russell, L.O. Edwards, J.W. Raymonda J. Am. Chem. Soc., 95, 2129-2133, (1973) Vacuum ultraviolet absorption spectra of the chloromethanes

T. Yano, E. Tschuikow-Roux J. Phys. Chem., 84, 3372-3377, (1980) A reexamination of the photodissociation of CH2ClCH2Cl at 147 nm. Test for chlorine atom reactions


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