Data Sheet
No. 1195, 455-464, (1956)
Substances: Chlorine Oxides (Cl2O, Cl2O2, Cl2O3, Cl2O4, Cl2O6, Cl2O7, ClClO2, ClO, ClO-, ClOO, OClO, OClO-, ClO3, ClO4)
The relevant Spectra Data are available (for registered users) at: Spectra Service
Please note: In addition, information concerning related publications (e.g. quantum yield studies or photolysis studies) for some of the substances are given. Send us your feedback
| Authors | Journal/Source | Title/Paper |
Data Sheet |
| Cl2O ; dichlorine oxide; CAS-No.: 7791-21-1 | |||
| C.F. Goodeve, J.I. Wallace | Trans. Faraday Soc., 26, 254, (1930) | The absorption spectrum of chlorine monoxide |
|
| W. Finkelnburg, H.J. Schumacher, G. Stieger | Z. Phys. Chem., 15, 127-156, (1931) | Das Spektrum und der photochemische Zerfall des Chlormonoxids |
|
| H. Martin, R. Gareis | Z. Elektrochem., 60, 959-964, (1956) | Die Kinetik der Reaktion von ClO2 mit NO2 in der Loesungsphase |
|
| C.-L. Lin | J. Chem. Eng. Data, 21, 411-413, (1976) | Extinction Coefficients of Chlorine Monoxide and Chlorine Heptoxide |
|
| L.T. Molina, M.J. Molina | J. Phys. Chem., 82, 2410-2414, (1978) | Ultraviolet Spectrum of HOCl |
|
| H.-D. Knauth, H. Alberti, H. Clausen | J. Phys. Chem., 83, 1604-1612, (1979) | Equilibrium Constant of the Gas Reaction Cl2O + H2O = 2HOCl and the Ultraviolet Spectrum of HOCl |
|
| F.G. Simon | Ph.D.-Thesis, (1989) | University of Mainz, Germany, 1989 |
|
| F.G. Simon, W. Schneider, G.K. Moortgat, J.P. Burrows | J. Photochem. Photobiol., 55, 1-23, (1990) | A Study of the ClO Absorption Cross-Section Between 240 and 310 nm and the Kinetics of the Self-Reaction at 300 K |
|
| J.B. Nee | J. Quant. Spectros. Radiat. Transfer, 46, 55-58, (1991) | Ultraviolet Absorption of Cl2O |
|
| F. Motte-Tollet, M. -P. Ska, G. M. Marston, I. C. Walker, M. R. F. Siggel, J. M. Gingell, L. Kaminski, K. Brown, N. J. Mason | Chem. Phys. Lett., 275, 298-306, (1997) | Absolute cross sections for the VUV optical absorption of Cl2O in the 6.5–9.7 eV energy range |
|
| R. Flesch, M. C. Schürmann, J. Plenge, M. Hunnekuhl, H. Meiss, M. Bischof, E. Rühl | Phys. Chem. Chem. Phys., 1, 5423 - 5428, (1999) | Absolute photoionization cross sections of the primary photofragments of chlorine dioxide and dichlorine monoxide |
|
| D. K. Papanastasiou, K. J. Feierabend, J. B. Burkholder | J. Chem. Phys., 134, 204310, (2011) | Cl2O photochemistry: Ultraviolet/vis absorption spectrum temperature dependence and O(3P) quantum yield at 193 and 248 nm |
|
| related data (quantum yield studies; photolysis studies etc.) | |||
| Y. Tanaka, M. Kawasaki, Y. Matsumi, H. Fujiwara, T. Ishiwata, L.J. Rogers, R.N. Dixon, M.N.R. Ashfold | J. Chem. Phys., 109, 1315, (1998) | The ultraviolet photodissociation of Cl2O at 235 nm and of HOCl at 235 and 266 nm |
|
| G. D. Smith, F. M. G. Tablas, L. T. Molina, M. J. Molina | J. Phys. Chem. A, 105 (38), 8658-8664, (2001) | Measurement of Relative Product Yields from the Photolysis of Dichlorine Monoxide (Cl2O) |
|
| M. Roth, C. Maul, K.-H. Gericke | J. Phys. Chem. A, 108, 7954-7964, (2004) | Photodissociation Dynamics of Cl2O: Interpretation of Electronic Transitions |
|
| M.H. Palmer, A.D. Nelson | Chem. Phys., 354, 94-105, (2008) | The electronic states of chlorine oxide (Cl2O) studied by ab initio configuration interaction methods and spectroscopy |
|
