Data Sheet
von COF2 und COFCl im UV-Bereich
von COF2 und COFCl im UV-Bereich
Substances: FCO, COF2, COCl2, COClF, COFI, COBr2
The relevant Spectra Data are available (for registered users) at: Spectra Service
Please note: In addition, information concerning related publications (e.g. quantum yield studies or photolysis studies) for some of the substances are given. Send us your feedback
| Authors | Journal/Source | Title/Paper |
Data Sheet |
| FCO; fluoroformyl radical; CAS-No.: 1871-24-5 | |||
| D.E. Milligan, M.E. Jacox, A.M. Bass, J.J. Comeford, D.E. Mann | J. Chem. Phys., 42, 3187-3195, (1965) | Matrix-Isolation Study of the Reaction of F Atoms with CO. Infrared and Ultraviolet Spectra of the Free Radical FCO |
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| M.M. Maricq, J.J. Szente, G.A. Khitrov, J.S. Francisco | Chem. Phys. Lett., 199, 71-77, (1992) | FCO: UV spectrum, self-reaction kinetics and chain reaction with F2 |
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| B.A. Williams, J.W. Fleming | J. Chem. Phys., 106, 4376-4382, (1997) | Laser-induced fluorescence spectrum of the FCO radical |
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| T.J. Wallington, T. Ellermann, O.J. Nielsen, J. Sehested | J. Phys. Chem., 98, 2346-2356, (1994) | Atmospheric chemistry of FCOx radicals: UV spectra and self-reaction kinetics of FCO and FC(O)O2 and kinetics of some reactions of FCOx with O2, O3, and NO at 296 K |
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| M.M. Maricq, J.S. Szente, Yi Su, J.S. Francisco | J. Chem. Phys., 100, 8673-8680, (1994) | Ultraviolet spectroscopy of the B 2A and C 2A states of FCO |
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| W.H. Howie, I.C. Lane, A.J. Orr-Ewing | J. Chem. Phys., 113, 7237-7251, (2000) | The near ultraviolet spectrum of the FCO radical: Re-assignment of transitions and predissociation of the electronically excited state |
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| Additional FCO spectra and datasheets are available via our Spectra Service | |||
| COF2; carbonyl fluoride; CAS-No.: 353-50-4 | |||
| C.C. Chou, G. Crescentini, H. Vera-Cruiz, W.S. Smith, F.S. Rowland | 173rd American Chemical Society Meeting, New Orleans, LA.,(1977) | Stratospheric Photochemistry of CF2O, CClFO, and CCl2O |
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| L.T. Molina, M.J. Molina | 182rd American Chemical Society Meeting, New York, (1982) | Chemistry of Fluorine in the Stratosphere |
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| A. Noelle, H. Heydtmann, R. Meller, G.K. Moortgat | Geophys. Res. Lett., 19, 281-284, (1992) | UV Absorption Spectra and Absorption Cross Sections of COF2 at 296 K in the Range 200 - 230 nm |
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| A. Noelle, H. Heydtmann, R. Meller, G.K. Moortgat | priv. comm., (1990) | University of Frankfurt and MPI Mainz, 1990 |
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| A. Noelle | PhD Thesis University of Frankfurt, (1996) | Bestimmung von Quantenausbeuten und Absorptiosquerschnitten von COF2 und COFCl im UV-Bereich |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| A. E. Croce, E. Castellano | J. Fluorine Chem., 44, 267-273, (1989) | Carbonyl fluoride infrared spectrophotometric determination |
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| A. Noelle, C. Krumscheid, H. Heydtmann | Chem. Phys. Lett., 299, 561-565, (1999) | Determination of quantum yields in the UV photolysis of COF2 and COFCl |
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| COCl2; carbonyl chloride; phosgene; CAS-No.: 75-44-5 | |||
| H. Okabe, A.H. Laufer, J.J. Ball | J. Chem. Phys. 55, 373, (1971) | Photodissociation of OCCl2 in the Vacuum Ultraviolet: Production and Electronic Energy of Excited Cl2 |
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| D. Chadwick | Can. J. Chem., 50, 737-746, (1972) | Photoelectron spectra of phosgene and thiophosgene |
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| H. Okabe | J. Chem. Phys., 66, 2058-2062, (1977) | Photodissociation of thiophosgene |
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| C.C. Chou, G. Crescentini, H. Vera-Cruiz, W.S. Smith, F.S. Rowland | 173rd American Chemical Society Meeting, New Orleans, LA.,1977 | Stratospheric Photochemistry of CF2O, CClFO, and CCl2O |
