science-softCon UV/Vis+ Spectra Data Base (UV/Vis+ Photochemistry Database)

Literature Service: Halogenated Alkenes

Substances: CHBr=CH2, CHCl=CH2, CHF=CH2, CH2=CF2, CH2=CFCl, cis-CHCl=CHF, trans-CHCl=CHF, CHI=CH2, CHBr=CF2, CFBr=CF2, C2F4, C2F3Cl, C2Cl4, CH2=CBrCF3, CH2=CBrC2F5, CH2=CHC2F4Br, C2HCl3, C3H5Cl, C3H5I

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Please note: In addition, information concerning related publications (e.g. quantum yield studies or photolysis studies) for some of the substances are given. Send us your feedback

Authors Journal/Source Title/Paper

Data Sheet

CHBr=CH2; vinyl bromide; bromoethene;  CAS-No.: 593-60-2
D. Chadwick, D.C. Frost, A. Katrib, C.A. McDowell, R.A.N. McLean Can. J. Chem., 50, 2642-2651, (1972) Photoelectron spectra of some bromoethylenes and 2-bromopropene

J. Schander, B.R. Russell J. Am. Chem. Soc., 98, 6900-6904, (1976) Vacuum ultraviolet spectra of bromoethylene and dibromoethylenes

A. Hoxha, R. Locht, B. Leyh, D. Dehareng, K. Hottmann, H.W. Jochims, H. Baumgärtel Chemical Physics, 260, 237-247, (2000) The photoabsorption and constant ionic state spectroscopy of vinylbromide

V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, 10195-10199, (2002) Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra 

A. Fahr unpublished data, NIST, (2002) UV spectrum and cross sections of vinyl bromide (C2H3Br)

CHCl=CH2; vinyl chloride; chloroethene; CAS-No.: 75-01-4
R. Locht, B. Leyh, K. Hottmann, H. Baumgärtel Chemical Physics, 220, 207-216, (1997) The photoabsorption spectrum of vinylchloride (C2H3Cl) in the 8-12 eV range

P. Limão-Vieira, E. Vasekova, B.N. Raja Sekhar, N.J. Mason, S.V. Hoffmann Chem. Phys., 330, 265-274, (2006) VUV photoabsorption spectroscopy of vinyl chloride studied by high resolution synchrotron radiation

related data (quantum yield studies; photolysis studies, etc.)
Y. Huang, Y.-A. Yang, G.-X. He, R.J. Gordon J. Chem. Phys., 99 (4), 2752-2759, (1993) The ultraviolet photodissociation dynamics of d1-vinyl chloride

C2H3F; vinyl fluoride; fluoroethene; CAS-No.: 75-02-5
G. Bélanger, C. Sandorfy J. Chem. Phys., 55, 2055, (1971) Far-Ultraviolet Spectra of Fluoroethylenes

R. Locht, B. Leyh, D. Dehareng, H.W. Jochims, H. Baumgärtel Chem. Phys., 362, 97-108, (2009) The vacuum UV photoabsorption spectroscopy of vinyl fluoride (C2H3F): The vibrational fine structure and its analysis

CH2=CF2; 1,1-difluoroethylene; CAS-No.: 75-38-7
P. Limao-Vieira, E. Vasekova, B.N. Raja Sekhar, N.J. Mason, S.V. Hoffmann Phys. Chem. Chem. Phys., 8, 4766-4772, (2006) VUV electronic state spectroscopy of 1,1-difluoroethene and difluorochloromethane by high resolution synchrotron radiation

related data (quantum yield studies; photolysis studies, etc.)
M. Baasandorj, G. Knight, V. C. Papadimitriou, R. K. Talukdar, A. R. Ravishankara, J. B. Burkholder J. Phys. Chem. A, 114 (13), 4619-4633, (2010) Rate Coefficients for the Gas-Phase Reaction of the Hydroxyl Radical with CH2=CHF and CH2=CF2; Supporting Information from ACS