| P. Zou, J. Shu, S. W. North | J. Photochem. Photobiol. A: Chem., 209 (1), 56-60, (2009) | The three-body dissociation dynamics of Cl2O at 248 and 193 nm |
|
| Cl2O2 ; ClOOCl; dichlorine dioxide; CAS-No.: CAS-No.: 12292-23-8 | |||
| L.T. Molina, M.J. Molina | J. Phys. Chem., 91, 433-436, (1987) | Production of Cl2O2 from the Self-Reaction of the ClO Radical (240 K) |
|
| T. Permien, R. Vogt, R.N. Schindler | Air Pollution Research Report, 17, 149-154, (1988) | Absorption Spectra of HOCl and Cl2O2 (235 K) |
|
| J.B. Burkholder | priv. comm., (1988) | NOAA, 1988 (250 K) |
|
| R.A. Cox, G.D. Hayman | Nature, 332, 796-800, (1988) | The Stability and Photochemistry of Dimers of the ClO Radical and Implications for Antarctica (265 K) |
|
| W.B. DeMore, E. Tschuikow-Roux | J. Phys. Chem., 94, 5856-5860, (1990) | Ultraviolet Spectrum and Chemical Reactivity of the ClO Dimer (206 K) |
|
| R. Vogt, R.N. Schindler | Air Pollution Research Report, 34, 167-172, (1990) | Photochemical Investigations on the Atmospheric Chlorine-Reservoir Compounds (230 K) |
|
| J.B. Burkholder, J.J. Orlando, C.J. Howard | J. Phys. Chem., 94, 687-695, (1990) | Ultraviolet Absorption Cross Section of Cl2O2 between 210 and 410 nm (250 K) |
|
| K.J. Huder, W.B. DeMore | J. Phys. Chem., 99, 3905-3908, (1995) | Absorption cross sections of the ClO dimer |
|
| W.J. Bloss, S.L. Nickolaisen, R.S. Salawitch, R.R. Friedl, S.P. Sander | J. Phys.Chem., A, 105, 11226-11239, (2001) | Kinetics of the ClO Self-Reaction and 210 nm Absorption Cross Section of the ClO Dimer |
|
| J.R. McKeachie, M.F. Appel, U. Kirchner, R.N. Schindler,T. Benter | J. Phys. Chem. B, 108 (43), 16786-16797, (2004) | Observation of a Heterogeneous Source of OClO from the Reaction of ClO Radicals on Ice |
|
| F.D. Pope, J.C. Hansen, K.D. Bayes, R.R. Friedl, S.P. Sander | J. Phys. Chem. A, 111, 4322-4332, (2007) | The ultraviolet absorption spectrum of chlorine peroxide, ClOOCl |
|
| H.-Y. Chen, C.-Y. Lien, W.-Y. Lin, Y. T. Lee, J. J. Lin | Science, 324, 781-784, (2009) | UV absorption cross sections of ClOOCl are consistent with ozone degradation models |
|
| M. von Hobe, F. Stroh, H. Beckers, T. Benter, H. Willner | Phys. Chem. Chem. Phys., 11, 1571 - 1580, (2009) | The UV/Vis absorption spectrum of matrix-isolated dichlorine peroxide, ClOOCl |
|
| D. K. Papanastasiou, V. C. Papadimitriou, D. W. Fahey, J. B. Burkholder | J. Phys. Chem. A, 113 (49), 13711-13726, (2009) | UV Absorption Spectrum of the ClO Dimer (Cl2O2) between 200 and 420 nm |
|
| D. M. Wilmouth, T. F. Hanisco, R. M. Stimpfle, J. G. Anderson | J. Phys. Chem. A, 113 (51), 14099-14108, (2009) | Chlorine-Catalyzed Ozone Destruction: Cl Atom Production from ClOOCl Photolysis |
|
| related data (quantum yield studies; photolysis studies etc.) | |||
| T. A. Moore, M. Okumura, J. W. Seale, T. K. Minton | J. Phys. Chem. A, 103 (12), 1691-1695, (1999) | UV Photolysis of ClOOCl |
|
| J. Plenge, R. Flesch, S. Kuehl, B. Vogel, R. Mueller, F. Stroh, E. Ruehl | J. Phys. Chem. A, 108 (22), 4859 -4863, (2004) | Ultraviolet Photolysis of the ClO Dimer |
|
| Cl2O3 ; dichlorine trioxide; CAS-No.: 17496-59-2 | |||
| F. J. Lipscomb, R. G. W. Norrish, B. A. Thrush | Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, Vol. 233, No. 1195, 455-464, (1956) |
The Study of Energy Transfer by Kinetic Spectroscopy. I. The Production of Vibrationally Excited Oxygen |
