Data Sheet
Substance: Halogenated Methanes IV (CH3Br, CH2Br2, CHBr3, CH2ClBr, CHBr2Cl, CHF2Cl, CHFCl2, CBrCl3, CH3F, CH2F2, CHF3)
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Please note: In addition, information concerning related publications (e.g. quantum yield studies or photolysis studies) for some of the substances are given. Send us your feedback
| Authors | Journal/Source | Title/Paper |
Data Sheet |
| CH3Br; methyl bromide; CAS-No.: 74-83-9 | |||
| D.E. Robbins | Geophys. Res. Lett., 3, 213-216, (1976) | Photodissociation of Methyl Chloride and Methyl Bromide in the Atmosphere |
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| A.P. Uthman, P.J. Demlein, T.D. Allston, M.C. Withiam, M.J. McClements, G.A. Takacs | J. Phys. Chem., 82, 2252-2257, (1978) | Photoabsorption Spectra of Gaseous Methyl Bromide, Ethylene Dibromide, Nitrosyl Bromide, Thionyl Chloride, and Sulfuryl Chloride |
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| S.P. Sander, M. Peterson, R.T. Watson, R. Patrick | J. Phys. Chem., 86, 1236-1240, (1982) | Kinetics studies of the HO2 + HO2 and DO2 + DO2 reactions at 298 K |
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| L.T. Molina, M.J. Molina, F.S. Rowland | J. Phys. Chem., 86, 2672-2676, (1982) | Ultraviolet Absorption Cross Sections of Several Brominated Methanes and Ethanes of Atmospheric Interest |
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| D. Gillotay P.C. Simon | Annales Geophysicae, 6, 211-215, (1988) | Ultraviolet Absorption Cross-Sections of Methyl Bromide at Stratospheric Temperatures (209 K) |
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| D. Gillotay P.C. Simon | Annales Geophysicae, 6, 211-215, (1988) | Ultraviolet Absorption Cross-Sections of Methyl Bromide at Stratospheric Temperatures (227 K) |
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| D. Gillotay P.C. Simon | Annales Geophysicae, 6, 211-215, (1988) | Ultraviolet Absorption Cross-Sections of Methyl Bromide at Stratospheric Temperatures (255 K) |
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| D. Gillotay P.C. Simon | Annales Geophysicae, 6, 211-215, (1988) | Ultraviolet Absorption Cross-Sections of Methyl Bromide at Stratospheric Temperatures (295 K) |
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| T. N. Olney, G. Cooper, Wing Fat Chan, G. R. Burton, C. E. Brion, K. H. Tan | Chem. Phys., 218, 127-149, (1997) | Absolute photoabsorption and photoionization studies of methyl bromide using dipole electron impact and synchrotron radiation PES techniques |
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| S.N. Kozlov, V.L. Orkin, R.E. Huie, M.J. Kurylo | J. Phys. Chem., A, 107, (2003), 1333-1338 | OH Reactivity and UV Spectra of Propane, n-Propyl Bromide, and Isopropyl Bromide (295 K) |
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| R. Locht, B. Leyh, H.W. Jochims, H. Baumgärtel | Chemical Physics, 317, 73-86, (2005) | The vacuum UV photoabsorption spectrum of methyl bromide (CH3Br) and its perdeuterated isotopomer CD3Br: a Rydberg series analysis |
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| F. Kwabia Tchana, D. Jacquemart, N. Lacome, I. Kleiner, J. Orphal | Journal of Molecular Spectroscopy, 235,132–143, (2006) | Absolute line intensities in methyl bromide: The 7-micrometer region |
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| CH2Br2; dibromomethane; CAS-No.: 74-95-3 | |||
| L.T. Molina, M.J. Molina, F.S. Rowland | J. Phys. Chem., 86, 2672-2676, (1982) | Ultraviolet Absorption Cross Sections of Several Brominated Methanes and Ethanes of Atmospheric Interest |
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| D. Gillotay, P.C. Simon, L. Dierickx | Proceedings of Quadrennial Ozone Symposium Goettingen, FRG, (1988) | Temperature Dependence of Ultraviolet Absorption Cross-Sections of Brominated Methanes and Ethanes (210 K) |
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| D. Gillotay, P.C. Simon, L. Dierickx | Proceedings of Quadrennial Ozone Symposium Goettingen, FRG, (1988) | Temperature Dependence of Ultraviolet Absorption Cross-Sections of Brominated Methanes and Ethanes (230 K) |
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| D. Gillotay, P.C. Simon, L. Dierickx | Proceedings of Quadrennial Ozone Symposium Goettingen, FRG, (1988) | Temperature Dependence of Ultraviolet Absorption Cross-Sections of Brominated Methanes and Ethanes (250 K) |