CH2=CFCl; 1-chloro-1-fluoroethylene; CAS-No.: 2317-91-1
G. Tornow, R. Locht, R. Kaufel, H. Baumgärtel, H.W. Jochims Chem. Phys., 146, 115-128, (1990) The vacuum ultraviolet photoabsorption and photoelectron spectroscopy of fluorochloroethenes. The 1,1-, cis- and trans-C2H2FCl

cis-CHCl=CHF; (Z)-1-chloro-2-fluoroethene; CAS-No.: 2268-31-7
G. Tornow, R. Locht, R. Kaufel, H. Baumgärtel, H.W. Jochims Chem. Phys., 146, 115-128, (1990) The vacuum ultraviolet photoabsorption and photoelectron spectroscopy of fluorochloroethenes. The 1,1-, cis- and trans-C2H2FCl

trans-CHCl=CHF; (E)-1-chloro-2-fluoroethene; CAS-No.: 2268-32-8
G. Tornow, R. Locht, R. Kaufel, H. Baumgärtel, H.W. Jochims Chem. Phys., 146, 115-128, (1990) The vacuum ultraviolet photoabsorption and photoelectron spectroscopy of fluorochloroethenes. The 1,1-, cis- and trans-C2H2FCl

CHI=CH2; vinyl iodide; iodoethene; CAS-No.: 593-66-8
S. Yamashita, S. Noguchi, T. Hayakawa Bull. Chem. Soc. Japan, 45 (3), 659-664, (1972) Photodecomposition of Vinyl Iodide in Gas Phase

related data (quantum yield studies; photolysis studies, etc.)
P.C. Roberge, J.A. Herman Can. J. Chem., 45, 1361-1367, (1967) Photolyse de l'iodure de vinyle pur et en solution dans le tétrachlorure de carbone. II. Rendements quantiques

CHBr=CF2; 1-bromo-2,2-difluoroethylene; CAS-No.: 359-08-0
V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, (2002), 10195-10199 Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra

CFBr=CF2; bromotrifluoroethylene; CAS-No.: 598-73-2
V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, (2002), 10195-10199 Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra 

C2F4; tetrafluoroethylene; CAS-No.: 116-14-3
J.R. Dacey, J.G.F. Littler Can. J. Chem., 47, 3871-3875, (1969) Direct photolysis of tetrafluoroethylene at 1849 A

S. Eden, P. Limão-Vieira, P. A. Kendall, N. J. Mason, J. Delwiche, M.-J. Hubin-Franskin, T. Tanaka, M. Kitajima, H. Tanaka, H. Cho, S. V. Hoffmann Chem. Phys., 297, 257-269, (2004) Electronic excitation of tetrafluoroethylene, C2F4

C2F3Cl; Chlorotrifluoroethene; CAS-No.: 79-38-9
J.R. Lacher, L.E. Hummel, E.F. Bohmfalk, J.D. Park J. Am. Chem. Soc., 72 (12), 5486-5489, (1950) The Near Ultraviolet Absorption Spectra of Some Fluorinated Derivatives of Methane and Ethylene

C2Cl4; tetrachloroethylene; tetrachloroethene; CAS-No.: 127-18-4
J.R. Lacher, L.E. Hummel, E.F. Bohmfalk, J.D. Park J. Am. Chem. Soc., 72 (12), 5486-5489, (1950) The Near Ultraviolet Absorption Spectra of Some Fluorinated Derivatives of Methane and Ethylene

S. Eden, B. Barc, N.J. Mason, S.V. Hoffmann, Y. Nunes, P. Limão-Vieira Chem. Phys., 365, 150-157, (2009) Electronic state spectroscopy of C2Cl4

CH2=CBrCF3
V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, (2002), 10195-10199 Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra 

CH2=CBrC2F5
V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, (2002), 10195-10199 Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra 

CH2=CHC2F4Br
V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, (2002), 10195-10199 Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra

C2HCl3; trichloroethylene; CAS-No.: 79-01-6
K. Li, M.I. Stefan, J.C. Crittenden Environ. Sci. Technol., 38 (24), 6685-6693, (2004) UV Photolysis of Trichloroethylene: Product Study and Kinetic Modeling

C3H5Cl; allyl chloride; 1-propene, 3-chloro-; CAS-No.: 107-05-1
related data (quantum yield studies; photolysis studies, etc.)
R.W. Phillips, D.H. Volman J. Am. Chem. Soc., 91(13), 3418, (1969) Photolysis of condensed allyl chloride

C3H5I; allyl iodide; 1-propene, 3-iodo-; CAS-No.: 556-56-9
related data (quantum yield studies; photolysis studies, etc.)
W. West, B. Paul Trans. Faraday Soc., 28, 688 - 697, (1932) The quantum yield in the photo-decomposition of the alkyl halides in non-polar solvents


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