Data Sheet
Substances: Br2, Cl2,
F2, I2, ClF,
BrCl,
ICl, IBr
The relevant Spectra Data are available (for registered
users) at: Spectra
Service
Please note: In addition, information concerning related publications (e.g. quantum yield studies or photolysis studies) for some of the substances are given. Send us your feedback
| Authors | Journal/Source | Title/Paper |
Data Sheet |
| Br2; bromine; CAS-No.: 7726-95-6 | |||
| A.P. Acton, R.G. Aickin, N.S. Bayliss | J. Chem. Phys., 4, 474-479, (1936) | The continuous absorption spectrum of bromine: A new interpretation |
|
| N.S. Bayliss, A.R.H. Cole, B.G. Green | Australian J. Scientific Res. A Physical Sciences, 1 (4), 472-479, (1948) | The Visible Absorption Spectrum of Bromine in Solution |
|
| D.J. Seery, D. Britton | J. Phys. Chem., 68 (8), 2263-2266, (1964) | The Continuous Absorption Spectra of Chlorine, Bromine, Bromine Chloride, Iodine Chloride, and Iodine Bromide |
|
| V. McMillan | Calvert and Pitts, Photochemistry, John Wiley & Sons, London, p. 184, (1966) | (298 K) |
|
| A.A. Passchier, J.D. Christian, and N.W. Gregory | J. Phys. Chem., 71, 937-942, (1967) | The Ultraviolett-Visible Absorption Spectrum of Bromine between Room Temperature and 440° |
|
| H. Gutmann, M. Lewin, B. Perlmutter-Hayman | J. Phys. Chem., 72 (10), 3671-3673, (1968) | Ultraviolet absorption spectra of chlorine, bromine, and bromine chloride in aqueous solution |
|
| C. Eden, H. Feilchenfeld, S. Manor | Analytical Chemistry, 41, 1150-1151, (1969) | Simultaneous spectrophotometric determination of nitrosyl bromide and bromine |
|
| T. Kennedy, R.S. Sinclair, T.J. Sinclair | J. Inorg. Nucl. Chem., 33, 2369-2376, (1971) | The U.V. spectrum and photolysis of phosphorus halides in hydrocarbon solvents - II: Phosphorus tribromide and phosphorus pentabromide in cyclohexane |
|
| W.Y. Wen, R.M. Noyes | J. Phys. Chem., 76, 1017-1018, (1972) | Ultraviolet spectra of single and double molecules of gaseous bromine |
|
| C.P. Hemenway, T.G. Lindeman, J.R. Wiesenfeld | J. Chem. Phys., 70, 3560-3561, (1979) | Measurement of the A 3PI 1u <-- X 1SIGMA+g continuum absorptivity in Br2 |
|
| W. Schneider, G. von Helden | priv. comm., (1991) | MPI Mainz, 1991 (294 K) |
|
| S. Hubinger, J.B. Nee | J. Photochem. Photobiol., 86, 1-7, (1995) | Absorption Spectra of Cl2, Br2 and BrCl between 190 and 600 nm |
|
| R. C. Sharmaa, H.-Y. Huang, W.-T. Chuang, K.-C. Lin | Spectrochimica Acta Part A: Mol. Biomol. Spectroscopy, 61, 2115-2120, (2005) | Continuum and discrete pulsed cavity ring down laser absorption spectra of Br2 vapor |
|
| Additional datasheets and spectra of Br2 are available at our Spectra Service |
| Cl2; chlorine; CAS-No.: 7782-50-5 | |||
| E.R. Laird | Astrophys. J., 14, 85-115, (1901) | The absorption spectrum of chlorine |
|
| H. von Halban, K. Siedentopf | Z. Elektrochem., 28, 496-499, (1922) | Die Lichtabsorption des Chlors |
|
| G.E. Gibson, N.S. Bayliss | Phys. Rev., 44, 188-192, (1933) | Variation with Temperature of the Continuous Absorption Spectrum of Diatomic Molecules: Part I. Experimental, The Absorption Spectrum of Chlorine |
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| F.W. Jones, W. Spooner | Trans. Faraday Soc., 31, 811-813, (1935) | Absorption of Light by Gaseous Chlorine in the Wavelength Region 5040 A.U. to 5320 A.U. |
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| W.C. Fergusson, L. Slotin, D.W.G. Style | Trans. Faraday Soc., 32, 956-962, (1936) | The absorption spectrum of aqueous chlorine and hydrogen peroxide vapor |
|
| R.G. Aickin, N.S. Bayliss | Trans. Faraday Soc., 33, 1333-1338, (1937) | The Continuous Absorption Spectrum of Chlorine in the Region 4000-5000 A |
|
| H. Martin, R. Gareis | Z. Elektrochem., 60, 959-964, (1956) | Die Kinetik der Reaktion von ClO2 mit NO2 in der Loesungsphase |