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| D. Gillotay, P.C. Simon, L. Dierickx | Proceedings of Quadrennial Ozone Symposium Goettingen, FRG, (1988) | Temperature Dependence of Ultraviolet Absorption Cross-Sections of Brominated Methanes and Ethanes (270 K) |
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| D. Gillotay, P.C. Simon, L. Dierickx | Proceedings of Quadrennial Ozone Symposium Goettingen, FRG, ( 1988) | Temperature Dependence of Ultraviolet Absorption Cross-Sections of Brominated Methanes and Ethanes (295 K) |
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| J.C. Mössinger, D.E. Shallcross, R.A. Cox | J. Chem. Soc., Faraday Trans., 94, 10, 1391-1396, (1998) | UV-VIS absorption cross-sections and atmospheric lifetimes of CH2Br2, CH2I2 and CH2BrI |
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| CHBr3; bromoform; CAS-No.: 75-25-2 | |||
| R.A. Cox, S.A. Penkett | University of East Anglia, Norwich, (1987) | priv. comm. (298 K) |
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| R. Meller, W. Schneider | MPI Mainz, (1988) | priv. comm. (294 K) |
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| D. Gillotay, A. Jenouvrier, B. Coquart, M.F. Merienne, P.C. Simon | Planet. Space Sci., 37, 1127-1140, (1989) | Ultraviolet Absorption Cross-Section of Bromoform in the Temperature Range 295-210 K (210 K, 230 K, 250 K, 270 K, 295 K) |
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| G.K. Moortgat, R. Meller, W. Schneider | NATO ASI Series, Vol. 17, (1993) | Temperature dependence (256-296 K) of the absorption cross-sections of bromoform in the wavelength range 285-360 nm |
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| R.K. Vatsa, H.-R. Volpp | Chem. Phys. Let., 340, 289-295, (2001) | Absorption cross-sections for some atmospherically important molecules at the H atom Lyman-alpha wavelength (121.567 nm) |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| K.D. Bayes, R.R. Friedl, S.P. Sander, D.W. Toohey | J. Geophys. Res., 108 (D3), 4095, (2003) | Measurements of quantum yields of bromine atoms in the photolysis of bromoform from 266 to 324 nm |
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| CH2ClBr; bromochloromethane; CAS-No.: 74-97-5 | |||
| V.L. Orkin, V.G. Khamaganov, A.G. Guschin, R.E. Huie, M.J. Kurylo | J. Phys. Chem., 101, 174-178, (1997) | Atmospheric Fate of Chlorobromomethane Rate Constant for the Reaction with OH, UV Spectrum, and Water Solubility |
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| CHBr2Cl; chlorodibromomethane; CAS-No.: 124-48-1 | |||
| T. Ibuki, A. Hiraya, K. Shobatake | J. Chem. Phys., 96, 8793, (1992) | Vacuum ultraviolet absorption spectra and photodissociative excitation of CHBr2Cl and CHBrCl2 |
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| M. Bilde, T.J. Wallington, C. Ferronato, J.J. Orlando, G.S. Tyndall, E. Estupinan, S. Haberkorn | J. Phys. Chem. A, 102 (11), 1976-1986, (1998) | Atmospheric Chemistry of CH2BrCl, CHBrCl2, CHBr2Cl, CF3CHBrCl, and CBr2Cl2 |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| F. Taketani, K. Takahashi, Y. Matsumi | J. Phys. Chem. A, 109 (12), 2855-2860, (2005) | Quantum Yields for Cl(2Pj) Atom Formation from the Photolysis of Chlorofluorocarbons and Chlorinated Hydrocarbons at 193.3 nm |
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| CHF2Cl; difluorochloromethane; F-22; CAS-No.: 75-45-6 | |||
| J. Doucet, P. Sauvageau, C. Sandorfy | J. Chem. Phys., 58, 3708, (1973) | Vacuum ultraviolet and photoelectron spectra of fluoro-chloro derivatives of methane |
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| R.K. Vatsa, H.-R. Volpp | Chem. Phys. Let., 340, 289-295, (2001) | Absorption cross-sections for some atmospherically important molecules at the H atom Lyman-alpha wavelength (121.567 nm) |
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| P. Limao-Vieira, E. Vasekova, B. N. Raja Sekhar, N. J. Mason, S. V. Hoffmann | Phys. Chem. Chem. Phys., 8, 4766 - 4772, (2006) | VUV electronic state spectroscopy of 1,1-difluoroethene and difluorochloromethane by high resolution synchrotron radiation |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| R. A. Brownsword, M. Hillenkamp, T. Laurent, R. K. Vatsa, H.-R. Volpp, J. Wolfrum | J. Phys. Chem. A, 101 (6), 995-999, (1997) | Photodissociation Dynamics of CHF2Cl after Photoexcitation at the Lyman-alpha Wavelength (121.6 nm) |