|
| G.D. Hayman, R.A. Cox | Chem. Phys. Lett., 155, 1-7, (1989) | UV Absorption Spectrum and Thermochemistry of Cl2O3 Formed in the Photolysis of OClO-Containing Mixtures at Low Temperatures |
|
| J. B. Burkholder, R. L. Mauldin, , III R. J. Yokelson, S. Solomon, A. R. Ravishankara | J. Phys. Chem., 97(29); 7597-7605, (1993) | Kinetic, thermochemical, and spectroscopic study of chlorine oxide (Cl2O3) |
|
| T.J. Green, M. Islam, P.Guest, K. Hickson, C.E. Canosa- Mas and R.P. Wayne | Phys. Chem. Chem. Phys. 5, 5409-5418, (2003) | A discharge flow study of Cl2O3 |
|
| M. H. Harwood, D. M. Rowley, R. A. Freshwater, R. A. Cox, R. L. Jones | J. Chem. Soc., Faraday Trans., 91, 3027 - 3032, (1995) | A spectroscopic study of Cl2O3 |
|
| Cl2O4 ; dichlorine tetroxide; CAS-No.: 27218-16-2 | |||
| M.I. Lopez, J.E. Sicre | J. Phys. Chem., 92, 563-564, (1988) | Ultraviolet Spectrum of Chlorine Perchlorate |
|
| T.J. Green, M. Islam, C. Canosa-Mas, G. Marston, R.P. Wayne | J. Photochemistry and Photobiology A: Chemistry, 162, 353-370, (2004) | Higher oxides of chlorine: absorption cross sections of Cl2O6 and Cl2O4, the decomposition of Cl2O6, and the reactions of OClO with O and O3 |
|
| Cl2O6 ; dichlorine hexoxide; CAS-No.: 12442-63-6 | |||
| M. Jansen, G. Schatte, K.M. Tobias, H. Willner | Inorg. Chem., 27, 1703-1706, (1988) | Properties of dichlorine hexaoxide in the gas phase and in low temperature matrices |
|
| M.I. Lopez, J.E. Sicre | J. Phys. Chem., 94, 3860-3863, (1990) | Physicochemical Properties of Chlorine Oxides. 1. Composition, Ultraviolet Spectrum, and Kinetics of the Thermolysis of Gaseous Dichlorine Hexoxide |
|
| T.J. Green, M. Islam, C. Canosa-Mas, G. Marston, R.P. Wayne | J. Photochemistry and Photobiology A: Chemistry, 162, 353-370, (2004) | Higher oxides of chlorine: absorption cross sections of Cl2O6 and Cl2O4, the decomposition of Cl2O6, and the reactions of OClO with O and O3 |
|
| Cl2O7; chlorine heptoxide; CAS-No.: 12015-53-1 | |||
| C. F. Goodeve, B. A. M. Windsor | Trans. Faraday Soc., 32, 1518-1519, (1936) | The absorption spectrum of chlorine heptoxide |
|
| Chorng-Lieh Lin | J. Chem. Eng. Data, 21 (4), 411-413, (1976) | Extinction coefficients of chlorine monoxide and chlorine heptoxide |
|
| ClClO2 | |||
| H.S.P. Mueller, H. Willner | Ber. Bunsenges. Phys. Chemie, 96, 427-431, (1992) | Gas Phase Studies on Chloryl Chloride, ClClO2 |
|
| ClO ; chlorine oxide; CAS-No.: 14989-30-1 | |||
| Johnston, H.S., E.D. Morris, J. Van den Bogaerde | J. Am. Chem. Soc., 91, 7712-7727, (1969) | Molecular Modulation Kinetic Spectrometry. ClOO and ClO2 Radicals in the Photolysis of Clorine in Oxygen (298 K) |
|
| M. Mandelman, R.W. Nicholls | J. Quant. Spectrosc. Radiat. Transfer, 17, 483-491, (1977) | The Absorption Cross Section and f-values for the v''=0 Progression of Bands and Associated Continuum for the ClO (A2Pi-X2Pi) System (298 K) |
|
| Rigaud, P., B. Leroy, G. Le Bras, G. Poulet, J.L. Jourdain, J. Combourieu | Chem. Phys. Lett. 46 (1977) 161 | About the Identification of Some UV Atmospheric Absorptions Laboratory Study of ClO (298 K) |
|
| Jourdain, J.L., G. Le Bras, G. Poulet, J. Combourieu, P. Rigaud, B. Leroy | Chem. Phys. Lett., 57 (1978), 109-112 | UV Absorption Spectrum Of ClO (A2P-X2P) up to the (1,0) Band (298 K) |
|