|
| D.J. Seery, D. Britton | J. Phys. Chem., 68 (8), 2263-2266, (1964) | The Continuous Absorption Spectra of Chlorine, Bromine, Bromine Chloride, Iodine Chloride, and Iodine Bromide |
|
| T. A. Jacobs, R. R. Giedt | J. Quant. Spectr. Rad. Transfer, 5 (3), 457-458, (1965) | Absorption coefficients of Cl2 at high temperatures |
|
| H. Gutmann, M. Lewin, B. Perlmutter-Hayman | J. Phys. Chem., 72 (10), 3671-3673, (1968) | Ultraviolet absorption spectra of chlorine, bromine, and bromine chloride in aqueous solution |
|
| H.-D. Knauth, H. Alberti, H. Clausen | J. Phys. Chem., 83, 1604-1612, (1979) | Equilibrium Constant of the Gas Reaction Cl2O + H2O = 2HOCl and the Ultraviolet Spectrum of HOCl |
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| C. Roxlo, A. Mandl | J. Appl. Phys., 51, 2969-2972, (1980) | Vacuum Ultraviolet Absorption Cross Sections for Halogen Containing Molecules |
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| A.E. Douglas | Can. J. Phys./Rev. can. phys., 59(6): 835-840, (1981) | The absorption spectrum of Cl2 in the vacuum ultraviolet |
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| J.B. Burkholder, E.J. Bair | J. Phys. Chem., 87, 1859-1863, (1983) | Potential Energy Parameters and Shapes of the Vibrational Components of the 345-nm System of Chlorine |
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| J. Heicklen, J. Desai, A. Bahta, C. Harper, R. Simonaitis | J. Photochem., 34, 117-135, (1986) | The temperature and wavelength dependence of the photo-oxidation of propionaldehyde |
|
| P. Gürtler, H. Kunz, J. Le Calve | J. Chem. Phys., 91, 6020-6028, (1989) | Vacuum ultraviolet spectroscopy of the Cl2 molecule trapped in pure neon, pure argon, or mixed neon–argon matrices |
|
| J.A. Ganske, H.N. Berko, B.J. Finlayson-Pitts | J. Geophys. Res., 97, 7651-7656, (1992) | Absorption Cross Sections for Gaseous ClNO2 and Cl2 at 298 K: Potential Organic Oxidant Source in the Marine Troposphere |
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| D. Maric, J.P. Burrows, R. Meller, and G.K. Moortgat | J. Photochem. Photobiol. A: Chem., 70, 205-214, (1993) | A Study of the UV-Visible Absorption Spectra of Molecular Chlorine |
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| S. Hubinger, J.B. Nee | J. Photochem. Photobiol., 86, 1-7, (1995) | Absorption Spectra of Cl2, Br2 and BrCl between 190 and 600 nm |
|
| Y. Chen, L. Zhu | J. Phys. Chem. A, 105, 9689-9696, (2001) | The wavelength dependence of the photodissociation of propionaldehyde in the 280-330 nm region |
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| Y. Chen, L. Zhu, J.S. Francisco | J. Phys. Chem. A, 106, 7755-7763, (2002) | Wavelength-dependent photolysis of n-butyraldehyde and i-butyraldehyde in the 280-330-nm region |
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| J. Tellinghuisen | J. Phys. Chem. A, 107, 753-757, (2003) | Precise equilibrium constants from spectrophotometric data: BrCl in Br2/Cl2 |
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| Y. Chen, L. Zhu | J. Phys. Chem. A, 107, 4643-4651, (2003) | Wavelength-dependent photolysis of glyoxal in the 290-420 nm region |
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| I. A. K. Young, C. Murray, C. M. Blaum, R. A. Cox, R. L. Jones, F. D. Pope | Phys. Chem. Chem. Phys., 13, 15318-15325, (2011) | Temperature dependent structured absorption spectra of molecular chlorine |
|
| related data (quantum yield studies; photolysis studies, etc.) | |||
| G.E. Busch, R.T. Mahoney, R.I. Morse, K.R. Wilson | J. Chem. Phys. 51, 449 (1969) | Translational Spectroscopy: Cl2 Photodissociation |
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| J. Fournier, F. Salama, R. J. Le Roy | J. Phys. Chem., 89(16), 3530-3534, (1985) | Ultraviolet photolysis and internal dynamics of molecular chlorine in an argon matrix at 4.2 K |