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| W. Schneider, G. von Helden, Wilson, G.K. Moortgat | priv. comm., (1987) | MPI Mainz, 1987 (294 K) |
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| S. Glicker, H. Okabe | J. Phys. Chem., 91, 437-440, (1987) | Photochemistry of diacetylene |
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| R. Meller, D. Boglu, G.K. Moortgat | Kinetics and Mechanisms for the reactions of halogenated organic compounds in the troposphere. STEP-HALOCSIDE/AFEAS Workshop, Dublin, Eire, 110-115, (1991) | UV spectra of several halogenated carbonyl compounds and FTIR studies on the degradation of CF3COCl, HCFC-123 and HCFC-134a |
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| D. Gillotay, P.C. Simon, L. Dierickx | presented at: Quadrennial Ozone Symposium, Charlottesville VA, USA, (1992) | Ultraviolet absorption cross-sections of some carbonyl compounds and their temperature dependence |
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| M. Jäger, H. Heydtmann, C. Zetzsch | Chem. Phys. Letters, 263, 817-821, (1996) | Vacuum Ultraviolet Spectrum and Quantum Yield of the 193 nm Photolysis of Phosgene |
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| M.R.J. Hachey, F. Grein | Chem. Phys., 224, 19-31, (1997) | Multireference configuration-interaction studies on the UV and photoelectron spectrum of phosgene, Cl2CO |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| M. H. J. Wijnen | J. Am. Chem. Soc., 83, 3014-3017, (1961) | Photolysis of Phosgene in the Presence of Ethylene |
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| J. Heicklen | J. Am. Chem. Soc., 87 (3), 445-453, (1965) | The Photolysis of Phosgene-Ethylene Mixtures |
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| T. Einfeld, A. Chichinin, C. Maul, K.-H. Gericke | J. Chem. Phys., 116, 2803-2810, (2002) | Photodissociation dynamics of phosgene: New observations by applying a three-dimensional imaging technique |
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| COClF; carbonyl chlorofluoride; CAS-No.: 353-49-1 | |||
| C.C. Chou, G. Crescentini, H. Vera-Cruiz, W.S. Smith, F.S. Rowland | 173rd American Chemical Society Meeting, New Orleans, LA.,(1977) | Stratospheric Photochemistry of CF2O, CClFO, and CCl2O |
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| A. Noelle, H. Heydtmann, R. Meller, G.K. Moortgat | Geophys. Res. Lett., 20, 707-710, (1993) | Temperature Dependent UV Absorption Spectra of Carbonyl Chloro-Fluoride |
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| A. Noelle | PhD Thesis University of Frankfurt, (1996) | Bestimmung von Quantenausbeuten und Absorptiosquerschnitten von COF2 und COFCl im UV-Bereich |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| M. Hermann, A. Noelle, H. Heydtmann | Chem. Phys. Lett., 226, 559-562, (1994) | Photolysis and quantum yield of carbonylchlorofluoride at 193 nm |
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| A. Noelle, C. Krumscheid, H. Heydtmann | Chem. Phys. Lett., 299, 561-565, (1999) | Determination of quantum yields in the UV photolysis of COF2 and COFCl |
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| C. Maul, C. Dietrich, T. Haas, K.-H. Gericke | Phys. Chem. Chem. Phys., 1, 1441 - 1446, (1999) | Photodissociation dynamics of carbonyl chloride fluoride and its implications for phosgene three body decay |
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| COFI; fluorocarbonyl iodide; CAS-No.: | |||
| M. S. Chiappero, G. A. Arguello, P. Garcia, H. Pernice, H. Willner, H. Oberhammer, K. A. Peterson, J. S. Francisco | Chem. Eur. J., 10, 917-924, (2004) | Molecular Structure, Spectroscopy and Matrix Photochemistry of Fluorocarbonyl Iodide, FC(O)I |
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| COBr2; carbonyl bromide; CAS-No.: 593-95-3 | |||
| H.G. Libuda, F. Zabel, K.H. Becker | CEC-Report, STEP-HALOCSIDE/AFEAS Workshop, Dublin, Kinetics and mechanism for the reactions of halogenated organic compounds in the troposphere, 126-131, (1991) | UV spectra of some organic chlorine and bromine compounds of atmospheric interest |
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| H.G. Libuda | Ph-D-Thesis, (1992) | Uni Wuppertal, Germany |
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