| Sander, S.P., and R.R. Friedl | J. Phys. Chem., 93 (1989), 4764-4771 | Kinetics and Product Studies of the Reaction ClO + BrO Using Flash Photolysis-Ultraviolet Absorption (298 K) |
|
| Trolier, M., R.L. Mauldin III, and A.R. Ravishankara | J. Phys. Chem., 94 (1990), 4896-4907 | Rate Coefficients for the Termolecular Channel of the Self-Reaction of ClO (263 K) |
|
| Simon, F.G., W. Schneider, G.K. Moortgat, and J.P. Burrows | J. Photochem. Photobiol., 55 (1990), 1-23 | A Study of the ClO Absorption Cross-Section Between 240 and 310 nm and the Kinetics of the Self-Reaction at 300 K (300 K) |
|
| Howie W.H., I.C. Lane, S.M. Newman, D.A. Johnson, A.J. Orr-Ewing | Phys. Chem. Chem. Phys., 1, (1999), 3079-3085 | The UV absorption of ClO |
|
| R. Kopitzky, H. Grothe, H. Willner | Chemistry - A European Journal, 8 (24), 5601-5621, (2002) | Chlorine Oxide Radicals ClOx (x=1-4) Studied by Matrix Isolation Spectroscopy |
|
| related data (quantum yield studies; photolysis studies, etc.) | |||
| F.H.C. Edgecombe, R.G.W. Norrish, B.A. Thrush | Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, Vol. 243, No. 1232, 24-32, (1957) | The flash photolysis of chlorine monoxide |
|
| H. F. Davis, Y. T. Lee | J. Phys. Chem., 100, 30-34, (1996) | Photodissociation Dynamics of ClO Radicals at 248 nm |
|
| Hahkjoon Kim, Jiho Park, Tracy C. Niday, Simon W. North | J. Chem. Phys., 123, 174303, (2005) | The UV photodissociation dynamics of ClO radical using velocity map ion imaging |
|
| ClO-; chlorine oxide anion | |||
| M.K. Gilles, M.L. Polak, W.C. Lineberger | J. Chem. Phys., 96, 8012-8020, (1992) | Photoelectron spectroscopy of the halogen oxide anions FO-, ClO-, BrO-, IO-, OClO-, and OIO- |
|
| ClOO | |||
| H.S. Johnston, E.D. Morris, J. Van den Bogaerde | J. Am. Chem. Soc., 91, 7712-7727, (1969) | Molecular Modulation Kinetic Spectrometry. ClOO and ClO2 Radicals in the Photolysis of Chlorine in Oxygen |
|
| S. Baer, H. Hippler, R. Rahn, M. Siefke, N. Seitzinger, J. Troe | J. Chem.Phys., 95, 6463-6470, (1991) | Thermodynamic and Kinetic Properties of the Reaction Cl+O2+M<=> ClOO+M in the range of 160-300 K and 1-1000 bar |
|
| R.L. Mauldin III, J.B. Burkholder, A.R. Ravishankara | J. Phys. Chem., 96, 2582-2588, (1992) | A Photochemical, Thermodynamic, and Kinetic Study of ClOO |
|
| OClO ; ClO2; chlorine dioxide; CAS-No.: 10049-04-4 | |||
| Z.W. Ku | Phys. Rev., 44, 376-382, (1933) | The Absorption Spectrum of Chlorine Dioxide |
|
| H. Martin, R. Gareis | Z. Elektrochem., 60, 959, (1965) | Die Kinetik der Reaktion von ClO2 mit NO2 in der Lösungsphase |
|
| C. M. Humphries, A. D. Walsh, P. A. Warsop | Discuss. Faraday Soc., 35, 137-143, (1963) | Absorption spectrum of chlorine dioxide in the vacuum ultra-violet |
|
| C.C. Hong, W.H. Rapson | Can. J. Chem., 46, 2061- 2064, (1968) | Analysis of chlorine dioxide, chlorous acid, chlorite, chlorate, and chloride in composite mixtures |
|
| N. Basco, S.K. Dogra | Proc. Roy. Soc. London A, 323, 29-68, (1971) | Reactions of halogen oxides studied by flash photolysis. I. The flash photolysis of chlorine dioxide |
|
| N. Basco, R.D. Morse | Defense Technical Information Center, Canada, Accession No.: AD0782591, (1973) | Reactions of Halogen Oxide Studied by Flash Photolysis. IV. Vacuum Ultraviolet Kinetic Spectroscopy Studies on Chlorine Dioxide |
|