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| J.B. Nee | Chinese Journal of Physics, 26, 254-261, (1988) | Excited Chlorine Atoms Produced from Photodissociation of Cl2 with Vacuum Ultraviolat Radiation |
|
| M. J. Watts, K. G. Linden | Water Research, 41 (13), 2871-2878, (2007) | Chlorine photolysis and subsequent OH radical production during UV treatment of chlorinated water |
|
| Additional datasheets and spectra of Cl2 are available at our Spectra Service |
| F2; fluorine; CAS-No.: 7782-41-4 | |||
| R.K. Steunenberg, R.C. Vogel | J. Am. Chem. Soc. 78, 901-902, (1956) | The Absorption Spectrum of Fluorine |
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| R. P. Iczkowski, J. E. Margrave | J. Chem. Phys., 30, 403-405, (1959) | Absorption Spectrum of Fluorine in the Vacuum Ultraviolet |
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| G.N. Makeev, V.F. Sinyanskii, B.M. Smirnov | Dokl. Akad. Nauk SSSR 222, 151-154, (Doklady- Phys. Chem., 452-455), (1975) | Absorption spectra of certain fluorides in the near ultraviolet region |
|
| E.A. Colburn, M. Dagenais, A.E. Douglas, J.W. Raymonda | Can. J. Phys., 54, 1343-1359, (1976) | The electronic spectrum of F2 |
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| V. A. Legasov, G. N. Makeev, V. F. Sinyansky, B. M. Smirnov | J. Fluorine Chem., 11 (2), 109-118, (1978) | Fluorine absorption spectra and some fluorides in condensed state |
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| R. Holland, J. L. Lyman | J. Quant. Spectr. Rad. Transfer, 38, 79-80, (1987) | Ultraviolet Absorption Spectrum of Molecular Fluorine |
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| P.F. Levelt, K.S.E. Eikema, S. Stolte, W. Hogervorst, W. Ubachs | Chem. Phys. Lett., 210, 307-314, (1993) | XUV-laser excitation of molecular fluorine |
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| G.A. Argueello, G. Balzer-Joellenbeck, B. Juelicher, H. Willner | Inorg. Chem., 34 (3), 603-606, (1995) | Properties of fluoroformyl hypofluorite, FC(O)OF, revisited |
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| A.J. Cormack, A.J. Yencha, R.J. Donovan, K.P. Lawley, A. Hopkirk, G.C. King | Chem. Phys., 213, 439-448, (1996) | High-resolution threshold photoelectron spectroscopy of molecular fluorine |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| A.E. Croce, C. A. Tori, E. Castellano | Zeitschrift für Physikalische Chemie; 216, 947, (2002) | The Photolysis of Fluorine at 366 nm in the Presence of Bis(Fluoroformyl)Peroxide |
|
| I2; iodine; CAS-No.: 7553-56-2 | |||
| K. Vogt, J. Koenigsberger | Zeitschrift für Physik, 13 (1), 292-311, (1923) | Beobachtungen über Absorption in Joddampf und anderen Dämpfen |
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| E. Rabinowitch, W. C. Wood | Trans. Faraday Soc., 32, 540-546, (1936) | The extinction coefficients of iodine and other halogens |
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| R.D. Verma | J. Chem. Phys., 32, 738, (1960) | Ultraviolet Resonance Spectrum of the Iodine Molecule |
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| J. Tellinghuisen | J. Chem. Phys., 58, 2821-2834, (1973) | Resolution of the visible-infrared absorption spectrum of I2 into three contributing transitions |
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| A.J. Yencha, M.C.R. Cockett, J.G. Goode, R.J. Donovan, A. Hopkirk, G.C. King | Chem. Phys. Lett., 229, 347-352, (1994) | Threshold photoelectron spectroscopy of I2 |
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| A. Saiz-Lopez, R. W. Saunders, D. M. Joseph, S. H. Ashworth, J. M. C. Plane | Atmos. Chem. Phys., 4, 1443-1450, (2004) | Absolute absorption cross-section and photolysis rate of I2 |