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| CHFCl2; fluorodichloromethane; F-21; CAS-No.: 75-43-4 | |||
| D.E. Robbins, R.S. Stolarski | Geophys. Res. Lett., 3, 603-606, (1976) | Comparison of stratospheric ozone destruction by fluorocarbons 11, 12, 21, and 22 |
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| R.G. Green, R.P. Wayne | J. Photochem., 6, 375-377, (1976/77) | Vacuum ultraviolet absorption spectra of halogenated methanes and ethanes |
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| C. Hubrich, C. Zetzsch, F. Stuhl | Ber. Bunsenges. Phys. Chem., 81, 437-442, (1977) | Absorptionsspektren von halogenierten Methanen im Bereich von 275 bis 160 nm bei Temperaturen von 298 und 208 K |
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| B.E. Cole, R.N. Dexter | J. Quant. Spectrosc. Radiat. Transfer, 19, 303-309, (1978) | Photoabsorption cross sections for chlorinated methanes and ethanes between 46 and 100 Å |
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| P.C. Simon, D. Gillotay, N. Vanlaethem-Meurée, J. Wisemberg | J. Atmos. Chem., 7, 107-135, (1988) | Ultraviolet absorption cross-sections of chloro- and chlorofluoro-methanes at stratospheric temperatures |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| F. Taketani, K. Takahashi, Y. Matsumi | J. Phys. Chem. A, 109 (12), 2855-2860, (2005) | Quantum Yields for Cl(2Pj) Atom Formation from the Photolysis of Chlorofluorocarbons and Chlorinated Hydrocarbons at 193.3 nm |
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| CBrCl3; bromotrichloromethane; CAS-No.: 75-62-7 | |||
| T. Sumiyoshi, K. Tsugaru, M. Katayama | Chemistry Letters, 11 (9), 1431-1432, (1982) | Picosecond pulse radiolysis of fluorotrichloromethane and bromotrichloromethane |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| Y.-J. Jung, M. S. Park, Y. S. Kima, K.-H. Jung, H.-R. Volpp | J. Chem. Phys., 111, 4005-4012, (1999) | Photodissociation of CBrCl3 at 234 and 265 nm: Evidence of the curve crossing |
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| CH3F; methyl fluoride; HFC-41; CAS-No.: 593-53-3 | |||
| C.Y.R. Wu, L.C. Lee, D.L. Judge | J. Chem. Phys., 71, 5221-5226, (1979) | Photoabsorption cross sections of CH3F, CHF3, CH3Cl, and CF2Cl2 from 175 to 760 Å |
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| Terry N. Olney, Glyn Cooper, Wing Fat Chan, Gordon R. Burton, C. E. Brion, K. H. Tan | Chem. Phys., 189, 733-756, (1994) | Quantitative studies of the photoabsorption, photoionization, and ionic photofragmentation of methyl fluoride at VUV and soft X-ray energies (7-250 eV) using dipole electron scattering and synchrotron radiation |
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| R. Locht, B. Leyh, A. Hoxha, D. Dehareng, H.W. Jochims, H. Baumgärtel | Chem. Phys., 257, 283-299, (2000) | About the vacuum UV photoabsorption spectrum of methyl fluoride (CH3F): the fine structure and its vibrational analysis |
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| CH2F2; difluoromethane; F 32; CAS-No.: 75-10-5 | |||
| P. Wagner, A.B.F. Duncan | J. Am. Chem. Soc., 77 (9), 2609-2610, (1955) | The Vacuum Ultraviolet Absorption Spectrum of Difluoromethane |
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| T. Pradeep, D.A. Shirley | J. Electr. Spectr. Rel. Phenomena, 66, 125-138, (1993) | High resolution photoelectron spectroscopy of CH2F2, CH2Cl2 and CF2Cl2 using supersonic molecular beams |
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| Aparna Shastri, B. N. Raja Sekhar, Param Jeet Singh, M. N. Deo | Spectroscopy Letters, 42 (5), 219-225, (2009) | Vacuum Ultraviolet Absorption Spectrum of Difluoromethane Reinvestigated |
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| CHF3; trifluoromethane; fluoroform; CAS-No.: 75-46-7 | |||
| C.Y.R. Wu, L.C. Lee, D.L. Judge | J. Chem. Phys., 71, 5221-5226, (1979) | Photoabsorption cross sections of CH3F, CHF3, CH3Cl, and CF2Cl2 from 175 to 760 Å |
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| M. Suto, L.C. Lee | J. Chem. Phys., 79, 1127-1133, (1983) | Emission spectra of CF3 radicals. V. Photodissociation of CF3H, CF3Cl, and CF3Br by vacuum ultraviolet |
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| H. Biehl, K.J. Boyle, R.P. Tuckett, H. Baumgärtel, H.W. Jochims | Chem. Phys., 214, 367-381, (1997) | Vacuum-UV fluorescence spectroscopy of CF3X (X=F, H, Cl, Br) in the range 10-30 eV |
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