| N. Basco, R.D. Morse | Proc. Roy. Soc. London A, 336, 495-505, (1974) | Reactions of halogen oxides studied by flash photolysis. IV. Vacuum ultraviolet kinetic studies on chlorine dioxide |
|
| H.D. Knauth, H. Alberti, H. Clausen | J. Phys. Chem., 83, 1604-1612, (1979) | Equilibrium Constant of the Gas Reaction Cl2O+H2O<->2HOCl and the Ultraviolet spectrum of HOCl |
|
| R. A. Barton, R. A. Cox, T. J. Wallington | J. Chem. Soc., Faraday Trans., 1, 80, 2737 - 2743, (1984) | Novel ultraviolet product spectra in the photolysis of chlorine dioxide |
|
| A. Wahner, G.S. Tyndall, A.R. Ravishankara | J. Phys. Chem., 91, 2734-2738, (1987) | Absorption Cross sections of OClO as a Function of Temperature in the Wavelength range of 240-480 nm |
|
| R. Flesch, E. Ruehl, K. Hottmann, H. Baumgaertel | J. Phys. Chem., 97 (4), 837-844, (1993) | Photoabsorption and photoionization of chlorine dioxide |
|
| R. Flesch, M. C. Schürmann, J. Plenge, M. Hunnekuhl, H. Meiss, M. Bischof, E. Rühl | Phys. Chem. Chem. Phys., 1, 5423-5428, (1999) | Absolute photoionization cross sections of the primary photofragments of chlorine dioxide and dichlorine monoxide |
|
| H. Kromminga, J. Orphal, P. Spietz, S. Voigt, J.P. Burrows | J. Photochem. Photobiol. A: Chem., 157, 149-160, (2003) | New measurements of OClO absorption cross-sections in the 325–435 nm region and their temperature dependence between 213 and 293 K |
|
| related data (quantum yield studies; photolysis studies, etc.) | |||
| V. Vaida, J.D. Simon | Science, 268, 1443-1448, (1995) | The Photoreactivity of Chlorine Dioxide |
|
| H.F. Davis, Y.T. Lee | J. Chem. Phys., 105 (18), 8142-8163, (1996) | Photodissociation dynamics of OClO |
|
| A. Furlan, H. A. Scheld, J. R. Huber | J. Chem. Phys., 106, 6538, (1997) | The photodissociation dynamics of OClO between 306 and 370 nm: Fragment translational energy release and recoil anisotropy |
|
| M. Roth, C. Maul, K.-H. Gericke | J. Chem. Phys., 107 (24), 10582-10591, (1997) | Photodissociation dynamics of OClO: O(3PJ) state and energy distributions |
|
| J. Thogersen, C. L. Thomsen, J. Aa. Poulsen, S. R. Keiding | J. Phys. Chem. A, 102 (23), 4186 -4191, (1998) | Chemical Reactions in Liquids: Photolysis of OClO in Water |
|
| C. L. Thomsen, P. J. Reid, S. R. Keiding | J. Am. Chem. Soc., 122 (51), 12795 -12801, (2000) | Quantum Yield for ClOO Formation following Photolysis of Aqueous OClO |
|
| A.E. Croce, M.I. Lopez, J.E. Sicre | Journal of Photochemistry Photobiology A: Chemistry, 196, 67–76, (2008) | The photochemical decomposition of gaseous OClO at 436 nm: Dependence of products distribution on total pressure |
|
| OClO-; chlorine dioxide anion | |||
| M.K. Gilles, M.L. Polak, W.C. Lineberger | J. Chem. Phys., 96, 8012-8020, (1992) | Photoelectron spectroscopy of the halogen oxide anions FO-, ClO-, BrO-, IO-, OClO-, and OIO- |
|
| ClO3; chlorine trioxide; CAS-No.: 13932-10-0 | |||
| C. F. Goodeve, F. D. Richardson | Trans. Faraday Soc., 33, 453 - 457, (1937) | The absorption spectrum of chlorine trioxide and chlorine hexoxide |
|
| R. Kopitzky, H. Grothe, H. Willner | Chemistry - A European Journal, 8 (24), 5601-5621, (2002) | Chlorine Oxide Radicals ClOx (x=1-4) Studied by Matrix Isolation Spectroscopy |
|
| ClO4; chlorine tetraoxide | |||
| R. Kopitzky, H. Grothe, H. Willner | Chemistry - A European Journal, 8 (24), 5601-5621, (2002) | Chlorine Oxide Radicals ClOx (x=1-4) Studied by Matrix Isolation Spectroscopy |
|