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| J. A. Eng, J. L. Hardwick, J. A. Raasch, E. N. Wolf | Spectrochimica Acta Part A: Mol. Biomol. Spectroscopy, 60, 3413-3419, (2004) | Diode laser wavelength modulated spectroscopy of I2 at 675 nm |
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| P. Spietz, J. Gomez Martin, J.P. Burrows | Atmos. Chem. Phys., 6, 2177-2191, (2006) | Effects of column density on I2 spectroscopy and a determination of I2 absorption cross section at 500 nm |
|
| related data (quantum yield studies; photolysis studies) | |||
| L. Brewer, J. Tellinghuisen | J. Chem. Phys. 56, 3929-3938, (1972) | Quantum Yield for Unimolecular Dissociation of I2 in Visible Absorption |
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| P. O'Keeffe, D. Stranges, P.L. Houston | J. Chem. Phys., 127, 144309, (2007) | Neutral photodissociation of superexcited states of molecular iodine |
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| ClF; chlorine fluoride; CAS-No.: 7790-89-8 | |||
| A. L. Wahrhaftig | J. Chem. Phys., 10, 248, (1942) | The Absorption Spectrum of Chlorine Fluoride |
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| H. Schmitz, H.J. Schumacher | Zeitschrift für Naturforschung A, 2a, Heft 11/12, 359, (1947) | Das Bandenspektrum und die Dissoziationswärme des ClF |
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| R.D. Wilson, A.E. Axworthy, K.O. Christe | Journal of the Argentine Chemical Society, Vol. 93 - No. 4/6, 1-20, (2005) | Photochemistry of interhalogen compounds |
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| V. A. Alekseeva, N. Schwentner | Chem. Phys. Lett., 495, 24-26, (2010) | Absorption and luminescence excitation spectra of ClF in the Vac UV region |
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| BrCl; bromine chloride; CAS-No.: 13863-41-7 | |||
| D.J. Seery, D. Britton | J. Phys. Chem., 68 (8), 2263-2266, (1964) | The Continuous Absorption Spectra of Chlorine, Bromine, Bromine Chloride, Iodine Chloride, and Iodine Bromide |
|
| H. Gutmann, M. Lewin, B. Perlmutter-Hayman | J. Phys. Chem., 72 (10), 3671-3673, (1968) | Ultraviolet absorption spectra of chlorine, bromine, and bromine chloride in aqueous solution |
|
| A. Hopkirk, D. Shaw, R.J. Donovan, K.P. Lawley, A.J. Yencha | J. Phys. Chem., 93, 7338-7342, (1989) | Vacuum-Ultraviolet Absorption, Fluorescence Excitation, and Dispersed Fluorescence Spectra of BrCl |
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| D. Maric, J.P. Burrows, G.K. Moortgat | J. Photochem. Photobiol. A: Chem., 83, 179-192, (1994) | A Study of the UV-Visible Absorption Spectra of Br2 and BrCl |
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| S. Hubinger, J.B. Nee | J. Photochem. Photobiol., 86, 1-7, (1995) | Absorption Spectra of Cl2, Br2 and BrCl between 190 and 600 nm |
|
| ICl; iodine chloride; CAS-No.: 7790-99-0 | |||
| J.L. Binder | Phys. Rev., 54, 114-117, (1938) | The Continuous Absorption Spectrum of Iodine Monochloride in the Ultraviolet |
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| D.J. Seery, D. Britton | J. Phys. Chem., 68 (8), 2263-2266, (1964) | The Continuous Absorption Spectra of Chlorine, Bromine, Bromine Chloride, Iodine Chloride, and Iodine Bromide |
|
| Additional datasheets and spectra of ICl are available at our Spectra Service |
| IBr; iodine bromide; CAS-No.: 7789-33-5 | |||
| D.J. Seery, D. Britton | J. Phys. Chem., 68 (8), 2263-2266, (1964) | The Continuous Absorption Spectra of Chlorine, Bromine, Bromine Chloride, Iodine Chloride, and Iodine Bromide |
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| R. J. Donovan, P. J. Robertson | Spectroscopy Letters, 5, 361-369, (1972) | Vacuum Ultraviolet Spectrum of IBr |
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| Additional datasheets and spectra of IBr are available at our Spectra Service |
